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Changed susceptibility of the chemically and thermally degraded spruce wood to its attack by the dry rot fungus Serpula lacrymans
1999 - IRG/WP 99-10322
In buildings, some intentional or unintended situations can occur at which some wood products are exposed to aggressive chemicals and also to higher temperatures. Occasional activity of fungi on such pre-attacked wood products can be either higher or lower. This paper deals with changes in the susceptibility of spruce wood (Picea abies L. Karst.) to attack by the dry rot fungus Serpula lacrymans, in such situations, when the wood samples 8.5x8.5x120 mm3 (RxTxL) were first pre-treated with 1% water solutions of selected acids (H2SO4, CH3COOH), bases (NaOH, NH4OH) or oxidizing agent (H2O2), or they were also exposed to a higher temperature (190°C/3h). The activity of S. lacrymans was totally restricted only in one situation, if the wood was pre-treated with sulphuric acid and then exposed to 190°C. On the other hand, specimens pre-treated with ammonium hydroxide were more susceptible to bio-attack (in both situations: without or with high temperature pre-treatment effect) than sound ones.
L Reinprecht

Screening potential preservatives against stain and mould fungi on pine timber in Zimbabwe
1995 - IRG/WP 95-30063
The search for environmentally and toxicologically safer chemicals for use in the timber preservative industry against stain and mould fungi has been intensified during the past few years. Results of field tests with two chemicals previously evaluated in the laboratory are presented. The conventional sodium pentachlorophenate was the more efficacious chemical against stain and mould fungi, providing up 90% control at a concentration of 2.5%. A potential alternative, Stopstain a borate-based chemical, gave results only slightly better than the untreated control timber, at a concentration of 5%. Unless the environmental cost and toxicological hazards of traditional chemicals are highlighted the newer and safer chemicals will be reluctantly accepted by industry as they are regarded as being prohibitively expensive.
A J Masuka

The evaluation of synergistic effects of chemicals on fungicidal efficacy in crossed-paper tests
1991 - IRG/WP 2383
The mixing effects of wood preservatives were evaluated using the crossed-paper technique. Two filter paper strips (0.7 x 8 cm²) were treated by soaking with different chemicals [fungicides, a termiticide (chlorpyrifos or phoxim), a surface-active agent, a synergistic agent, and a stabilizer], and placed at right angles to each other on a fully grown mycelial mat of a test fungus in a Petri dish. When the four organoiodine fungicides were incorporated with chlorpyrifos or surface active agent, only 3-iodo-2-propynyl butyl carbamate (IPBC) showed the desirable synergistic effect against every wood-decaying fungus tested. Other fungicides did not always tend to produce the synergistic effect with the addition of a surface active agent. 4-Chlorophenyl-3-iodopropargyl formal (IF-1000) appeared to indicate an undesirable antagonistic effect when mixed with either chlorpyrifos or a surface active agent. 3-Bromo-2, 3 diiodo-2-propenylethyl carbamate (EBIP) did not show any synergistic action by mixing with chlorpyrifos and/or a surface active agent, although the fungicidal enhancement was induced satisfactorily by mixing the fungicide with chlorpyrifos, a stabilizer and/or a synergistic agent, especially against Tyromyces palustris and Coriolus versicolor. Similarity of the results obtained in the present investigation and in the previous laboratory decay tests leads to the conclusion that the crossed-paper technique is suitable for the evaluation of the mixing effect of chemicals on fungicidal efficacy.
Dong-heub Lee, K Tsunoda, M Takahashi

Programme section 3, Wood protecting chemicals
1997 - IRG/WP 97-30159
IRG Secretariat

In search of alternative antisapstain chemicals for use in Papua New Guinea
1988 - IRG/WP 3472
The paper presents results of antisapstain field trials from three locations in Papua New Guinea as part of the Research Centre's programme to find suitable antisapstains to replace the hazardous sodium pentachlorophenate. Effectiveness of seven tested chemicals varied between indigenous pines (Araucaria cunninghamii, Araucaria husteinii) and white coloured hardwoods (Alstonia scholaris, Pterocymbium beccarii) but not between sites. The indigenous pines required lower chemical concentration for same level and period of protection than white coloured hardwoods like amberoi and white cheesewood. Period of protection ranged from four weeks to a maximum of 16 weeks depending on chemical concentration and species of timber. Potential chemicals recommended for use as antisapstain include Celbrite T, Busan 1009, Penacide and Woodguard E.S. and Woodguard E.C.
A Oteng-Amoako

Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi
1989 - IRG/WP 1394
Field tests using freshly felled pine sapwood were set up to determine the effectiveness of a range of antisapstain compounds and to study the problems of colonization by mould and sapstain fungi. Differences were recorded both in the overall performance of the compounds and also their selectivity in controlling specific fungal types. These results were found to be useful in gaining a better understanding of biocide - fungal interactions.
G R Williams, D A Lewis

Laboratory evaluation of chemicals as termiticides
1986 - IRG/WP 1293
Laboratory procedures are described for screening chemicals against subterranean termites. Fast-acting compounds with persistent termiticidal activity are identified in tests using a soil substrate, and slower-acting bait toxicants are evaluated in a series of tests using cellulose substrates.
S C Jones

Commercially available anti-sapstain chemicals in New Zealand - An update
1987 - IRG/WP 3416
Six anti-sapstain chemicals or mixtures (NaPCP plus borax, Haipen 5F, Mitrol PQ375, Busan 1009, Protek S, Pinefol 50W) are available as commercial treatments in New Zealand. A further two (Hylite 20F and Isothon-35) have shown potential in field and mill trials and will be available for use. A number of other formulations are under evaluation.
J A Drysdale

Mould resistance of lignocellulosic material treated with some protective chemicals
1984 - IRG/WP 3294
Effectiveness of preserving lignocellulosic material against moulding by treatement with water solutions of commercial wood preservatives and mixtures of various inorganic salts was investigated and compared with the effectivenes of sodium pentachlorophenoxide and boric acid.
K Lutomski

Proposed standard laboratory method for testing fungicides for controlling sapstain and mould on unseasoned lumber
1977 - IRG/WP 292
This laboratory method is for determining the effective concentration, or concentration for zero growth (CGo), for fungicides or preparations of fungicides which are potentially useful in protecting packaged or unseasoned lumber in storage and shipment from biodeterioration by sapstain fungi and moulds. The test is rapid and may be completed in three weeks and gives a good indication of the toxicity of a chemical against sapstain fungi and moulds.
A J Cserjesi

Selective adsorption of antisapstain actives from two aqueous suspensions, and movement of actives into wood
1996 - IRG/WP 96-30103
Green-off-saw rough sawn Pinus elliottii (slash pine) boards were dipped in aqueous suspensions of two antisapstain formulations, NeXgenâ and Busanâ Sap Stain Preventative (Busan 1009), at three product concentration levels. Concentrations of active ingredients (NeXgen: CTL (chloro-thalonil) and MTC (methylene bisthiocyanate); Busan 1009: TCMTB (2(thiocyanomethylthio)-benzothiazole) and MTC) were monitored with respect to the amount of material dipped. Selective adsorption (removal of actives from the suspension at greater than simple volumetric transfer rates) varied with formulation and active ingredient, and increased with decreasing product concentration. Movement of active ingredients into dipped boards was monitored for 30 days after dipping. Mobility order was MTC >> TCMTB > CTL. Surface depletion characteristics were obtained for each active ingredient.
M J Kennedy, T L Woods

Efficacy of anhydrides as wood protection chemicals - II. Performance against soft rot fungi
1998 - IRG/WP 98-30174
Pine sapwood modified with various anhydrides and with butyl isocyanate was tested for its resistance to soft rot decay. Small stakes were exposed for 20 months in unsterile soil in a fungal cellar test. Wood modified with butyl isocyanate performed better than any of the anhydrides tested, with a threshold level of protection (less than 3% weight loss) at 12% weight percent gain (WPG). Stakes acetylated to 15% WPG did not give complete protection against soft rot. Stakes modified with alkenyl succinic anhydride showed increasing resistance to soft rot with WPG up to about 10% WPG, above which no further improvements were evident. Succinic anhydride and phthalic anhydride treated stakes showed little or no noticeable protection.
S C Forster, M D C Hale, G R Williams

The effectiveness test of chemicals against Serpula lacrymans
1984 - IRG/WP 2222
The effectiveness tests of wood preservatives against Serpula lacrymans were conducted in accordance with Japan Industrial Standard A 9302 and Japanese Wood Preserving Association Standard No. 1. Also, the soil treatment test against this fungus was carried out with two chemicals. The preservatives tested without Creosote oil (out of JIS) had sufficient preservative effect against Serpula lacrymans. Flutolanil for soil treatment had full effect for suppression of the hyphal growth of Serpula lacrymans onto the soil surface.
S Doi

Fire resistance of Alder wood treated with some chemicals. Part II. Effect of Other Chemicals on the Combustion Properties
2002 - IRG/WP 02-40235
Samples from alder wood (Alnus glutinosa (L.) Gaertn. subsp. barbata (C.A.Mey) Yalt.) were impregnated according to ASTM D 1413-88 with boron compounds (boric acid, borax, sodium perborate), vinyl monomers (styrene, methyl methacrylate), Tanalith-CBC, Phosphoric acid, Vacsol, Immersol, Polyethylene glycole (PEG-400) and their mixed solutions of chemicals in order to determine their combustion properties. The results indicated that inorganic boron compounds with aqueous solutions were very effective as fire retardant and reduced burning of some vinyl monomers at some extent such as styrene and methylmetacrylate when used as a secondary treatment chemical polimerized later on wood structure and phosphoric acid was also showed fire-reterdancy. Further studies are suggested on boron-vinyl monomers, and boric acid+borax with different concentrations by physical and chemical interactions in terms of fire reterdancy.
A Temiz, Ü C Yildiz

Field trials of anti-sapstain products. Part 1
1991 - IRG/WP 3675
The results obtained in two field tests of anti-sapatain products, carried out in four locations in Portugal, are presented. Boards from freshly cut logs were hand-dipped, close staked and left to dry for periods from four to six months. The results obtained seem to indicate that some of the products tested performed at least as well and sometimes better, than a 3% NaPCP solution which was used as control product.
L Nunes, F Peixoto, M M Pedroso, J A Santos

Point sur la réglementation et contraintes administratives
1990 - IRG/WP 3575
J H Moneger

Evaluation of the effectiveness of three microbiocides in the control of sapstains
1982 - IRG/WP 3212
Results of field test on the effectiveness of BUSAN 30, CAPTAN, FOLPET against mould and sapstain in Pinus elliottii are presented. The viability of use of FOLPET in Brazil as an alternative to sodium pentachlorophenate is also discussed.
S Milano, J A A Vianna Neto

Questionnaire pour la préparation de fiches monographiques pour les champignons lignivores
1972 - IRG/WP 103 F
C Jacquiot

Austrian field test method for anti-sapstain chemicals
1994 - IRG/WP 94-20020
Although Austria is a small country, the annual consumption of anti-sapstain products ranks to approximately 500 tons annually. In 1994, only three products will be approved by the Austrian Wood Preservation Committee (AWPEC). There is demand for a field test method, which demonstrates the efficacy of an anti-sapstain product and consequently implies the acceptance and approval of product by the AWPEC. Present field test was carried out in 1992 and 1993. The results were evaluated after six months storage of test stacks. A TCMTB based product was used as a reference. The results show that the AFPRL method proves very suitable for the simulation of practical situation in Austrian treatment plants, where pine and/or spruce are treated periodically and where different methods of stack storage are applied.
R Gründlinger, M Brandstätter, H Melzer, O Janotta

The collaborative developement of soil acceptance criteria for timber treatment chemicals in New Zealand
1995 - IRG/WP 95-50040-34
In New Zealand, the issue of potential contamination on timber treatment sites arose in the late 80's due to the long history of use of PCP by the industry. One of the recommendations from the task group set up to investigate the issue was the development of a set of acceptance criteria to define trigger levels for remediation. A technical group from the government, industry and regional councils supported by experienced environmental consultants was formed by the Ministry for the Environment to prepare the criteria. Guidelines for soil and landfill criteria were drafted covering the commonly used preservative products based primarily on human health risk exposure. Guidelines were also developed for specific beneficial uses where other risk exposures may dominant. The guidelines have been peer reviewed and issued in draft form for public comment. Several benefits have flowed from this process namely, a relatively short timeframe, low cost, multiple party ownership, practicality of application and ease of administration.
H C Boyd

Effects of timber surface properties and dipping conditions on uptake of antisapstain actives from two aqueous suspensions, and ultimate effects on efficacy against mould and staining organisms
1995 - IRG/WP 95-30073
Green-off-saw rough sawn Pinus elliottii (slash pine) boards were dipped in aqueous suspensions of two antisapstain formulations, and the resultant surface retentions of active ingredients MTC (methylene bisthiocyanate), CTL (chlorothalonil) or TCMTB (2(thiocyanomethylthio)benzothiazole) were monitored by chemical analysis. Surface retentions increased with suspension concentration and surface roughness, and decreased with initial timber moisture content. Dipping time beyond 20 seconds, timber basic density and earlywood content had little effect. Relatively low surface retentions, produced by dipping smoother boards with higher initial moisture contents, provided lower protection against mould and stain during seasoning than higher retentions. Equations describing the effect of surface retention on efficacy were developed for both formulations, and retentions providing complete protection under the conditions of the test were determined.
M J Kennedy, T L Woods

Termite standards questionnaire survey
1987 - IRG/WP 1324
J R J French, J P La Fage

Working Group II: Sub-group: Methods of testing anti-stain chemicals for protecting sawn lumber during storage, transit
1978 - IRG/WP 2121
R Smith

A standardised procedure for the treatment of timber with test chemicals
1986 - IRG/WP 2257
A procedure is described which allows the standardisation of sample handling and data manipulation during trials invastigating the treatability of timber with test chemicals. The use of computer software allows the data to be handled efficiently.
J Norton, A Zosars, L E Leightley

Model questionnaire for preparation of monographic cards for wood-destroying fungi
1972 - IRG/WP 103
C Jacquiot

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