IRG Documents Database and Compendium


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Alternative technologies for wood wastes recycling - Part B: Biotreatment of PCP- and creosote-treated wood
1998 - IRG/WP 98-50101-18 b
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
S Legay, P Marchal, G Labat


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


Borates and their biological applications
1998 - IRG/WP 98-30178
This paper reviews some of the many biological applications of borates. Boron is a ubiquitous element found widely distributed in the environment and is a normal component of a healthy diet. Elemental boron does not exist in nature, but is always found combined with oxygen in compounds called borates. Boron is an essential micronutrient for plants, and there is evidence to suggest that boron is of...
J D Lloyd


Chemical analysis for TBTN in LOSP-treated wood and preservative fluids
1994 - IRG/WP 94-20027
Tributyltin napthenate (TBTN) is being substituted for tributyltin oxide (TBTO) in LOSP preservative formulations because its lower reactivity/better stability allows co-formulation with synthetic pyrethroids. Better stability may reduce molecular degradation both in-service and during analysis. It was considered necessary to check whether TBTO analysis methods were suitable for use on TBTN treate...
D P Wraight, M J Kennedy


CCA Chemistry
1983 - IRG/WP 3268
A Pizzi


Rapid analytical methods for wood waste - An overview
1998 - IRG/WP 98-50104
The proper handling of wood after service is a today's problem. Untreated wood could be reused or may be used as fuel. For treated wood special care is demanded to avoid environmental impacts. Thus, analytical methods are requested to detect rapidly whether and to what extend wood is contaminated, covering a wide spectrum of organic and inorganic agents used during the last 50 years. Trad...
A Peylo, R-D Peek


Soil chemistry and wood decay
1978 - IRG/WP 2109
Soil is a most complex biological, chemical and physical material; its study is effectively a separate branch of science but almost entirely in relation to ist ability to grow plants - this paper is intendet just to note some known facets that might have relevance to the decay of wood and the performance of wood preservatives....
E A Hilditch


Accelerated laboratory soil contact decay test using soil amended with composted wood
2004 - IRG/WP 04-20284
The effect of amending soil with wood compost on the decay rate of wood wafers in contact with the unsterile soil, as measured by radial compression strength loss, was explored. It was found that the addition of composted wood to the soil significantly increased the wood decay rate. The reason for this acceleration in wood decay is not entirely clear, but appears to be at least partially associate...
D D Nicholas, H Borazjani, T Schultz


Copper naphthenate: An analysis of the materials found in the worldwide marketplace using a new analytical technique
2000 - IRG/WP 00-30224
Naphthenic acid has been recovered from products of petroleum refining for well over 100 years. The metal soaps, specifically copper and zinc naphthenate, have been evaluated and used as commercial wood preservatives for in excess of 60 years. Most of the early data supporting the continued use of copper naphthenate as a wood preservative was based on materials manufactured from naturally occurrin...
J A Brient, R E Moyer, M H Freeman, H Jiang


Natural weathering of wood in a sunny climate effects on surface chemistry and paint adhesion
1997 - IRG/WP 97-20109
Radiata pine veneers and blocks were exposed to natural weathering under Australian summer conditions over a period of 30 days. Infrared spectroscopy revealed that there was perceptible surface delignification after 4 hours exposure, substantial surface delignification after 3 days exposure and almost complete surface delignification after 6 days. Viscometry determinations on holocellulose samples...
P D Evans, P D Thay, K J Schmalzl


Development of a turbidity method for the determination of water repellent in CCA treatment solutions
2000 - IRG/WP 00-40177
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground exposures. However, they are also used in pole treatments to improve the climbing characteristics and in low VOC millwork ...
P J Walcheski, L Jin


The environmental chemistry of chromium: Science vs. U.S. law
1993 - IRG/WP 93-50014
The cooperation which existed among chromium chemical producers, industrial health laboratories, and governmet agencies was destroyed after 1970 by the advent of environmental activism and regulatory legislation. As prewar plants had been found to pose a serious cancer risk, this fact was the basis of EPA regulations, especially during the term of Joe Califano in HEW under Jimmy Carter. However, a...
W H Hartford


Analysis of water repellents in wood treated with water borne formulations using FTIR
2000 - IRG/WP 00-40176
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These products are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground applications. They are also used in pole treatments to improve climbing characteristics and in low VOC millwork t...
P J Walcheski, L Jin


Silafluofen: Novel chemistry and versatility for termite control
1995 - IRG/WP 95-30069
A novel silicon - containing insectizide, HOE 084498 ('Silafluofen'), with a favourable toxicological profile, has shown activity against a broad spectrum of agricultural and environmental health pests. Results from laboratory and field studies around the world have demonstrated that silafluofen is effective at protecting timber from attack by various species of termite and wood-...
A J Adams, A Jermannaud, M-M Serment


Natural Durability studies and Changes in wood chemistry of some Ghanaian hardwoods during decay by white- and brown-rot fungi
2004 - IRG/WP 04-10542
The natural decay resistance of Esa (Celtis mildbraedii), Wawabima (Sterculia rhinopetela) and Dahoma (Piptadeniastrum africanum) obtained from Ghana was determined according to BS EN 113 (1997). Esa was found not durable to the white-rot, but very durable to the brown-rot; Wawabima was very durable to both white- and brown-rots; and Dahoma was durable to the white-rot, and very durable to the bro...
Zeen Huang, K Maher, S A Amartey


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


On the nature of the tertiary wall in wood cells. Summary of lecture given at 9th Annual Meeting, Noordwijk-aan-Zee, Holland
1977 - IRG/WP 169
During recent discussions on the possible causes of failure of treated hardwood species by soft rot fungi, the uneven micro distribution of toxic components was found to be of importance; this might be attributed to a restricted diffusion of the preservative from the cell lumina into the cell wall.·In this context, the nature of the tertiary wall as the inner lining of wood cells merits special a...
W Liese


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Wood preservation requirements in Queensland, Australia
1983 - IRG/WP 3227
In Queensland the preservative treatment and utilization of timber must comply with the Timber Users' Protection Act. Preservative retention levels and penetration patterns must be complied with. Analytical zones are specified for removing samples for chemical analysis of preservative retention. The required retention levels have been expressed as percent weight of oven dry wood weight. T...
L E Leightley, M J Kennedy


The role of toilet paper in studies of desert subterranean termites in Arizona, USA
2000 - IRG/WP 00-10375
Toilet paper rolls were used as a substrate for observing foraging activity of Heterotermes aureus (Snyder) and Gnathamitermes perplexus (Banks) in the Sonoran Desert of Arizona. Foraging was minimal during the winter months, increased in the spring, was high but erratic in the summer, and then was moderate again in the fall. H. aureus foraged within a temperature range of 7.6° to 47°C, G. perpl...
M I Haverty


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


Diagnostics methods and routes proposalsto define selective sorting of demolition wood wastes
2001 - IRG/WP 01-50177
Wood wastes are more and more often used in different wood waste valorisation industries (panels, wood energy, cement factories, ...). These industries are in progress to include in their processes, wood wastes coming from demolition wood. A state of the art and an analysis have been made to propose : (1) diagnostics methods to carry out a classification of wood wastes on demolition sites and in t...
G Labat, E Bucket, C Fréret, G Deroubaix


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Water analysis in chemicals, wood or chemically treated wood using a new analytical method for selective water detection
2006 - IRG/WP 03-30391
Water or moisture content analysis can be a challenging task in many applications. However, knowing accurately the type of water which can be found in a given sample or product can provide important information about a chemical compound used for wood treatment and especially about the treated wood sample. Moisture content in wood plays an important role in fungal growth and it needs to be extensi...
R Craciun, D Taylor


Chelator-Mediated Fenton Chemistry in Wood Degraded by Fungi
2007 - IRG/WP 07-10618
Wood specimens were colonized by individual isolates of brown rot, white rot, soft rot and blue (sap) stain fungi. Ethyl acetate extracts of the ground wood were analyzed for their iron-reducing capabilities using a ferrozine-based assay. Extracts from wood colonized by brown rot fungi showed a significantly greater iron-reducing capability than extracts from wood colonized by white rot fungi or n...
B Goodell, G Daniel, J Jellison, Yuhui Qian


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