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Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


Can CCA be substituted as reference preservative?
2018 - IRG/WP 18-20641
While field testing of wood protective formulations remains probably the best method to find out the effective preservative concentration, the use of chrome-copper arsenate (CCA) as reference becomes debatable due to environmental and legislative reasons. This emerges from the European standardization bodies who have discussed reference alternatives that can omit the use of CCA. The present debate...
N Terziev, M Jebrane, P Larsson Brelid, N Morsing, P-O Flaete, P Torniainen, J S Kim, G Daniel


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Long-term Performance of Treated Timbers in a Sub-tropical Marine Exposure
2023 - IRG/WP 23-11015
The long-term performance of preservative-treated and modified wood in marine exposures was assessed in Brisbane, Queensland, Australia. This report describes the final destructive assessment of the surviving Australian panels after 11 years of exposure. This site presents the potential for attack by shipworms (likely Bankia spp.), pholads (Martesia striata), Limnoria and Sphaeroma terebrans. Mos...
E L Galore, J Norton, A Zahora


Establishing the minimum effective penetration of wood preservatives in the refractory heartwood of E. nitens
2023 - IRG/WP 23-30780
Conventional pressure treatment of many Australian hardwoods results in little to no penetration of heartwood and a non-uniform envelope treatment of <5 mm surrounding a mostly untreated core. This is a major issue for many of the low durability plantation hardwood timbers that are grown in Tasmania, which contain high percentages of heartwood. Long term studies on softwoods such as spruce decking...
J R Vargas, J J Morrell, L Yermán, K C Wood


Through-boring to improve the performance of low durability Eucalyptus species for utility poles: 10-year field test results of pole stubs exposed in Southeast Queensland
2023 - IRG/WP 23-40972
An impending shortage of naturally durable hardwood electricity pole timbers in Australia has encouraged investigation of alternatives containing less durable, untreatable heartwood. Through-boring or drilling holes perpendicular to the long axis before treatment, has been used successfully on refractory softwood poles in North America and might have application in Australia. The use of through-bo...
J Norton, L P Francis, J J Morrell


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


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