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Oxygen index levels and thermal analysis of wood treated with melamine-formaldehyde-boron combinations
1997 - IRG/WP 97-30135
Melamine formaldehyde (MF) resin was impregnated into scots pine (Pinus sylvestris L.) specimens with aqueous solutions of 5, 10 and 20% concs. Boric acid (BA) and borax (BX) was added to MF resin at the concentration levels of 0.25, 1.00 and 4.70% to each level of resin concs. BA and BX mixture was prepared at the 5:1 (w/w) ratio considering resultant pH of solutions and better fire resistance. U...
M K Yalinkilic, W-Y Su, Z Demirci, E Baysal, M Takahashi, S Ishihara


Borates and their biological applications
1998 - IRG/WP 98-30178
This paper reviews some of the many biological applications of borates. Boron is a ubiquitous element found widely distributed in the environment and is a normal component of a healthy diet. Elemental boron does not exist in nature, but is always found combined with oxygen in compounds called borates. Boron is an essential micronutrient for plants, and there is evidence to suggest that boron is of...
J D Lloyd


A new approach to the maintenance of wooden railway sleepers. (Second report)
1988 - IRG/WP 3492
The microenvironment and micro-ecology of wooden railway sleepers was investigated to assess their condition to determine the necessary treatment, repair and replacement criteria. In this report the efficacy of the secondary preservative treatment with solid boron rods is discussed and the development of an in-situ, nondestructive test method based on the creation and assessment of structural dyna...
W Beauford, P I Morris, A M Brown, D J Dickinson


The influence of boric acid on respiratory quotients and methane production of subterranean termites
1995 - IRG/WP 95-10136
The toxicity of boron compounds to subterranean termites (Reticulitermes lucifugus) was studied by analysing changes in the levels of oxygen uptake respiratory quotients and methane production. Termites were fed with filter paper treated at different levels of boric acid, the RQ was evaluated by constant volume manometry and the methane production by gas chromatography. Results are discussed in re...
L Nunes, D J Dickinson


The benefits to New Zealand of boron salt treatment of Pinus radiata
1992 - IRG/WP 92-3692
The historical reasons for New Zealand adopting boric salt diffusion of Pinus radiata are summarised, and present day processes and their associated costs are given. The biological hazards of using Pinus radiata untreated are then argued, using endemic fungal and insect species as examples, as well as a discussion of the risks from species that may yet be accidentally introduced into the country....
D J Cross


The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures....
P Vinden


The influence of previous anti-blue-stain preservative treatments on the fixation of CC in spruce
1997 - IRG/WP 97-30134
Freshly cut and kiln dried spruce boards were treated with 4 different anti-blue stain preservatives (ABP). After a period of 10 days allowing the samples to dry and fixate, the samples were treated with CC (chromium, copper formulation) using a vacuum pressure cycle. After impregnation the wood was steam fixed. A submersion leaching test showed differences in the leachable quantity of copper and ...
M Van der Zee, W J Homan


Potentialities of protein borates as low-toxic, long-term wood preservatives - Preliminary trials
1999 - IRG/WP 99-30212
Boron compounds are efficient wood preservatives, as well as safe for the mammals and environmentally acceptable. Their natural solubility allows them to treat almost any wood species, but is also the cause of their high depletion from treated timber in outside exposure. In order to reduce this leachability, potentialities of proteinic polymer networks retaining boron within the wood have been inv...
M-F Thévenon, A Pizzi, J P Haluk


The rate of redistribution and loss of leachable preservatives under service conditions
1993 - IRG/WP 93-30026
This paper describes experiments carried out to determine patterns of preservative redistribution and any associated losses which occur when wood containing unfixed water-soluble wood preservatives is exposed to service conditions where leaching is possible. Scots pine sapwood treated with disodium octaborate was used as a model system. Results are recorded and discussed for trials representing pa...
R J Orsler, G E Holland


Examen chimique du traitement de poteaux effectué à St-Michel s/Meurthe
1974 - IRG/WP 337
J Guillemain-Thévenot, C Jacquiot


CCA fixation experiments. Part 1
1989 - IRG/WP 3504
A method of squeezing solution from CCA treated wood that has not been dried at various times after treatment appears to be useful in following the fixation of CCA in wood. Experiments confirm that temperature governs the rate of fixation....
W S McNamara


Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles


CCA Chemistry
1983 - IRG/WP 3268
A Pizzi


Checking of sodium pentachlorophenate fixation in wood
1990 - IRG/WP 3620
In order to estimate the volatilization of sodium pentachlorophenate from treated wood, wood samples treated with pentachlorophenate were analysed after various durations of an EN 73 weathering The results giving no clear evidence of volatilization, treated wood samples were put in a test chamber with precise climatic conditions, the air used in the experiment being analysed. The pentachlorophenat...
M Lamour, H Sageot


Treatment of Douglas fir heartwood with disodium octaborate tetrahydrate (Tim-BorÒ ) to prevent attack by the Formosan subterranean termite
1991 - IRG/WP 1487
Toxicity of disodium octaborate tetrahydrate (Tim-BorÒ) to Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae), and termite feeding on treated Douglas-fir heartwood were evaluated in laboratory and field tests. Feeding on filter papers impregnated with Tim-BorÒ solutions reduced but did not eliminate termite gut protozoan populations. In a forced-feeding laboratory assay, Douglas-fir hear...
M Tamashiro, R T Yamamoto, J K Grace


A fixation model, based on the temperature dependence of CCA-C fixation
2000 - IRG/WP 00-40163
A model was prepared for the fixation of 1% CCA-C in red pine that allows the prediction of extent of fixation based on the temperature history of the treated wood following pressure treatment. The reaction kinetics of the rapid initial reaction and the slower main reaction were characterized using the Van t'Hoff equation. The initial reaction could be represented by a 10th order chemical...
P A Cooper, K M F Kazi, Jianbin Chen, Y T Ung


Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood....
W S McNamara


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


HCB - a new preservative combination for wood pole maintenance
1996 - IRG/WP 96-30122
New combination of heavy creosoted boron (HCB) applied on hardwood and softwood logs at different moisture content revealed successful diffusion of boron in all sapwoods within 7 days and in all sapwoods plus hardwoods within 15 days. The new cost effective paste sterilizes wood through diffusion and suitable for pole maintenance at groundline and above groundline e.g. cut ends, drilled holes, woo...
A K Lahiry


Diffusion of bifluorides and borates from preservative rods in laminated beams
1991 - IRG/WP 3644
Laminated beams from spruce, pine and larch were treated with two preservative rods, based on bifluorides and octaborate respectively. After 3 and 6 months placed in different climates (65% r.h., 100% r.h., water) the diffusion of the active ingredient was measured. After the 6 months period, the diffusion of the bifluorides was, in all species, ca. 5 times larger than the diffusion from octaborat...
H Militz


The variation in electrical resistance in the CCA-treated wood during the fixation
1989 - IRG/WP 3554
The curve commonly used in Scandinavia for describing the fixation period at different temperatures for CCA-impregnated wood is based on investigation by Dahlgren on the pH-variations in a mixture of sawdust and preservative solution. As far as we know there is no such investigation on solid wood. We have therefore measured the electrical resistance in CCA-treated solid wood to see if this will di...
F G Evans, B Nossen


Field Test Results after Nine Years for CCA and ACQ Preservative-treated Wood Fixed in Different Climates
2003 - IRG/WP 03-30303
During assessment of the ground contact stakes in the Norwegian test field, we have frequently found that the first visual rot attack is in the zone of the stakes, where the stakes have been in contact with each other during the fixation. These parts are usually light green, caused by the lack of light during fixation, compared to the rest of the stake surface, which has a darker colour. To inves...
F G Evans


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


Fixation of CCA in Pinus sylvestris after kiln-drying
1990 - IRG/WP 3594
Tanalith C Paste is 98% fixed and Tanalith Oxide C is 99% fixed irrespective of whether treated Pinus sylvestris is kiln or air dried. A schedule suitable for kiln drying of CCA treated Pinus sylvestris is described....
P Warburton, J A Cornfield, D A Lewis, D G Anderson


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