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The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Recycling and disposal of timber treated with waterborne copper based preservatives
1993 - IRG/WP 93-50008
Recycling and disposal technologies are briefly reviewed. Details are given of chemical extraction techniques suitable for recovery of copper from timber treated with a new copper based preservative, and traditional chromium based products. Details of thermal decomposition tests according to the DIN 53436 protocol under flaming and non-flaming conditions are given. The decomposition products were ...
J A Cornfield, S Vollam, P Fardell


Inter-laboratory comparison of assessment methods for wood preservatives against subterranean termites: Determination of protection threshold limits for CCA
1999 - IRG/WP 99-10317
In 1996, several institutes conducted laboratory bioassays on the efficacy of unleached Pinus radiata specimens treated with copper-chromium-arsenic (CCA) and copper naphthenate (Cu Naph) at retentions of 0.5, 1.0, 2.0 and 4.0 kg/m3 (total salt for CCA; elemental copper for Cu Naph) against a range of species of subterranean termites (IRG/WP/96-10174). Each participant employed the standard test m...
J W Creffield, M Lenz


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers by the vermiculite-burial method. (+ correction document of 25 July 1990)
1990 - IRG/WP 2354
Heartwood of copper-chrome-arsenic (CCA) treated kempas (Koompassia malaccensis), tualang (Koompassia excelsa) and keruing (Dipterocarpus spec.) was found to be susceptible to soft rot in recent pole surveys. Standardized heartwood blocks were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay for twelve weeks by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicula grisea...
R-D Peek, A H H Wong


The effect of copper/chrome/arsenic (CCA) treated timber on soil fungi
1981 - IRG/WP 1131
The aim of this investigation was to study the effect of CCA treated wood on the microflora of soil with particular reference to copper tolerant soft rot fungi. The IRG collaborative field experiment was designed to monitor the performance of a range of preservative treated hardwoods with particular reference to soft rot in CCA treated timber (Dickinson 1976) and site 33 of this experiment was use...
R J Murphy, D J Dickinson


Surface checking of CCA-treated radiata pine decking timber exposed to natural weathering
2000 - IRG/WP 00-40165
A field trial was established at four locations in Australia to assess the effect of CCA and CCA-wax treatment on the checking (cracking) of radiata pine decking timber exposed to natural weathering. Untreated decking timber and timber that had been pressure treated with water acted as controls. After 1 year's exposure the number and sizes of checks occurring in treated timber and control...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Studies in an accelerated soil bed facility on the decay susceptibility of U.K. grown spruce and pine poles treated with copper/chrome/arsenic (CCA) by pressurised sap-displacement. Part 1: Setting up of soil beds and initial soft rot results
1990 - IRG/WP 2344
The paper describes the methodology used in the construction and early operation of an accelerated soil bed facility used to examine the decay susceptibility of U.K. grown Scots and Corsican pine and Sitka and Norway spruce treated with C.C.A. by high pressure sap-displacememt. The design and control of the facility as well as the preparation, soil exposure and soft rot decay analysis of quarter p...
A Bruce, S D Hainey, G M Smith, B King, P D Evans


Performance of Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) treated panels of Bombax ceiba and Paraserianthus falcataria against bio-deterioration at Krishnapatnam harbour, east coast of India
2003 - IRG/WP 03-30310
Results of investigations on the durability of light weight timber species (Specific gravity below 0.4) i.e., Bombax ceiba and Paraserianthus falcataria in treated and untreated condition conducted at Krishnapatnam harbour (Lat 13o28’ to 13o59’ N; Long: 80o10’ to 80o16’E) along the east coast of India are reported in the paper. Exposure trails were conducted with panels (Size: 30 x 3.8 x...
B Tarakanadha, N R Raveendra Prasad, K S Rao


An audit of copper chrome arsenic timber treatment plants throughout Queensland
1995 - IRG/WP 95-50047
Thirty seven copper chrome arsenic (CCA) timber treatment plants in Queensland were assessed according to the operational criteria specified in Australian Standard 2843.2 - 1985, Timber Preservation Safety Code - Plant Operation. The criteria have been designed to provide information on the design and operational activities of a CCA plant. Design aspects that have an effect on the environment are ...
J Norton


A 53-year old field trial to evaluate the performance of a range of chemical treatments on eucalypt poles
1989 - IRG/WP 3526
Hardwood pole stubs of Eucalyptus maculata, Eucalyptus pilularis, Eucalyptus saligna and Eucalyptus paniculata were examined for termite attack and fungal decay after 53 years in ground contact. The trial compared eight different chemical treatments with untreated pole stubs of the four species investigated. Untreated Eucalyptus paniculata, a Class I durability species, performed particularly well...
R S Johnstone, R A Eaton


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


The present status of wooden catamarans of the Indian Coast
1997 - IRG/WP 97-10231
Catamarans (a.k.a. kattumarams) are the most widely used fishing craft in India, and hundreds of thousands of poor, traditional fishermen depend on these vessels for their livelihood that are almost made entirely of wood. In recent years, acute shortages and phenomenal increases in prices of timber species used in catamaran fabrication have been reported, causing great hardship to the user communi...
K S Rao


Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Wood preservation in Canada - Regulation and Registration
2001 - IRG/WP 01-50166-02
The Canadian wood preservation industry is at a critical juncture now as a number of initiatives converge on the industry over the next few years. Issues facing the industry include: Re-evaluation of the conventional wood preservative chemicals - inorganic arsenicals, creosote and pentachlorophenol targeted for July 2001. Delayed registration of new actives as a result of re-evaluation activity an...
P A Cooper


Interactions between soft rot fungi and CCA preservatives in Betula verrucosa
1988 - IRG/WP 1367
Ultrastructural investigations were carried out to obtain information on the cell wall distribution of CCA elements during soft rot decay of 4% K33 CCA preservative treated birch (Betula verrucosa) wood. TEM observations on fibres at various stages of S2 cavity formation by mutabilis showed a distinct pattern of electron dense materials to occur within the S2 cell wall region. These materials (gra...
G F Daniel, T Nilsson


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Treatment and recycle of CCA hazardous waste
1993 - IRG/WP 93-50007
Chromated copper arsenate containing hazardous materials is generated from the manufacture, treatment of the wood, and from the wood itself, after its life cycle. Laboratory treating of these wastes has resulted in materials suitable for recycle or disposal as non-hazardous residues. The extraction, by both acidic and ammoniacal routes, of CCA production and treating plant waste materials has been...
E A Pasek, C R McIntyre


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


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