Your search resulted in 181 documents. Displaying 25 entries per page.
Development of an Australasian protocol for assessment of wood preservatives
1994 - IRG/WP 94-20043
The Australasian Wood Preservation Committee (AWPC) is currently developing a suite of assessment procedures (protocols) for the biocidal efficacy of wood preservatives for approval in Australasia (Australia, New Zealand, Papua New Guinea, Fiji). Protocols are being prepared for the six hazard levels recognised in the relevant standards of member countries and represent the minimum procedures required to provide biocidal efficacy data which may be needed to obtain preservative approval and registration by the appropriate regulatory authorities. The protocols cover a combination of laboratory and/or field testing. This document presents a brief outline of the proposed format of the protocols.
W D Gardner, H Greaves, M E Hedley, K J McCarthy, J Norton
Increased biological durability differs for traditional wood preservation and new non-biocidal systems (NBS)
2000 - IRG/WP 00-20212
Wood preservation is a way to increase the biological durability of wood by the addition of chemical components with a biocidal effect. The effect of such treatment is clearly concentration dependent. At distinct levels of fungicide concentration fungi are killed or inhibited in their enzymatic functioning to provide nutrients. The toxic limits allow decision-makers to provide treating prescriptions based on a teared approach of European standards. Non-biocidal treatments may act totally different. Mechanisms as moisture exclusion or hydrophobation and modification of wood components inhibit, retard or stop the colonisation by fungi. Though these treatments are only effective from certain levels on or when a certain degree of substrate modification is reached, it is hardly possible to establish a dose response curve. Since these treatments do not fit into the standard methodology for evaluation of traditional wood preservation either new test methods or at least new ways of judgement and interpretation of results are required.
J Van Acker, M Stevens
The biocidal efficacy of sulphates against basidiomycetes
1999 - IRG/WP 99-30192
Copper sulphate is used for the preservation of wood since decades. However, if copper sulphate is not combined with a compound it can be leached up to 50% and more from the treated wood. Previous results for leached wood indicated that the loss of biological efficacy against soft rot corresponds to leaching of copper. For basidiomycetes, however, the effectiveness decreases much more rapidly. Therefore it is assumed that also the sulphate ion has a toxic effect against basidiomycetes. Systematic investigations were carried out to evaluate the biological efficacy of the sulphate ion using several copper free sulphates. The results of unleached test blocks show that other metal sulphates investigated have a similar biological efficacy against various types of basidiomycetes as copper sulphate.
H Leithoff, E Melcher
Guidance on the European Biocidal Products Regulation Concerning Efficacy of Wood Preservatives
2017 - IRG/WP 17-20627
In Europe wood preservatives belong to Product Type 8 (PT8) of the Biocidal Products Regulation (BPR, EU n. 528/2012), which regulates the authorisation of biocidal active substances and products in the European market. The applicant, who aims to obtain authorization to place a product onto the European market, needs to submit data to substantiate the label claims for the intended uses. Label claims are a central issue in the assessment of efficacy. The aim of this paper is to raise awareness of the recently issued “Guidance on the Biocidal Products Regulation” concerning the evaluation of efficacy of wood preservatives. This guidance document is addressed to the applicants as well as to the competent authorities of the member states of Europe in charge of assessing efficacy data, and has been in the public domain, in its latest version, since February 2017. The CEN/Technical Committee 38 “Durability of wood and wood based products” / WG 22 "Performance, assessment and specification” decided to bring the Guidance to a wider audience with the aim of disseminating the information and to trigger discussion among the experts of IRGWP. An excerpt of the Guidance that is relevant to wood preservative products is presented in an Annex to this paper.
I Stephan, M Kutnik, E Conti, M Klamer, L Nunes, J Van Acker, R Plarre
Promoting Commercially Available Epoxy Resins for Non-biocidal Wood Preservation
2019 - IRG/WP 19-40877
Commercially available epoxy and polyamine resins were evaluated with the aim of developing new non-biocidal wood preservation treatments. A simple method allowing the impregnation of wood by vacuum double impregnation followed by a curing process was developed for two reference species, beech Fagus sylvatica and Scots pine Pinus sylvestris. The tested products were evaluated for their ability to improve wood’s physico-mechanical properties, such as the anti-swelling efficiency (ASE) and resistance against biological agents (fungal decay, termites, marine borers). The weight percent gain (WPG) measured throughout the experimental steps was used to optimise the treatment parameters (such as dilution of the resins, curing temperatures, impregnation sequence). The best performing treatments demonstrated highly improved resistance against fungal decay, termites and marine borers, unusual patterns of attempted termite attacks being observed. Observations conduced on the termites’ and marine borers’ behavior suggest that the treatment applied to wood induces a starving effect and thus provides an indirect protection to the treated wooden samples. SEM analyses of the treated wood samples were also performed in order to determine if the polymers impregnated into wood tend to cure inside of the wood cell walls. These analyses demonstrated that wood polymers could be cured inside impregnated resin and then protected against water-related and biological damage. The last tests performed demonstrated that improving the penetration into wood cell walls of less concentrated products/polymers and optimizing the post-curing step are major issues for improving the resistance against fungal decay.
P Poveda, M Mubarok, S Dumarcay, M Montibus, I Le Bayon, M Kutnik, P Gerardin, F Simon
Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports of some copper naphthenate-treated poles rapidly failing. One possible explanation for the varying effectiveness could be that the structure, and resulting biological activity, of the naphthenic acids used to make copper naphthenate may vary. To test this hypothesis several naphthenic acids and copper naphenates were obtained and their fungicidal activity against three wood-destroying fungi measured. In addition, the chemical structure of the naphthenic acids were examined by proton- and carbon- NMR. Different activities were observed, especially against a copper-tolerant fungus. Some apparent correlations were seen between the fungicidal activity and chemical structures for the few samples studied.
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher
Developments in the protection of wood and wood-based products
1980 - IRG/WP 340
Technology is playing an increasingly important role in the field of wood protection. This current review highlights how modern techniques have provided greater insight into the biological and physical processes affecting the durability of wood and wood-based products. Emphasis is also given to developments in preservative testing methodology and to the encouraging changes towards both the correct use of timber and the improvement of Standards and Codes of Practice. A final section, on recent technical developments in wood preservation, considers subjects ranging from an evaluation of new specific biocides to methods of increasing the permeability of refractory timber species.
J M Baker
Proposed methodology for the assessment of safety indexes
1990 - IRG/WP 3562
Safety Indexes (SI)s are developped on the same concept as Efficacy Indexes (EI)s: EIs are retentions of wood preservatives (percentages of the critical values "efficacy") which are presumed efficient for a given biological class of risk. In the same way, SIs are retentions of wood preservatives (percentages of the critical values "safety") which are taken as acceptable for human health and the general environment. EIs and SIs as well are derived from different types of bioassays and related to objectives of quality which may be either regulatory or harmonized within the programmes of the Standard Committees (CEN TC/38 for example). Critical Values are characteristics of wood preservatives; EIs and SIs are characteristics of treated wood; they vary with the different classes of risks.
European Biocides Directive (98/8/EC): Programme for systematic examination of all active substances of biocidal products on the market on May 13, 2000 Article 16(2)
2001 - IRG/WP 01-50166-03
K Rasmussen, A B Payá Pérez
Copper naphthenate performance: A new way to look at old data
2000 - IRG/WP 00-30215
Although copper naphthenate has over a 50-year test history, it is still considered as a "new" preservative in the United States when it is used for utility poles. It has also been extensively used in remedial treatments for poles and has considerable retail or over-the-counter sales. The test history includes a number of different tests and a rationale for evaluating this data and comparing the performance of copper naphthenate to other common pole preservatives is presented. Thus, the efficacy of copper naphthenate can be easily summarized.
C R McIntyre
Boron treatments for the preservation of wood - A review of efficacy data for fungi and termites
1994 - IRG/WP 94-30037
Boron treatments have been used for many decades for protection of timber from biological attack and also as a fire retardant treatment. In recent years there has been an increased interest in boron treatments as an option for protection of structural timbers' e.g. timber framing used in termite risk areas. This paper reviews efficacy data for both fungi and termites relevant to this end-use.
J A Drysdale
A collaborative test to determine the efficacy of polyurethane coatings on wood samples exposed in the marine environment
1984 - IRG/WP 4113
Aims are: a) to determine the effectiveness of elastomeric polyurethane as a protective coating against marine wood boring animals in a range of tropical and tempreate sites; b) to compare the adhesion of polyurthane coatings on different wood species exposed in seawater; c) to record the severity of attack in failed samples and to identify the causal marine organisms.
R A Eaton
A wood preservative for the future: Copper dimethyldithiocarbamate
1994 - IRG/WP 94-30045
The development of a new wood preservative, copper dimethyl-dithiocarbamate (CDDC) is reviewed in this paper. CDDC is formed in situ by dual pressure treatments. Laboratory and field efficacy trials, physical and chemical properties of the preservative solutions and treated wood, and plant handling characteristics of the system are examined.
D K Stokes, M H Freeman, T L Woods, R D Arsenault
The evaluation of synergistic effects of chemicals on fungicidal efficacy in crossed-paper tests
1991 - IRG/WP 2383
The mixing effects of wood preservatives were evaluated using the crossed-paper technique. Two filter paper strips (0.7 x 8 cm²) were treated by soaking with different chemicals [fungicides, a termiticide (chlorpyrifos or phoxim), a surface-active agent, a synergistic agent, and a stabilizer], and placed at right angles to each other on a fully grown mycelial mat of a test fungus in a Petri dish. When the four organoiodine fungicides were incorporated with chlorpyrifos or surface active agent, only 3-iodo-2-propynyl butyl carbamate (IPBC) showed the desirable synergistic effect against every wood-decaying fungus tested. Other fungicides did not always tend to produce the synergistic effect with the addition of a surface active agent. 4-Chlorophenyl-3-iodopropargyl formal (IF-1000) appeared to indicate an undesirable antagonistic effect when mixed with either chlorpyrifos or a surface active agent. 3-Bromo-2, 3 diiodo-2-propenylethyl carbamate (EBIP) did not show any synergistic action by mixing with chlorpyrifos and/or a surface active agent, although the fungicidal enhancement was induced satisfactorily by mixing the fungicide with chlorpyrifos, a stabilizer and/or a synergistic agent, especially against Tyromyces palustris and Coriolus versicolor. Similarity of the results obtained in the present investigation and in the previous laboratory decay tests leads to the conclusion that the crossed-paper technique is suitable for the evaluation of the mixing effect of chemicals on fungicidal efficacy.
Dong-heub Lee, K Tsunoda, M Takahashi
Effect of protective additives on leachability and efficacy of borate treated wood
2002 - IRG/WP 02-30290
Borate preservatives have been used extensively in many countries as an effective means for protecting wood against fungal and insect attack especially in interior environments. Under exterior conditions, borate compounds have a main disadvantage as they can be leached from treated wood as a result of their water solubility. In this study, we compared the potential of different additives for reducing the leachability of boron preservatives from treated wood. Scots pine sapwood (Pinus sylvestris) and poplar (Populus trichocarpa x deltoides) test samples were vacuum treated with 1 % BAE (Boric Acid Equivalent) disodium octaborate tetrahydrate (DOT) solutions containing various additives e.g. glycerol/glyoxal, polyvinylpyrrolidone (PVPY), a commercial resin compound and a commercial water repellent. The European Standard EN 84 was used as a leaching test for both coated and uncoated specimens. The results of chemical analysis of leachates taken at different periods showed that the use of protective additives reduces the boron leachability. The glycerol/glyoxal additive applied to treated pine sapwood showed the best performance. The percent of boron retained in uncoated pine sapwood was 26% while coated samples still retained 45% after 14 days of intense leaching. Similar tests on poplar revealed 19% and 34% for uncoated and coated samples, respectively.This represents a gain of 20 to 25% compared to pure DOT treated specimens of both wood species. Preliminary biological tests were carried out on malt agar using a miniblock technique for uncoated pine sapwood and beech, with Poria placenta and Coriolus versicolor, respectively. After six weeks of exposure to fungal attack all boron protective systems tested proved their effectiveness, as none of the test samples exhibited a mass loss exceeding 4%. The reference 1% BAE without protective additives showed an average mass loss of 15%. Finally, test data are reported of standard EN 113 testing in view of a further evaluation of the biological efficacy of combined DOT-additive treatments.
A Mohareb, J Van Acker, M Stevens
Determination of the preventive efficacy against wood destroying basidiomycetes fungi, EN V 839 - CEN/TC 38 WG 9
1993 - IRG/WP 93-20015
The WG 9 of CEN TC/38 has presented to EC a mycological test to assess efficacy of preservatives applied by surface process. This method is now an experimental standard (EN V 839) which has to be approved by the different european delegations. The following paper is not the standard as it has been proposed but is a presentation of the principle of the method. The experimental standard specifies a laboratory method of test which gives a basis of the assessment of the preventive action of a wood preservative when applied as a surface treatment against Basidiomycetes fungi. This method is applicable to formulations of preservatives in a ready to use form (organic formulations, organic water-dispersible formulations, water-soluble materials). Series of susceptible wood species specimens are treated on longitudinal faces whith the preservative in test using brushing as surface procedure. Test specimens are then exposed by an intermediate mesh to feeder blocks infestedby pure culture of Basidiomycetes fungi in sterile conditions and penetration of fungi is assessed on cross section sawn in the samples at the end of the test.
The Biocidal Products Directive ( 98/8/EC ) - its consequences for the wood preservation industry
2001 - IRG/WP 01-50166-04
1. The Current Position This European Union Directive is one of the most technically complex pieces of legislation that has been developed by the European Commission (EC). Although the Directive was to have been implemented in the legislation of individual Member States of the EU by May 2000 progress has been slow. A number of Member States have yet to declare the Competent Authority who will handle their legislation. The body text of the Directive cannot stand-alone and is dependent on ancillary regulations and the development of technical guidance for both the Competent Authorities in the Member States and also industry to understand their roles in the whole process for the regulation of biocides and the biocidal products containing them. The process is far from complete in terms of a piece of workable legislation and this leaves not only industry but also the Competent Authorities with significant areas of uncertainty. This is potentially economically and socially damaging to the marketing and use of biocides and biocidal products. Because of this evolutionary process this paper can only be written in general terms as by the time the symposium takes place some significant changes to the position at the time of writing may have occurred. 2. Background The Biocidal Products Directive (98/8/EC), (BPD), is a directive which requires that biocides ( as active substances) are approved for use within the EU and the individual biocidal products containing these active substances are approved for use by the Competent Authority(s) of the Member State(s) in which it is intended to market the product. The product authorisation obtained in the first Member State should be mutually recognised by the other Member States in which application for authorisation to place the product on the market is sought. The Directive has to be seen in the context various other Directives, notably the Plant Protection Directive 91/414/EC). Biocidal products are grouped in the directive into twenty three "product types" and wood preservatives are Product Type 8. The intention of the directive is to harmonise the requirements for the placing of biocidal products and active ingredients on the market throughout the EU. EU wide use of so-called Common Principles are intended to be used to assess the dossiers in order to achieve a common approach and eliminate the current situation where individual Member States apply their own particular national approaches and criteria in the assessment and regulation of products . Annex IIA of the directive identifies the data requirements for the active substance and Annex II B for the biocidal product. There are additional data requirements identified in Annexes IIIA and IIIB for each product type reflecting potential for exposure to man and the environment. 3. Entry onto Annex I Any new active substance will require approval before it or any biocidal products including it can be placed on the market. The dossier to be submitted to the EC will have to include additional data and risk assessments for the product types (as defined in the BPD) in which it will be intended to be used. For those active substances that are accepted as being existing substances on the market before May 2000 (say in wood preservatives) these will be ranked and prioritised. This process is being defined in the so-called: Review Regulations. 4. An environmental directive There is no doubt that this Directive has a high environmental content in terms of the data and the associated risk assessments which are to be prepared. The protocols and the end points for some of these data requirements are still being developed. In general the EC considers that modelling exposure using human and environmental exposure scenarios covering the end use of the product is an acceptable approach . Data are required to enable these scenarios to be modelled and risk assessments made. It is necessary that regulators do not make decisions based on hazard assessment alone in the absence of fully worked out and agreed emission scenarios to define exposure levels which generate a realistic worst case risk assessment. Risk is a function of both hazard and exposure. A lot of work has been done in the development of Technical Notes for Guidance intended to help the regulator and the applicant in the submission and the interpretation of the data. Whilst it may be the case that the human toxicity data requirements still leave questions to be answered it is in the environmental aspects part of the regulatory process where there is still much work to be done. The Directive would seem to rely heavily on the development of Pass / Fail criteria in simulation tests. This is a big subject and of key importance to the risk assessment. 5. Wood preservatives ---- a test case Wood preservation has achieved a certain reputation. On the one hand it is said that a prime reason for the development of the Biocidal Products Directive arose from European problems in the regulation of the marketing and use of dangerous substances, notably wood preservatives. On the other hand because wood preservatives have been regulated by a number of Member States for many years it is believed they are well understood. The EC and the Member States also wanted to be seen to have achieved early success in the implementation of the Directive therefore the decision was taken to start, following failings with the speed of progress of the Plant Protection Products Directive, with a product type they knew all about i.e. wood preservatives. There is no doubt that there is a much greater understanding on the exposure scenarios, both human and environmental, for wood preservatives than many other product types. However, would it not have been better to have tackled some of the other product types where such an understanding is much less well developed? It is regrettable that the EC and Member States did not feel able to accept the results of an EC sponsored study (Haskoning report) on the assessment of risks for all the product types covered under the BPD. The results of this study clearly showed that wood preservatives did not constitute the most significant risk to man or the environment and in fact the risk was significantly greater for other product types. 6. Wood preservatives and the OECD Biocides Programme Another speaker will be covering this subject in more detail. Suffice it to say that because of the perception there was good knowledge about wood preservatives again they were selected as the pilot for an OECD project looking at environmental and human exposure assessment under the OECD Biocides Programme. The findings from two OECD Workshops actually demonstrated there was still much to be learnt about wood preservatives in order to refine the risk assessments to a state where they would be sufficient for the requirements of the BPD. This work is ongoing but it clearly demonstrates the problems that both the regulator and industry will have in the preparation and the assessment of the dossiers for both the active substances and the biocidal products. This is especially the case for other biocidal products that have not been subject to the same kind of regulation that wood preservatives have subjected to in the past. 7. Inorganic and organic biocides With current wood preservation technology there is still a dependence on inorganic chemicals such as copper (in conjunction with other biocides) or with chromium, as well as arsenic and boron for many end use applications. This is very much the case where a long term service life is a key factor in the use of treated wood for that end use. These substances are commodity chemicals and are also covered under the Existing Substances Regulations (EC) 1488/94. There is also work going on revising the Technical Notes for Guidance covering them . This includes a significant addition in the environmental risk assessment area. Efforts are being made to integrate and coordinate the requirements for both the BPD and the Existing Substances Regulations and OSPAR ( OSPAR Convention for the Protection of the Marine Environment of the North-East Atlantic). OSPAR refers to the Oslo Paris Convention. Whilst the BPD seems primarily aimed at the regulation of biocides based on organic chemicals wood preservative products may contain both inorganic and organic components. Indeed there are probably few wood preservative formulations on the market that contain only one active substance. This must have a significant impact on the way the dossiers are prepared for the active substance and the biocidal products and how they are assessed both at the EC and the Member State level. 8. Consequences of the BPD for the wood preservation industry Whilst this paper addresses the consequences for the wood preservation industry per se, it must not be overlooked that there may be implications for the fabricaÈors of articles made from treated timber. Some current wood preservative formulations may over a period of time be withdrawn from the market because the risks and costs of generating the data and the preparation of the dossier make the product economically unviable. The presence of large working volumes of wood preservative solutions at treatment plants requires realistic withdrawal periods to avoid the unnecessary disposal and associated environmental risk of products that have been used satisfactorily for many years. 9. Availability of active substances The structure of the industry has changed dramatically in the past few months and there is no doubt that other changes both within and outside the wood preservation industry itself are yet to happen. The original differentiation between formulator of wood preservatives and active substance suppliers to the wood preservation industry has become blurred. Some of the active substances used in wood preservation are used in other either other biocidal product types or in products regulated under another directive, e.g. Plant Protection Products Directive 91/414/EC. 10. Data protection This continues to be a key issue for industry and some companies may find it strategically or financially necessary not to support an active substance in a particular product type thus leaving that sector without being able to use the active substance. The coming months will start to reveal which active substances are likely to be supported, at least through the notification process. Formulators are therefore in a close dialogue with their suppliers to try to determine their intentions on whether or not they intend to support their active substance. Today's wood preservative formulations are largely multi active substance based. Product costs, efficacy spectra, niche marketing and other considerations have made this process inevitable. New wood preservative formulations take time to research and develop and the continuity of availability of a choice of active substances is of key importance. A lack of adequate return on investment necessary to sustain the development of new products could have a negative impact on innovation and the rate of introduction of new products. It is extremely unlikely that any new active substance will be solely developed for use in wood preservation. This would be an effect contrary to expectations of the EC. The situation with wood preservatives is complicated by the fact that treated wood is a construction product and comes under the scope of the Construction Products Directive (89/106/EEC) (CPD). Products under the scope of the CPD are required to meet certain so-called essential requirements and one of these is durability. Demonstration of compliance involves the extensive suite of CEN wood preservative efficacy tests. Even relatively small changes in formulations may require extensive re-testing under the EN 599 regime in some Member States. 11. Task Forces Companies are encouraged by the EC to enter into Task Forces in order to reduce the burden of testing on animals and also to reduce the number of dossiers to be reviewed for each active substance. Ideally, and understandably, the EC would like one dossier per active substance. Parts of the wood preservation industry have been co-operating in Task Forces and much practical experience has been gained. Even closer co-operation will be required and this will enable companies to pool experience and expertise and manage their financial exposure to potentially high regulatory costs by sharing them amongst a larger number of parties. 12. Financial aspects Industry will have to make some best guesses with respect to its investment programmes for supporting its portfolio of products. Formulators and active substance suppliers are likely to group into Task Forces in order to reduce their costs in terms of data generation and the fees likely to be charged at the EU and the Member State level for the assessment of the dossiers. The compilation of the dossiers requires specialist expertise to assist the industrial applicant(s). This is likely to cost in the order of £100,000 per active substance, not including the costs of generating any data. The Rapporteur State's costs for reviewing the dossier is also expected to be of the same order. Clearly these kinds of costs will impact on innovation. An adequate payback must be available to the company to justify this level of investment. 13. Will mutual recognition work? Member States are required to recognise the authorisation of the biocidal product placed on the market in the first Member State when subsequent applications are made to place the product on the market. This is a fundamental principle of the BPD, although there is concern that Member States continue to have enough flexibility to prevent this happening if there are particular concerns in that Member State. Industry very much hopes this will not be the case and that mutual recognition, a fundamental principle of the BPD, will work in practice. 14. Environmental aspects Biocidal products such as wood preservatives are generally applied in controlled situations and not over large areas. Consequently any emissions can be considered to be from discreet sources, such as treated timber or potentially from timber treatment plants. This is in contrast to plant protection products and some other biocidal products that are usually dispersed over a relatively large area. Because of this a lot of work is required to be done to re evaluate how the environmental aspects of biocidal products such as wood preservatives can be assessed in an objective manner. The criteria that define an emission and how the PEC (Predicted Environmental Concentration) for each environmental compartment is determined are critical. The wood preservation industry, through the EWPM (European Wood Preservative Manufacturers Group), has been working with institutes and other interested parties in a co-operation known as the EFG (Environment Focus Group) to progress the development of appropriate methodology. Data will be required for both primary and secondary exposure to treated timber. The protocols for this work are yet to be agreed. This work is being further progressed in the OECD together with input from CEN TC 38 WG27. This co-operation between the OECD and CEN is extremely significant in that it is, I believe, the first time such a co-operation has taken place in the development of an OECD Guideline. If one considers all of the end uses where treated timber may be found carrying out a risk assessment with few guidelines on how it should be done is a very uncertain process for both industry and the regulator. Reliance on so-called expert opinion may be inadequate. 15. Comparative assessment (the substitution principle) This is a process whereby the health safety and environmental properties of acti_u101 ? substances used in the same product type could be compared and those with the most undesirable properties would not be placed on Annex I. Consequently biocidal products containing them would have to be removed from the market. This process is embodied in the BPD but it was initially considered that it would only be applied in the event of problems arising with active substances or products containing them rather than being used as a screening tool early on in the review process for active substances. This area is still an uncertain one with Member States having different interpretations of this principle. It is unfortunate that the wood preservation industry could be used to test out this concept at a European level. The consequences of this principle could be further losses of active substances available to the wood preservative formulators. 16. Substances of concern The BPD is not only concerned with the active substances that are formulated into the biocidal product but also with so-called "substances of concern". These are defined as any substance, other than the active substance, which has the inherent capacity to cause an adverse effect on humans, animals or the environment and is present or is produced in a biocidal product in sufficient concentration to create such an effect. There are significant implications for the formulator of the biocidal product . The formulator may have to submit an extensive dossier containing toxicological and metabolic as well as ecological data on each of the substances of concern when seeking approval for the biocidal product. There may be classes of compounds that become unavailable to the formulator either because of the risks posed by the co-formulant or because the cost of generating data will be uneconomic. 17. The wood preservation Industry's view on the BPD Industry has supported the development of the BPD since its conception in 1989. It is still supportive it but believes that the degree of complexity is disproportionate to the level of risk when it comes to wood preservatives. After all wood preservatives have been regulated for a long time and in reality there have been few significant health safety and environmental problems associated with them. Industry believes there is no need to determine an absolute understanding about a biocide and its application but rather there is a need to determine the level of understanding that will enable characterisation so that a risk assessment can be made. The wood preservation industry has sought either directly or through representative bodies a pro-active and collaborative approach with the regulators although at times this appears to have encouraged inappropriate demands. The regulators have invariably responded positively to this however they may not always understand the burden in both time and resource in having made wood preservatives the test case. Industry hopes that its efforts to be pro-active will be recognised and will be dealt with equitably when considered before the other product types defined in the Biocidal Products Directive.
Water-based wood preservatives for curative treatement of insect-infested spruce constructions
1998 - IRG/WP 98-30171
On laying down sanitation measures for wooden constructions infested by wood boring insects, we must take into account static risks for the construction - and, thus, for the security of the user - as well as risks for humans and environment due to the chemical preservative compounds of the treated wood. Analyses on many roof constructions made with spruce (Picea abies L.) have revealed that Hylotrupes bajulus L. and Anobium punctatum De Geer have not the significance given to them for decennies. That often allows to replace solvant-based with water-based wood preservatives in old buildings, for the protection of humans and environment. Therefore, a method has been developed in Switzerland for testing wood preservatives with delayed curative efficacy against the house longhorn beetle. Like the European Anobium Standard EN 370 this method intends to prevent the emergence of Hylotrupes beetles. Laboratory tests with diverse water-based wood preservatives available on the market in Switzerland have shown that particularly boron and benzoylphenylurea derivatives containing products get a sufficient penetration in the wood and prevent the emergence of the beetles.
E Graf, P Manser, B Lanz
Developing the technical guidance document on data requirements for biocidal products
1998 - IRG/WP 98-50101-02
Finland has been developing a discussion document for EC and the Member States concerning the specified data requirements for 23 biocidal product types, including wood preservatives, and their active substances. This data is required when applying for authorisation for a wood preservative according to the forthcoming Biocides Directive. The data requirements comprise of the core data set, which is common for all product types, and the product type specific additional data sets. The core data set has been outlined in the common position of Biocide Directive adopted by the EU Council and has only been complemented with some technical details. The data required in the additional data set is supplementary to the core data set and it takes into consideration the product type specific properties and direct and indirect human and environmental exposure. At the same time other guides have also been preparing: a guide for risk assessment of active substances by Sweden and a guide for risk assessment of biocidal products by UK. Close cooperation with these projects is an essential part of the preparatory work. After finalizing the draft discussion papers by the end of February 1998 the formal discussion on these will take place with EC and the Member States during 1998. The proposals on the data requirements will be circulated for comments to the EC, the Member States, industry and other interested parties. The final document will be addressed to the authorities and the applicants.
P Karvinen, E Nikunen
The effect of treatment method on CCA efficacy in Corsican pine
1992 - IRG/WP 92-3723
As part of a study into the influence of application method on preservative efficacy Corsican pine (Pinus nigra) samples (50 x 50 x 400 mm³) were treated with a CCA formulation using Bethel, Steam/Bethel or Lowry processes. Full penetration of the preservative at a gross level was confirmed using a copper disclosing reagent. The preservative was allowed to fix and then samples were converted into mini-blocks (30 x 10 x 5 mm³) to produce decay test samples from various locations within the larger samples. After leaching, sets of replicate mini-blocks were exposed to the decay fungi Coniophora puteana FPRL 11E, Coriolus versicolor FPRL 28A, and Chaetomium globosum FPRL S70K. Equivalent sets of leached blocks, were analysed using atomic absorption spectrophotometry to determine preservative concentration and balance. The results of this study have been used to assess the effect of preservative application method on CCA efficacy. They also indicate how treatment method affects the distribution of the active elements of the preservative throughout the treated wood.
P R Newman, R J Murphy
Efficacy of anhydrides as wood protection chemicals - II. Performance against soft rot fungi
1998 - IRG/WP 98-30174
Pine sapwood modified with various anhydrides and with butyl isocyanate was tested for its resistance to soft rot decay. Small stakes were exposed for 20 months in unsterile soil in a fungal cellar test. Wood modified with butyl isocyanate performed better than any of the anhydrides tested, with a threshold level of protection (less than 3% weight loss) at 12% weight percent gain (WPG). Stakes acetylated to 15% WPG did not give complete protection against soft rot. Stakes modified with alkenyl succinic anhydride showed increasing resistance to soft rot with WPG up to about 10% WPG, above which no further improvements were evident. Succinic anhydride and phthalic anhydride treated stakes showed little or no noticeable protection.
S C Forster, M D C Hale, G R Williams
Testing of termiticides in soil by a new laboratory method with regard to Phoxim for replacement of chlorinated hydrocarbons
1986 - IRG/WP 1292
In comparison to chlorinated hydrocarbons insecticides of the compound classes organophosphates, carbamates and pyrethroids were tested according to an earlier described soil-test in the laboratory. The following termite-species were used: Heterotermes indicola, Reticulitermes santonensis and in addition Reticulitermes flavipes, Reticulitermes lucifugus, Reticulitermes speratus and Coptotermes formosanus (Rhinotermitidae). The method gives reliable results. Criteria for evaluation are mortality and penetration of the termites into the treated soil. According to this test organophosphates, specially phoxim, have a good potential to replace chlorinated hydrocarbons.
Efficacy of some extractives from Pinus heartwood for protection of Pinus radiata sapwood against biodeterioration. Part 1: Fungal decay
1995 - IRG/WP 95-30072
Chemical compounds thought to contribute to the natural durability of heartwood of Pinus spp. were either chemically synthesised in the laboratory or extracted from the heartwood of Pinus elliottii or Pinus caribaea. These compounds included the stilbenes, pinosylvin and its mono- and di-methyl ethers, and the flavonoids, pinobanksin and pinocembrin. Small blocks of Pinus radiata sapwood were impregnated with methanolic solutions of pure compounds or heartwood extracts, to a range of retentions extending above and below the concentration of each compound known to occur in the heartwood of Pinus spp.. Fungicidal efficacy of these compounds has been evaluated by exposure of treated blocks to pure cultures of a white and a brown rot, in addition to an unsterile soil test.
M J Kennedy, J A Drysdale, J Brown
A note on testing the efficacy of wood preservatives above ground
1995 - IRG/WP 95-20078
A number of test methods have been used to evaluate the performance of wood preservatives in above ground situations. These have included EN 113 tests following natural exposure weathering (NEWT), L-joint or T-joint tests, lap-joint tests, and decking tests. A new test referred to as the A-frame test has been developed and is under evaluation. This is based on a sandwich-type test in which a thin (3.5 mm) sample is exposed outdoors between two untreated samples on a rack or A-frame. The advantages and disadvantages of these types of tests are discussed in a short note.
G R Williams, J A Drysdale, R F Fox
Effects of timber surface properties and dipping conditions on uptake of antisapstain actives from two aqueous suspensions, and ultimate effects on efficacy against mould and staining organisms
1995 - IRG/WP 95-30073
Green-off-saw rough sawn Pinus elliottii (slash pine) boards were dipped in aqueous suspensions of two antisapstain formulations, and the resultant surface retentions of active ingredients MTC (methylene bisthiocyanate), CTL (chlorothalonil) or TCMTB (2(thiocyanomethylthio)benzothiazole) were monitored by chemical analysis. Surface retentions increased with suspension concentration and surface roughness, and decreased with initial timber moisture content. Dipping time beyond 20 seconds, timber basic density and earlywood content had little effect. Relatively low surface retentions, produced by dipping smoother boards with higher initial moisture contents, provided lower protection against mould and stain during seasoning than higher retentions. Equations describing the effect of surface retention on efficacy were developed for both formulations, and retentions providing complete protection under the conditions of the test were determined.
M J Kennedy, T L Woods