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Effectiveness of wood preservatives by IUFRO's method
1984 - IRG/WP 3305
Pinus elliottii and Eucalyptus saligna stakes treated with 4.9; 6.9; 9.6 and 13.5 kg/m³ of CCA-A, CCA-C and CCB and with 30-50; 60-80; 90-110 and 120-140 kg/m³ of Benzotar and CNSL (cashew-nut shell liquid) were exposed in seven test sites in Sao Paulo State, Brazil. After 4 years it was concluded that the mean useful life of untreated Pinus elliottii stakes was 8 months and of untreated Eucalyp...
G A C Lopez, E S Lepage, O B Neto


Rapid fixation of Chromated Copper Arsenate (CCA) wood preservatives by microwave treatment
2000 - IRG/WP 00-40184
Rapid microwave heating of freshly chromated copper arsenate (CCA) treated timber indicates that rapid preservative fixation is possible within approximately 40 seconds. The leaching of CCA was evaluated using simulated rainfall. Cost analyses indicates that microwave fixation using an on-line conveyor belt fixation process with an output of 4m3/hour using a microwave power supply of 230 kW costs ...
G Torgovnikov, P Vinden, E Mapanda, P R S Cobham


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


EPA’s Current Views on Heavy-Duty Wood Preservative Regulation
2003 - IRG/WP 03-50206
This paper describes the current EPA system for regulating pesticides and wood preservatives. In particular it focuses on the voluntary phase-out of CCA for residential uses after December 30, 2003, which was agreed between the CCA manufacturers and EPA. Even though the EPA reached an agreement with industry to phase out CCA for residential uses, EPA is continuing the most rigorous risk assessmen...
F T Sanders


Biosorption of metals for wood waste effluent clean up
1997 - IRG/WP 97-50090
The common filamentous fungi can sorb metal ions from aqueous solutions. The biosorption of metal ions like copper Cu2+, chromium Cr6+ and arsenic As5+ by dead fungal mycelia was investigated. Two industrial fermentation byproducts are tested: Mucor miehei and Aspergillus oryzae. The adsorption of metal ions depends on parameters such as chemical treatment of fungi before biosorption (acid or basi...
S Legay, G Labat


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Evaluating the performance of wood preservatives against fungi
1974 - IRG/WP 247
A compilation is made of results published by various workers for agar/block laboratory tests of the effectiveness of wood preservatives against 11 species of wood destroying Basidiomycetes and one species of soft rot fungus. Preservatives include creosote, boron, metal/arsenic mixtures, metallic naphthenates, chlorinated naphthalene, chlorinated phenols and tri-n-butyl tin oxide. The results are ...
R Cockcroft


Working plan: Second international collaborative field trial
1995 - IRG/WP 95-20056
This paper describes the scope, objectives, and approaches to be used in the second international collaborative field trial approved by the Scientific Programme Committee for partial funding in 1994. The trial is designed to develop a broad data base on causal mechanisms, interactions, and factor affecting the performance of treated wood in ground contact. The trial encompasses 12 different field ...
H M Barnes, T L Amburgey


International comparison of three field methods for assessing the in-ground resistance of preservative-treated and untreated wood to termites and fungal decay – Summary of observations after five years
2003 - IRG/WP 03-20261
Results are presented from a five-year study conducted in five locations in Australia, Thailand and the USA. Three methods of exposure were assessed (below-ground, graveyard and ground contact) for evaluating the in-ground termite and decay resistance of Pinus radiata D. Don sapwood stakes that had been vacuum pressure impregnated with CCA (Type C) and ACQ (Type D) each at two nominal retentions (...
M Lenz, J W Creffield, T A Evans, B M Kard, C Vongkaluang, Y Sornnuwat, A F Preston


Determination of fungitoxic value of preservatives in laboratory wood-block tests. Part 2: Statistical estimation
1989 - IRG/WP 2327
Laboratory modified agar-block tests were made to determine the fungitoxic value of the wood preservative CCA against the test fungus Serpula lacrymans using statistical methods. With the aid of statistical computer programmes based on the least square method. the regression equation was found for the dependence between sample mass loss and preservative retention both in terms of percentage and fo...
J Wazny, J D Thornton, K J Krajewski


Surface characteristics of wood treated with various AAC, ACQ and CCA formulations after weathering
1991 - IRG/WP 2369
Wood samples treated with various alkylammonium compounds (AACs) as well as ammoniacal copper quat (ACQ) and chromated copper arsenate (CCA) have been studied in accelerated weathering experiments. Microscopic examination of the surfaces of these samples after exposure in a weatherometer revealed several different changes. Samples treated with didecyldimethyl ammonium chloride (DDAC) show consider...
L Jin, K J Archer, A F Preston


Determination of fungitoxic value of preservatives in laboratory wood-block tests. Part 1: Standard procedures
1989 - IRG/WP 2326
By applying a modified agar-block method, a comparative analysis was made on the toxic value of the wood preservative CCA against the test fungus Serpula lacrymans. The procedure applied to determine the results accounted for different standards: EN (Toxic limit), ASTM (threshold retention), GOST (threshold retention and protection probability), PN (toxic doses) and JIS (value of efficiency). Desp...
J Wazny, J D Thornton


Protection and efficient utilization of plantation grown lesser-known timbers of arid region in India - Acacia tortilis, Prosopis juliflora and Prosopis cineraria
2005 - IRG/WP 05-40321
The plantation-grown timbers are highly susceptible to insects/pests, borers and wood rot fungus. Wood preservatives copper chrome arsenic (CCA) 2% and chloropyriphos 2% solution treated under pressure on three plantation grown timber species viz. Acacia tortilis, Prosopis juliflora and Prosopis cineraria have shown encouraging results in enhancement of shelf life by protection of wood against woo...
S H Jain, H Kumar, R Arya, R L Srivastava


Five years field test results for CCA and ACQ preservatives fixed in different climates
1999 - IRG/WP 99-30208
During assessment of the ground contact stakes in the Norwegian test field, we have found that very often the first visual rot attack is in the zone of the stakes were the stakes have been in contact with each other during the fixation. These parts are usually light green, caused by the lack of light during fixation, compared to the rest of the stake surface, which has a darker colour. To investig...
F G Evans


Inter-laboratory comparison of assessment methods for wood preservatives against subterranean termites: Determination of protection threshold limits for CCA
1999 - IRG/WP 99-10317
In 1996, several institutes conducted laboratory bioassays on the efficacy of unleached Pinus radiata specimens treated with copper-chromium-arsenic (CCA) and copper naphthenate (Cu Naph) at retentions of 0.5, 1.0, 2.0 and 4.0 kg/m3 (total salt for CCA; elemental copper for Cu Naph) against a range of species of subterranean termites (IRG/WP/96-10174). Each participant employed the standard test m...
J W Creffield, M Lenz


Field test of wood preservatives with Nasutitermes rippertii RAMBUR in Cuba
1996 - IRG/WP 96-10181
A field test of wood preservatives was carried out with Nasutitermes rippertii RAMBUR in the vicinity of the Material Testing Centre „Alexander von Humboldt" in Santiago de las Vegas/ Havana (Cuba) for 12 and 24 months. Test specimens of Pinus sylvestris L., Picea abies (L.) Karst. and Fagus sylvatica L. with dimensions of 25 x 25 x 490 mm³ were arranged vertically or horizontally in a circle o...
W Unger


Influence of water-borne preservatives on water repellency and the impact of addition of water repellent additives
1992 - IRG/WP 92-3704
The primary goal of a desirable wood preservative system is to effectively control decay fungi and other biodeteriogens in service. The water repellent nature of a given system may play an important role in the protection of wood. In this study, the water repellency of several water-borne preservative systems has been evaluated by measurements of tangential swelling during immersion. The systems i...
L Jin, D M Roberts, A F Preston


Technologies for the Management of Wood Waste Containing Metals-Based Preservatives
2005 - IRG/WP 05-50224-16
Disposal of the metals from preservative treated wood can occur through two general strategies: “removal and confinement” or “dilution”. The acceptability of each of these two choices is typically dictated through the disposal regulations of a particular region. A considerable amount of research has been conducted to develop new and innovative “removal and confinement” technologies...
H M Solo-Gabriele, T G Townsend


Wood preservatives treatment of black spruce
1997 - IRG/WP 97-40092
A representative sample of black spruce logs from Central Newfoundland was harvested and processed to dressed 2"x4" lumber. Over 400 pieces of lumber were then incised and treated with ACQ preservative in a semi-industrial retort. 9 charges of 20 samples were used to determine treating parameters and 11 charges of 20 pieces were treated using the optimized process. This material was inspected by a...
A R Zahora, J P Hösli


Determination of toxicity data for preservatives against Basidiomycetes by measuring the reduction in compression strength of wood
1988 - IRG/WP 2297
Blocks of Pinus radiata D. Don were treated to 12 retention levels with CCA and NaPCP. These were exposed for 12 weeks in agar jars to the dry rot (brown rot) Serpula lacrymans (Schum. ex Fr.) S.F. Gray. After mass loss determination, the same blocks were tested for reduction in compression strength parallel to the grain. Using both these parameters, together with interpolated 6 week strength loss...
J Wazny, J D Thornton


The resistance of timbers to impregnation with wood preservatives
1979 - IRG/WP 3137
It is anatomical structure which determines liquid flow rate within different timber species. This cannot be deduced from properties such as density or rate of growth, and can only be found by experiment. A standard test has been in use at the Princes Risborough Laboratory for many years, employing a pressure-impregnation treatment, and a large number of timbers have been studied. The test consist...
Anonymous


Less pollution due to technical approaches on accelerated steam fixation of chromated wood preservatives
1988 - IRG/WP 3487
Steaming of freshly treated wood at 100°C to 120°C initiates a spontaneous fixation of copper-chromate-containing wood preservatives. For the performance, a suitable anticorrosive equipment is necessary. Good results can be achieved using a separate steaming equipment which allows a rapid heating of the wood. While warming-up, in the wood some preservative solution extends and can be partly extr...
H Willeitner, R-D Peek


Effectiveness of wood preservatives and treatments against marine borers in Philippine waters
1976 - IRG/WP 416
A 5-year exposure test was conducted on the effectiveness of wood preservatives and treatments against marine borers in Philippine waters. Air-dried heartwood samples of apitong (Dipterocarpus grandiflorus) 76.2 x 88.9 x 609.6 mm³ (3 x 3.5 x 24 in³) in size were pressure treated with coal tar creosote and two types of CCA (copper/chrome/arsenic) and CuCZA (copperized chromated zinc arsenate) wat...
F R Siriban, M G Laxamana, P G Mata


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


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