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Water-borne preservative marine trials in Western Canada
1981 - IRG/WP 470
Red pine boards treated with chromated copper arsenate, ammoniacal copper arsenate, copper zinc arsenic additive, a modified ammoniacal copper arsenate, and zinc arsenic additive, have been installed in a marine field test at West Vancouver, British Columbia. After two and a quarter years exposure, all the test samples are in excellent condition with the exception of those treated with the zinc ar...
J N R Ruddick


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


A Preliminary Report on the Properties of Engineered Wood Composite Panels Treated with Copper Naphthenate
2005 - IRG/WP 05-40294
This paper reports on our preliminary investigation of the properties of randomly oriented strandboard which had waterborne or powdered copper naphthenate (CuN) incorporated into the board during manufacture. When compared to zinc borate-treated controls (ZnB), the mechanical properties of strandboard (MOR, MOE, work-to-maximum load, internal bond strength) were not adversely affected by treatmen...
J W Kirkpatrick, H M Barnes


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Assessment of the toxicity of some copper-, zinc- and boron-based wood preservatives to the cellar fungus Coniophora cerebella Schröet
1974 - IRG/WP 242
This article reports the use of a method based on the determination of the probability of the protection of timber against destruction by fungi. By converting the probability values to probit values and plotting them as a function of the amount of preservative retained in the timber, curves of the toxic effect are obtained, enabling any timber protection probability to be assessed....
V N Sozonova, D A Belenkov


Laboratory evaluation of metallic naphthenates as wood preservatives
1991 - IRG/WP 3654
Fungicidal and termiticidal efficacy of copper and zinc naphthenates was appraised according to Japanese standardized laboratory testing methods. Copper and zinc naphthenates succeeded in protecting wood from decay fungi at retentions of 0.5 and 1.0 kg/m³ as metal, respectively. [JIS A 9302 (1976)] when they were applied to vacuum/soak impregnation [JIS A 9301 (1976)]. With respect to the fungici...
K Tsunoda, M Sakurai


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Basilit CCFZ. Further studies on ecotoxicological behaviour
1992 - IRG/WP 92-3722
Basilit CCFZ is a new developed water based preservative for the protection of timber in hazard class 4 and 5 (ground-, fresh- and salt-water contact). The active components of this salt are copper, chromium, zinc and fluorine. In addition to primarily studies on the acute toxicity against organisms of the aquatic food chain a long term ecotoxicological study was performed. In a prolonged toxicity...
H W Wegen


Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Progress report on "Studies on the effect of salinity on the growth and mortality of teredinids"
1976 - IRG/WP 418
An open flow aquarium was constructed at Forest Products Research Centre in 1972 in order to study the effect of salinity on the growth and mortality of teredinids. To determine the reliability of results obtained during salinity experiments, the growth rate of teredinids in the aquarium were compared with the growth rate of the same species living under natural conditions in the harbour in 1973. ...
S M Rayner


Upgrading the fungal resistance of OSB
1999 - IRG/WP 99-40138
There is a perception that oriented strand board (OSB) is less resistant to fungl than plywood under conditions of moderate exposure to moisture. Douglas fir-faced plywood (DFP) has been suggested as a benchmark for acceptable durability under such conditions. This project was initiated to determine the minimum level of low-toxicity chemical treatment needed to upgrade the fungal resistance of OSB...
P I Morris, J E Clark, D Minchin, R Wellwood


Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Effect of Nano-silver and Nano-copper and Nano-zinc oxide on Paulownia wood exposed to white-rot fungus
2013 - IRG/WP 13-30635
Paulownia is known as a fast growing tree and it can be used in several applications. The present study investigated the effect of Nano-silver and Nano-copper and Nano- zinc oxide on resistance of Paulowina (Paulownia fortunei) wood against the white rot fungus (Coriolus versicolor). Wood specimens with a dry density of 0.37g/cm3 were impregnated with a 400 ppm aqueous suspension of micronized na...
M Akhtari, M Ganjipour


Incidence of soft rot attack on preservative treated Douglas-fir poles: a preliminary survey
2014 - IRG/WP 14-10818
Occurrence of soft rot decay in Douglas-fir poles treated with ammoniacal copper zinc arsenate (ACZA) or pentachlorophenol in oil was studied. Soft rot was less prevalent in poles treated with penta, but some soft rot was found in approximately 20 % of poles examined. Soft rot was more common in poles treated with ACZA, and, when present, was found in almost 20% of the cells examined. The potenti...
P Torres Andrade, J J Morrell


Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Comparative response of Reticulitermes flavipes and Coptotermes formosanus to borate soil treatments
1991 - IRG/WP 1486
Eastern (Reticulitermes flavipes [Kollarl]) and Formosan (Coptotermes formosanus Shiraki) subterranean termite workers (Isoptera: Rhinotermitidae) were exposed to borate-treated sand in an indirect exposure tunneling assay in the laboratory. In the ten day assay period, both termite species readily penetrated sand containing 5000, 10000, or 15000 ppm (wt. of compound / wt. of sand) disodium octabo...
J K Grace


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


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