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The decay resistance of chemically modified aspen composites to the white rot fungus Coriolus versicolor (L.) Quelet
1998 - IRG/WP 98-40122
Chemical modification of Aspen wood (Populus tremula L.) in the form of solid wood, veneers and sawdust was undertaken by a two step procedure consisting of esterification with maleic anhydride (MA) and subsequent oligoesterification with MA and glycidyl methacrylate (GMA) or allyl glycidyl ether (AGE). Modified wood was thermoplastic and was thermally formed by hot-pressing to produce veneer or s...
M C Timar, A J Pitman, M D Mihai


About the water and biological resistance of some new chemically modified wood composites
1997 - IRG/WP 97-40077
As well known, wood represents a valuable natural composite material with a very large utilisation as solid wood or in wood based composite materials. Its qualities but also its defects as the dimensional instability, the susceptibility to biological attack, the anisotropy, are due to its complex structure. Research has demonstrated that the chemical modification of wood, meaning the involving of ...
M C Timar, M D Mihai, G Baciu


Termite field test results of preservative treated and modified woods in Kumamoto, Japan
2001 - IRG/WP 01-30275
Various preservative treated or modified wood stakes other than CCA, were buried in the soil, maximum for six years in Kumamoto, south west side of Japan. In this area, two main termite species, Coptotermes formosanus and Reticulitermes speratus, are distributed. After two years in field, untreated sapwood of sugi (Cryptomeria japonica) were observed severe attacks by termites, but the preservativ...
K Suzuki


Results on field stake tests against termite – Maximum for 8 years examination at Kumamoto in Japan
2003 - IRG/WP 03-10463
Various preservative treated or modified wood and charcoal painting stakes were tested in field, maximum for eight years in Kumamoto, distributed two main termite species, Coptotermes formosanus and Reticulitermes speratus. After two years in field, untreated sapwood of sugi (Cryptomeria japonica) were observed severe attacks by termites, but the preservative treated stakes were observed no signif...
K Suzuki


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Moisture and Fungal Durability of Wood-Plastic Composites Made With Chemically Modified and Treated Wood Flour
2013 - IRG/WP 13-40648
Evaluating the fungal durability of wood-plastic composites (WPCs) is complicated by the influence of slow moisture sorption. Recently, the American Wood Protection Association (AWPA) Standard Method E10, Testing Wood Preservatives by Laboratory Soil-Block Cultures, was modified to incorporate not only solid wood, but also wood-based composites and WPCs. To simulate long term WPC performance, cond...
B K Segerholm, R E Ibach


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Adhesion and performance of exterior wood coatings on chemically and thermally modified wood – Results from 5.5 years outdoor exposure
2023 - IRG/WP 23-40964
Non-durable softwood and hardwood species were treated with the water-soluble cyclic N-methylol compounds 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) and methylated DMDHEU. One half of the modified specimens were coated with a waterborne acrylic coating system prior a natural weathering for 5.5 years according to EN 927-3 (2020). By frequent evaluations, the impact of chemical modifications ...
L Emmerich, H Militz


Durability of pine modified by 9 different methods
2004 - IRG/WP 04-40288
The decay resistance was studied for pine modified by nine methods of wood modification: 1) Acetylation, 2) Treatment with methylated melamine resin (MMF), 3) Acetylation followed by post-treatment with MMF-resin, 4) Thermal modification, 5) Furfurylation, 6) Maleoylation (using water solution of MG or ethanol solution of maleic anhydride), 7) Succinylation, 8) NMA-modification and 9) modification...
M Westin, A O Rapp, T Nilsson


Changed susceptibility of the chemically and thermally degraded spruce wood to its attack by the dry rot fungus Serpula lacrymans
1999 - IRG/WP 99-10322
In buildings, some intentional or unintended situations can occur at which some wood products are exposed to aggressive chemicals and also to higher temperatures. Occasional activity of fungi on such pre-attacked wood products can be either higher or lower. This paper deals with changes in the susceptibility of spruce wood (Picea abies L. Karst.) to attack by the dry rot fungus Serpula lacrymans, ...
L Reinprecht


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


Decay resistance of high performance biocomposites based on chemically modified fibres
1998 - IRG/WP 98-40120
Different partners within the framework of a European research project produced high performance biocomposites aiming at the utilisation of board materials as durable products both in dimensional and biological degrading circumstances. This paper summarises test data, which indicate the potential of board materials produced with modified fibre material. The chemical modifications applied cover a r...
V Rijckaert, J Van Acker, M Stevens


Leachability of borate-modified oriented strandboard: A comparison of zinc and calcium borate
2002 - IRG/WP 02-40232
The leachability of boron in zinc and calcium borate-modified oriented strandboard (OSB) was investigated in this study. The leaching experiments were conducted by exposing edge-sealed OSB samples under running water for 8, 24, 72, and 216 hours. The results were compared with those from the unleached controls. Boron leaching of the modified OSB occurred upon the initial water exposure, and the le...
S Lee, Q Wu


Evaluating the potential of modified wood for use in marine environments using a short-term laboratory bioassay
2004 - IRG/WP 04-10525
Chemically modified wood may be an alternative to preservative treated timber for marine structures. In this study a screening laboratory test using the wood-boring isopod crustacean Limnoria quadripunctata was used to assess the durability of chemically modified Pinus sylvestris, Pinus radiata and Picea sp. Most of the treatments used a combination of one of two of types of the resin dimethyloldi...
L M S Borges, S M Cragg, M van der Zee


The dry rot fungus Serpula lacrymans, its growth and damaging of wood
2004 - IRG/WP 04-10511
The dry rot fungus (Serpula lacrymans) is one of the most dangerous wood rotting fungi, especially in the built environment. In our mycological laboratory more experiments with this fungus have been carried out aimed at:- its growth under stable and variable climatic conditions, - its possibility to attack either natural wood of different species and also modified wood primary pre-treated with ...
L Reinprecht


Microscopical analysis of formaldehyde-acid modified wood
1981 - IRG/WP 3182
Cross-linking of wood with gaseous formaldehyde improves its hygroscopic and dimensional behaviour, and its resistance against micro-organisms. However, formaldehyde cross-linking reactions take place only in the presence of an acid catalyst, which results in losses in mechanical By optimization of a formaldehyde-sulfur dioxide vapour phase process the reaction conditions were established to limit...
M Stevens, N Parameswaran


Prediction of Weight Percent Gain (WPG) of furfurylated wood by FT-NIR spectroscopy
2004 - IRG/WP 04-20295
Wood modification based on furfuryl alcohol improves several important wood properties, such as the resistance to fungal decay and insect attack, hardness, dimensional stability, bending strength and stiffness. The improvements of wood properties depend on the weight percent gain (WPG) due to furfurylation. Fourier transform near infrared (FT-NIR) spectroscopy was used to calibrate PLS-regression ...
M Eikenes, P O Flæte, E Ystrøm Haartveit, S Lande


A modified method to determine the toxic values of chemicals against Lyctus africanus (Lesne) by larval transfer method (laboratory method)
2005 - IRG/WP 05-20309
Lyctus africanus (Lesne) is the commonest species widely distributed by trade throughout India. It is one of the most important insect pest attacking logs, branchwood and and practically every kind of manufactured wooden article that contains sapwood. Presently, in India many short rotation and alternate timbers are being used for making many finished products .The inclusion of sapwood containin...
R Muthukrishnan, O K Remadevi


Improvement of some technological and biological properties of poplar wood by impregnation with aqueous macromolecular compounds
1992 - IRG/WP 92-3721
Poplars (Populus spp) belong to the most important tree species in afforestation programs of the Netherlands. Due to their rapid growth, the wood quality is usually low. Therefore, studies were performed to elucidate whether some technological properties and the resistance against fungal attack could be improved by impregnation with water-soluble resins. The results showed that swelling and shrink...
R D Peek, H Militz, J J Kettenis


Protection of rubberwood with modified creosote
1998 - IRG/WP 98-30165
Creosote is a renowned wood preservative but has certain disadvantages like obnoxius odour and colour, with its unpaintability and bleeding from wood surface may create environmental hazards. An effort has been made to isolate chemical fractions from creosote to obtain clean odourless preservative formulations by subjecting to steam distillation (SVC). Rubberwood treated with SVC and tested for it...
H C Nagaveni, H S Ananthapadmanabha, G Vijayalakshmi, M N Sharma, K H Shankaranarayana


Influence of concentration, catalyst, and temperature on dimensional stability of DMDHEU modified scots pine
1998 - IRG/WP 98-40119
Dimethyloldihydroxyethyleneurea (DMDHEU) is being used in textile industry to improve wrinkle recovery. Trials on solid wood have been performed to minimise swelling of the wood. This paper focuses on the effect of various types and concentrations of catalyst and reaction temperature on the dimensional stability of Scots pine. Three different catalysts, NKS (based on magnesium chloride), 3282 (bas...
M Van der Zee, E P J Beckers, H Militz


Modified Wood – Methods, testing and applications: Outcomes of the EU-Thematic Network
2003 - IRG/WP 03-40268
In the last decade, interest in the development of wood modification systems has increased in Europe. Alongside several industrial initiatives for heat treatments, there have also been scaling up and pilot plant projects for chemical wood modification. Between 2000 and 2003, the European Commission funded the "Thematic Network on Wood Modification". This paper will feature the modification process...
D Jones, W Homan, J Van Acker


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