IRG Documents Database and Compendium


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The dip diffusion treatment of tropical building timbers in Papua New Guinea
1972 - IRG/WP 310
In Papua New Guinea a dip diffusion process using a multi salt preservative developed by C.S.I.R.0. has been in commercial use for 8 years. Over 200 million super feet (236,000 m³ ) of timber has been treated during this period and current rate of treatment is 34 million super feet (80,400 m³ ) of timber per year in 70 licenced treatment plants. The process has been found to be simple to apply, ...
C R Levy, S J Colwell, K A Garbutt


Chromium in wood preservation: Health and environmental aspects
1978 - IRG/WP 3120
The majority of water-borne salts in current use contain hexavalent chromium, usually as dichromate or chromium trioxide. In about 1913 it was suggested that chromates, phosphates or borates could be added to the sodium fluoride and dinitrophenol mixtures then in use in order to inhibit corrosion. Dichromates were found to be most suitable and the resulting mixture known as Thriolith and later Tri...
T R G Cox, B A Richardson


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper-chrome-arsenic preservative
1981 - IRG/WP 3150
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. We have evaluated the influence of steaming on treatability with a waterborne CCA preservative....
C R Coggins


The leaching of copper, chrome and arsenate from CCA-impregnated poles stored for ten years in running water
1978 - IRG/WP 3122
There is no evidence to indicate that the chromium and copper components are leached from the outermost 5 mm of sapwood in poles impregnated with Boliden K33 and Tanalith C and stored in running water for ten years. The arsenic component, however, seems to be leached out during the first few months to an extent of about 20% of the initial amount. The leaching time is dependent on the preservative ...
F G Evans


Proposed test procedure to determine the effect of timber substrate on the effectiveness of a copper/chrome/arsenic preservative in seawater
1975 - IRG/WP 411
R A Eaton


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


X-ray analysis of selected anatomical structures in copper/chrome/arsenic treated wood
1973 - IRG/WP 320
Application of analytical electron microscopy to problems in wood preservation has been very limited. Indeed, less than ten workers appear to have published their results using the technique, and of these' only two papers deal with energy dispersion procedures in the scanning electron microscope; the others employ the more familiar wavelength dispersive methods of the electron probe....
H Greaves


A laboratory soil-block decay evaluation of plywoods edge-treated with preservatives
1982 - IRG/WP 2174
Preservative-treated plywood used under conditions or severe decay hazard frequently has its original, or cut edges, protected by the application of a field-cut preservative. This study uses a laboratory test method to compare the efficacy of four commercial preservative treatments against two commonly occurring brown-rot fungi. The results are not meant to indicate the service life of such treate...
R S Smith, A Byrne


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


Retention and distribution of copper/chrome/arsenic (CCA) in pressurised sap-displaced UK grown spruce and pine
1986 - IRG/WP 3366
Increment cores were taken from UK grown Scots pine (Pinus sylvestris L.), Corsican pine (Pinus nigra var. maritima Ait), Sitka Spruce (Picea sitchensis (Bong) Carr), and Norway spruce (Picea abies (L) Karst) distribution poles treated by pressurised sap-displacement using a 1.8% copper, chrome, arsenic (CCA) solution. Each increment core was sectioned radially and the copper, chrome, and arsenic ...
P D Evans, G M Smith, B King


The volatilization of arsenic on burning copper-chrome-arsenic (CCA) treated wood
1978 - IRG/WP 3111
Small scale burning experiments are described involving copper-chrome-arsenic treated wood. Approximately 20 per cent of the arsenic was volatilised when the wood was burned in air but 60 per cent when burned in an oxygen-enriched atmosphere, this increase is attributed to an increase in combustion temperature. Although a small increase in arsenic evolution was found with an increased concentratio...
A-J Dobbs, C Grant


Effect of treatment process on performance of copper-chrome-arsenate. Part 2: Field stake tests
1995 - IRG/WP 95-40046
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation stakes were installed in a randomised plot in the Whaka graveyard located on the FRI campus. Stakes were inspected at yearly interval...
M E Hedley, J Anderson, J B Foster, B E Patterson


Preliminary study on relation of wood structure to copper/chrome/arsenic (CCA) distribution in kempas (Koompassia malaccensis)
1995 - IRG/WP 95-40054
Kempas had been treated with copper/chrome/arsenic (CCA) preservative using full cell process. Analysis of preservative distribution at the micro level in relation to wood structure was carried out using scanning electron microscope (SEM) and energy dispersive X-ray (EDXA) analysis. The results showed that CCA elements were detected in all wood tissues at different ratios. Distribution of chemical...
S Ani, S Salamah


Sampling variation in a copper chrome arsenic treated power transmission pole
1990 - IRG/WP 2351
The Queensland Forest Service routinely samples poles treated at all treatment plants throughout the State. Each treatment plant is issued with a Certificate of Registration and the accompanying documents list the different levels of preservative retention required for performance in various service conditions. The posted levels represent the.minimum permissible, and it is to these concentrations ...
J Norton


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Preliminary studies on cellulase production by selected Basidiomycetes and the effect of copper-chrome-arsenate on these enzymes
1980 - IRG/WP 1122
The growth of wood-destroying fungi on ligno-cellulosic materials depends on the production of many enzymes, of which probably the most important is the multi component cellulase system. Within this system, at least three different kinds of enzym are believed to be involved in crystalline cellulose decomposition. These are endo-1,4-glucanase, exo-1,4-ß glucanase and ß-glucosidase. Most of the re...
O Collett


Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne


Safe application of copper-chrome-arsenate preservatives
1975 - IRG/WP 377
All wood preservatives contain biologically active substances and must, by design, be in some measure toxic to man. There is nothing fundamentally difficult, however, about using a wood preservative with complete safety. It depends on knowing the risks to health and/or the environment, which the preservative may present, and planning application accordingly. In this paper we examine these and othe...
I N Stalker, P B Cornwell


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers
1991 - IRG/WP 2381
Standardized heartwood blocks of kempas (Koompassia malaccensis), keruing (Dipterocarpus sp.) and tualang (Koompassia excelsa) were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicola grisea, Petriella setifera and Trichurus spiralis in a containerized vermiculite-burial decay system according to draft CEN/TC 38 WG 4....
A H H Wong, R-D Peek


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper/chrome/arsenic preservative
1981 - IRG/WP 3180
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. The growth characteristics of spruces (Picea spp) make them attractive candidates for forestry schemes. In 1975 the UK Forestry Commission had about 400 000 hectares, about 20% of total UK forest area, planted with Sitka spruce (Picea sitchensis)...
C R Coggins


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren


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