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Treatment application method and CCA efficacy in Corsican pine - Assessment by serial exposure and soil burial tests
1993 - IRG/WP 93-40006
A previous report on this research (Newman and Murphy, 1992) identified possible variation in the efficacy of a CCA preservative applied to Corsican pine (Pinus nigra var. maritima) dependant upon the treatment application method (Bethel, Lowry or Steam/Bethel). This paper presents further data from biological testing of CCA treated Corsican pine using serial exposure and unsterile soil techniques...
P R Newman, R J Murphy


Losses of CCA components and creosote from treated timber to soil
1997 - IRG/WP 97-50098
Components of creosote and CCA preservatives can migrate within the wood and move into surrounding soil. However, at present, the ecological significance of such losses is uncertain. This paper examines the distribution of four target polyaromatic hydrocarbons (PAHs ) and of copper, chromium and arsenic in treated stakes and surrounding soil after long term exposure in field trials. Concentrations...
N J Hudson, R J Murphy


Remediation of a large CCA-impregnation plant
1998 - IRG/WP 98-50101-13
During 1949-85 the Swedish Telecom ran a plant for pressure impregnation of poles in Hjältevad, 80 km east of Jönköping in the southern part of Sweden. About one million poles were treated with CCA-preservaties. Leaks and accidential spills have contaminated soil and groundwater within the 5 ha large site. The total amount of released arsenic, the main pollutant, is estimated to 6-7 metric tons...
P Englöv


Comparison of performance of wood preservatives in laboratory and field tests of treated commodities
1993 - IRG/WP 93-20010
The purpose of laboratory tests for evaluating efficacy of wood preservatives is usually to establish toxic values against standard strains of wood decay fungi. Exposure conditions are usually chosen as optimal for fungal growth. Toxic values so determined serve as a guide as to expected performance of the preservative in field stake tests or in above ground exposure tests. Test material is select...
M E Hedley


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Patterns of decay in CCA-treated horticultural post populations - A fungus cellar simulation
1986 - IRG/WP 1286
The distribution of decayed posts in 10-, 14-, and 18-year-old vineyards supported a hypothesis to explain variability in intensity of decay found among posts in New Zealand horticultural properties. The development of decay patterns between samples in a simulated vineyard plot established in the Forest Research Institute fungus cellar gave additional support to the hypothesis that decay within la...
M E Hedley


Lab and field test results for wood treated with polymeric alkylphenol polysulfide
2001 - IRG/WP 01-30268
A new wood preservative based on polymeric alkyphenol polysulfide (PXTS-A) is being evaluated in a series of laboratory and field tests and the results continue to show promise. A modified formulation (PXTS-B), which contains additives to reduce the viscosity, is being evaluated along with the original formulation. Soil block decay tests comparing PXTS-B with CCA-C indicate that PXTS-B is equally ...
J Goswami, A Abramson, R Buff, D D Nicholas, T Schultz


Laboratory studies of CCA-C-leaching: influence of wood and soil properties on extent of arsenic and copper depletion
2002 - IRG/WP 02-50186
The extent which a wood preservative leaches is important for efficacy studies and environmental concerns. However, little information exists on the effect soil properties have on leaching. This study investigated leaching of stakelets which had been cut from five different southern yellow pine (SYP) sapwood boards then treated with CCA-C to a target retention of 6.4 kgm-3 (0.4 pcf). All stakel...
D Crawford, R F Fox, D P Kamden, S T Lebow, D D Nicholas, D Pettry, T Schultz, L Sites, R J Ziobro


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Remediation of a site contaminated with creosote and CCA - a case study
1998 - IRG/WP 98-50101-12
Over sixty years of wood preservation activity conducted by ImpregNor at Ilseng, Norway, has caused serious contamination of the soil. High concentrations of creosote have been found at two separate sites, one in connection to the creosote wood preservation plant, and one further downstream were residues from the creosote preservation have been deposited. High levels of chromium, copper and arseni...
T Rødsand, K Hellum, H Lillemaehlum


Which substrate to use in a laboratory test with soft rot micro-fungi: vermiculite or unsterile soil?
1991 - IRG/WP 2372
A draft European Standard is being proposed by CEN TC 38 in which a vermiculite-burial and a soil-burial test to be carried out in succession are required. Various experiments with both procedures were set up with CCA, CC and propiconazole-formulations. The results show that vermiculite and unsterile soil yield comparable threshold values against soft rot. This poses the question of whether a two-...
A R Valcke


The efficacy of polymer/preservative treatments in soil-bed exposure
1992 - IRG/WP 92-3729
Southern pine was treated with CCA, CCB, sodium borax/boric acid, or disodiumoctaborate, alone or in combination with an acrylic polymer system containing a water repellent. Treated samples were subjected to an unsterile soil burial test. The addition of polymer reduced the weight loss in borontreated samples at the lower retentions but not at the higher retention. Results with borates indicate th...
R J Murphy, H M Barnes, S M Gray


Use of compression strength loss for measuring decay in the soil block test
1996 - IRG/WP 96-20083
The possibility of using radial direction compression strength of wood, rather than mass loss, was evaluated for both a brown-rot fungus (Gloeophyllum trabeum) and white-rot fungus (Trametes versicolor). With untreated pine wafers (5 x 19 x 19 mm³ - l x r x t) exposed to Gloeophyllum trabeum in a soil block test for five days, the compression strength loss was nearly 50% compared to a 5% mass los...
D D Nicholas, Zhongwei Jin


Mobility and bioavailability of wood preservation chemicals in soil - actual field measurements
1998 - IRG/WP 98-50101-11
Wood material intended for outdoor use is often impregnated with chemicals to withstand attack from fungi and bacteria. Both inorganic and organic substances are used to protect the wood, and they are used in a toxic and bioavailable form. At wood preservation facilities severe soil contamination can be encountered due to spills and deposition of sludge, especially at old sites. Two sites, one whe...
S Andersen, G Rasmussen


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


The performance of chlorothalonil after 4.5 years in the accelerated field simulator
1994 - IRG/WP 94-30041
The decay resistance of chlorothalonil in oil was examined in an accelerated field simulator (AFS). Pinus radiata D. Don and Eucalyptus regnans F. Muell. sapwood stakes were treated, placed in soil in the AFS, and monitored over 4.5 years. CCA type C treated stakes were included for comparison. Water and toluene treated control stakes were heavily decayed after 1-2.5 years. Oil treated controls, t...
L J Cookson


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Working plan: Second international collaborative field trial
1995 - IRG/WP 95-20056
This paper describes the scope, objectives, and approaches to be used in the second international collaborative field trial approved by the Scientific Programme Committee for partial funding in 1994. The trial is designed to develop a broad data base on causal mechanisms, interactions, and factor affecting the performance of treated wood in ground contact. The trial encompasses 12 different field ...
H M Barnes, T L Amburgey


The effect of aqueous leaching on moisture uptake by CCA-treated blocks during soil burial
1987 - IRG/WP 2283
Mass loss, moisture content and nitrogen data from two soil burial experiments with untreated and CCA-treated Scots pine (Pinus sylvestris L.), Sitka spruce (Picea sitchensis Carr) and lime (Tilia vulgaris Hayne) are presented. These show that aqueous leaching of CCA-treated wood prior to burial significantly reduces its subsequent moisture uptake from soil. In the case of lime, a reduction in the...
C A Green, G M Smith, B King


Effects of soil physical and chemical characteristics on adsorption of leached CCA and ACQ preservative components
2003 - IRG/WP 03-50200
The objective of this study was to examine the effect of soil characteristics on adsorption of wood preservative components from CCA and ACQ preservative systems. Adsorption of leached CCA and ACQ preservative components in soils with different characteristics were studied. Three soils (clay, sandy and organic) were investigated using different concentrations of leach water of CCA and ACQ wood pr...
S Stefanovic, P A Cooper


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Soft rot tests with soils of different origins
1984 - IRG/WP 2226
In the BAM a comparative soft rot test with 9 different types of soil (one soil each from Canada, New Zealand and Switzerland and 6 soils from laboratories in Germany) were carried out. The pH values of the different soils ranged from 3.2 to 7.1, and the amounts of organic matter were between 4 and 44% (w/w). The test specimens - Pine sapwood blocks treated with different concentrations of a CCA p...
M Gersonde, W Kerner


Effect of test methodology on seed germination using filter paper and soil as substrates
1994 - IRG/WP 94-50029
Tomato, cucumber and grass seeds were used to examine the influence ot two wood preservatives, chromated copper arsenate (CCA type C) and ammoniacal copper quat (ACQ tvpe B) in seed germination studies. Two methodologies, using contaminated filter paper and contaminated soil as substrates, were investigated to generate the comparison results. The results from these studies suggest that the test su...
L Jin, A F Preston


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