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Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


State of the art of industrial wood protection in Portugal
2016 - IRG/WP 16-30703
This work intended to give a perspective of industrial wood protection in Portugal. A survey was made of the companies treating wood mainly for use classes 3 and 4 such as autoclave treatments with biocides and wood modification procedures. Currently there are 23 companies with 33 production plants with an autoclave installed for wood preservation by impregnation. There are also two companies prod...
L Nunes, J Carmo, J Vicente, B Esteves


10 year Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2017 - IRG/WP 17-30718
A round robin involving 15 European participants was set up in 2006. The round robin consisted of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. The laboratory test results were reported in an earlier IRG paper (IRG/WP13-20535) but are included also in this paper in order to facilitate the comparison with the field test...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, E Melcher, R Moeller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


COST FP 1303 Cooperative Performance Test – Results after two years outdoor exposure
2017 - IRG/WP 17-20620
COST Action FP 1303 ‘Performance of Bio-Based Building Materials’ started in October 2013 and an ambitious program was set up for four years. Among this a collaborative field test was planned. The idea of the cooperative performance test was to distribute a fairly simple test set up to as many places in Europe as possible in order to collect performance data reflecting the full range of climat...
B Lesar, M Humar, C Brischke, L Meyer-Veltrup, D Jones, N Thaler, J M Abascal, G Alfredsen, B Brunnhuber, E Grodås, M Irle, J Kers, M Klamer, K-C Mahnert, E Melcher, S Palanti, M Noël, E Suttie, N Pfabigan, M Touza


New Standards for Approval of Modified Wood within the Nordic Wood Preservation Council (NWPC)
2017 - IRG/WP 17-20624
In the Nordic countries, there is a long tradition for quality labelling of preservative treated wood. Until now the labelling has been restricted to pine and other easy to treat wood species, but with the introduction of a new set of standards it is now possible to obtain the Nordic Wood Preservation Council’s (NWPC) quality labelling also for modified wood. In this paper, we will introduce th...
N Morsing, E Engelund Thybring, M Klamer


Commercialisation of DMDHEU Modified Wood in Australasia
2017 - IRG/WP 17-40772
While there is an increasing volume of data for the impregnation and curing of timber using dimethylol dihydroxyethyleneurea (DMDHEU) on species such as Scots Pine, Beech, Slash Pine and Spotted gum, there is limited information available on the impact of the modification process on the performance of Pinus radiata (referred to hence forth as Radiata pine). The variability within material and spec...
B R Derham, T Singh, H Militz


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


Studying Weathering Performance of Coatings on Thermally Modified Wood
2017 - IRG/WP 17-40805
Thermal modification and degree of improved properties depends on wood species and treatment parameters. Southern pine and spruce are the two common wood species for decking, fences and siding in North America. This study was the first to evaluate coating performance when applied on oil-heat-treated southern pine and spruce wood samples. Water uptake, colour and gloss changes of samples were analy...
M Nejad, M Dadbin, P Cooper


Decay resistance variability of European wood species thermally modified by industrial process
2017 - IRG/WP 17-40807
Thermal modification is now considered as a new ecofriendly industrial wood modification process improving mainly the material decay resistance and its dimensional stability. Most industrial thermal treatment processes use convection heat transfer which induces sometimes heterogeneous treatment temperature propagation within the oven and lead to the heterogeneity in treatment efficiency. Thus, it ...
K Candelier, L Pignolet, S Lotte, A Guyot, E Cuny, B Bousseau, M-F Thévenon


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Aesthetic changes of coated thermally modified wood after artificial weathering
2017 - IRG/WP 17-40819
The thermal modification process affects the chemical configuration of the wood matrix improving some physical properties and durability. In addition, the distinctive dark tones of thermally modified timber increase the economic value of several light-coloured species. However, heat-treatment alters the substrates and it could influence in the application of coating products, necessaries to mainta...
R Herrera, J Sandak, E Robles, J Labidi


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo


Hydroxyl accessibility - A brief review of deuterium exchange studies on modified wood
2019 - IRG/WP 19-20656
Wood modification imparts dimensional stability and decay resistance. The mechanism(s) by which this occurs are thought to be related to the bulking of the wood cell wall and subsequent moisture exclusion. Hence, quantification of accessible hydroxyl (OH) groups is of great interest when evaluating and increasing the understanding of the performance of modified wood. The aim of this study was to b...
G Beck, C Hill, G Alfredsen


Durability classification of preservative treated and modified wood
2019 - IRG/WP 19-20659
EN 350 (2016) allows formally to determine durability classes (DC) for wood products and wood-based materials, which was previously only possible for untreated wood in the form of natural durability. In a first study, the University of Goettingen carried out the durability classification of chemically modified (modified with 1,3-dimethylol-4,5-dihydroxyethyleneurea, DMDHEU) and preservative-treate...
S Bollmus, L Bachle, C Brischke, H Militz


Performance of modified wood in service - multi-sensor data fusion and its multi-way analysis
2019 - IRG/WP 19-20660
Recent developments in the field of electronic sensors and analytics provide new opportunity for accurate characterization of materials often based on portable and non-destructive methods. By using several complementary techniques, the material description is precise and complete. The data provided by multiple equipment, however, are often not directly comparable due to different resolution, sensi...
A Sandak, J Sandak, M Cocchi


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


The anti-weathering mechanism of extractives in thermally modified Scots pine
2019 - IRG/WP 19-40880
Results from the electron spin-resonance spectroscopy (ESR) analysis indicated that thermally modification of wood can inhibit the generation of phenoxyl radicals during UV irradiation and consequently lead to the increase of the color stability of wood. In order to clarify the evolution and role of extractives in thermally modified wood during the process of weathering, the compositions of aceton...
H Shen, J Cao


Studying amount, location and state of water in modified wood at moisture levels relevant for fungal degradation
2020 - IRG/WP 20-40889
Water is an essential parameter for fungal degradation of wood, but degradation primarily occurs at high moisture levels at water potential in the range of -4 to -0.1 MPa, which corresponds to 97-99.9% relative humidity. At these moisture levels, water is present in the wood structure both in and outside of cell walls. The majority of previous studies on the interaction between wood and water for ...
M Fredriksson, E Engelund Thybring, Ramunas Digaitis


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


Development of procedures for sampling, testing, and classification to determine the biological durability of wood and wood products
2020 - IRG/WP 20-20676
This paper informs about a research project, which deals with several shortcomings and a lack of clarity within EN 350:2016. The project started in January 2020, will run for 3 years, and is operated by the Institute of Wood Technology Dresden (IHD) and the University of Goettingen (UGOE). Determination and classification of durability of wood and wood products against wood-destroying organisms ...
W Scheiding, K Jacobs, S Bollmus, C Brischke


NewSiest-Enhancement of UV stability of thermally modified wood through envelope impregnation with nanobased stabilisers
2020 - IRG/WP 20-40909
Thermal modification is a process which improves the properties of wood, resulting in a material that can be disposed at the end of the product life cycle without presenting an environmental hazard. Thermally modified wood retains as a natural product and the grain, original colour variances and characteristics of wood are still present. However, exposure to daylight causes brightening or greying ...
K Srinivasa, M Petrič


Performance of resin-treated solid wood and laminated veneer lumber (LVL) under marine conditions
2021 - IRG/WP 21-10973
Wood is a traditional building material in the marine environment, where it is exposed to extremely harsh conditions. Most of the indigenous softwood and hardwood species in Europe are not durable against attack by marine organisms. Recently, wood modification has been considered as an alternative to protect non-durable wood species under use class (UC) 5 (EN 335, 2013) conditions. The present stu...
L Emmerich, C Brischke, S Bicke, H Militz


Experience Experience from over 20 years of field trials of resin treated wood – Marine borer resistance of MMF and DMDHEU modified wood
2021 - IRG/WP 21-10976
In 1999 a field test of Scots pine treated with MMF (Methylated Melamine Formaldehyde) resin and acetylated Scots pine post treated with MMF resin was started. Six years later a commissioned full NWPC test for BASF of Belmadur® (DMDHEU resin treated wood) was started at the same site. The testing, according to European Standard EN 275, was done in a bay by Kristineberg Marine Research Station o...
M Westin, P Larsson Brelid, A O Rapp, J Habicht


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