IRG Documents Database and Compendium


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Detoxification of preservatives: Tri-n-butyltin oxide as a biocide
1982 - IRG/WP 1156
T E Dudley-Brendell, D J Dickinson


Accelerated ageing of preservatives in treated wood
1988 - IRG/WP 3476
New preservatives are tested in the laboratory and often in field tests before they are used commercially. Some preservatives, however, tested in the laboratory do not show the expected stability when used in service. The differences between laboratory tests and practical use can never be completely eliminated but must be minimized as far as possible by relevant testing methods. Studies of the eff...
M-L Edlund, B Henningsson, B Jensen, C-E Sundman


An investigation into the stability of TBTO in LOSP-treated radiata pine
1987 - IRG/WP 3459
Nuclear magnetic resonance (NMR) spectroscopy and reverse phase paper chromatography were used to characterise the organotin compounds found in radiata pine treated with bis (tri-n-butyl) tin oxide (TBTO). Preliminary results indicate that the preservative is remarkably unstable in wood after light organic solvent preservative (LOSP) treatment. Significant decomposition of TBTO occurs in a matter ...
K J Archer, R Meder


Stability and performance of tributyltin compounds
1984 - IRG/WP 3275
Based on the critical examinations of the disputable permanence of tributyltin compounds in wood, this paper deals with a number of examinations of the relative evaporation, thermal stability and oxidation stability of some TBT-compounds. While thermal and oxidative stability is high for all TBT-species, the relative evaporation at elevated temperature is highly variable, and lowest for the TBT-es...
F Imsgard, B Jensen, H A B Landsiedel, H Plum


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


Chemical and biological investigations of double-vacuum treated windows after 5 years in service
1983 - IRG/WP 3219
In 1980 The Swedish Wood Preservation Institute initiated an investigation to study the degradation of TBTO and possible fungal attack in double-vacuum treated window joinery in service during 5 years. A hospital in Gothenburg was chosen that was built during 1969 to 1976. Both untreated and double-vacuum treated windows of Pinus sylvestris were used. A brown alkyl oil type paint (Nordsjö system ...
J Jermer, M-L Edlund, B Henningsson, W Hintze, S V Ohlsson


Fungal detoxification of organotin biocides
1985 - IRG/WP 1258
The ability of a range of wood decaying fungi to inactivate bis(tri-n-butyltin) oxide (TnBTO) in the extracellular growth medium, in stationary liquid culture was determined. A distinction between the ability to tolerate the fungicide and to inactivate it was made: the white-rot organism Coriolus versicolor being the most efficient inactivator. In an attempt to determine the extracellular agents r...
P S Belford, D J Dickinson


Chemical and biological investigations of double-vacuum treated windows after 7½ years in service
1985 - IRG/WP 3339
Earlier investigations of double-vacuum treated windows after five years in service have shown that tributyltin oxide (TBTO) degrades to di- and monobutyltin compounds and that the resistance of the wood against decay decreases. An investigation 2.5 years later of the same windows shows that the degradation of TBTO proceeds fast. After 7.5 years in service only 15-35% of the remaining organotin co...
M-L Edlund, J Jermer, B Henningsson, W Hintze


Microbiological degradation of wooden piles in building foundations
1988 - IRG/WP 1370
White rot, soft rot and bacterial attack have been detected in softwood piles under buildings. In some cases bacteria were found to be the main degradation organisms in the studied piles. The water content of degraded piles was very high. The compression strength was quite low also in the piles deteriorated by bacteria. The density of wood was very variable, and the degree of degradation could not...
L Paajanen, H Viitanen


Solvent drying and preservation of timber
1977 - IRG/WP 381
Processes which combine drying and preservation are first reviewed. Some preliminary experiments are then described in which blocks of green Sitka spruce sapwood were immersed, in a solution of tributyltin oxide (TBTO) in methanol at 60°C. Satisfactory penetration of the preservative and exchange of methanol and water occurred in a few hours. The methanol was removed rapidly from the wood by evap...
J A Petty


JWPA method for testing effectiveness of surface coatings with preservatives against decay fungi
1981 - IRG/WP 2164
In 1979 JWPA established a new method for testing effectiveness of surface coatings in accordance with practical use of preservative-treated lumber. Comparing the new testing method with JIS A 9302, a few new trials - size of wood specimen, weathering procedure, and decay-test procedure - are incorporated....
K Tsunoda


Fungal and bacterial attack of CCA-treated Pinus radiata timbers from a water-cooling tower
1991 - IRG/WP 1488
Transmission electron microscopy of decaying CCA-treated Pinus radiata timbers from an industrial water cooling tower showed presence of a thick biofilm covering some areas of the wood. The biofilm contained various morphologically distinct forms of microorganisms embedded in a slime. The study provided evidence of the activity of soft rot fungi and tunnelling and erosion bacteria in wood cells. T...
A P Singh, M E Hedley, D R Page, C S Han, K Atisongkroh


Improved techniques designed for evaluation of fungicides in soil for control of dry rot fungus Serpula lacrymans
1985 - IRG/WP 2238
Improved techniques provide a laboratory method for the evaluation of chemicals in soil for control of dry rot fungus Serpula lacrymans. Results with their application to three chemicals were reported. These techniques are useful to eliminate chemicals lacking the necessary toxicity and weatherbility for dry rot control when the chemicals have been applied to the soil....
M Takahashi, K Nishimoto


Ultra-structural observations on the degradation of wood surfaces during weathering
1987 - IRG/WP 2280
Radiata pine (Pinus radiata D. Don) sapwood was converted into blocks with a transverse face about 5 mm square and measuring 8 mm longitudinally. Transverse (T.S.), Radial (R.L.S.) and Tangential (T.L.S.) surfaces were prepared and specimens exposed to the weather inclined at 45° facing equatorially for periods of between 20-60 days. After 30 days exposure erosion of the middle lamella was observ...
P D Evans, S Thein


Effect of medium-term degradation of beech wood by erosive (Phanerochaete chrysosporium) and lignin-selective (Ceriporiopsis subvermispora) strains of white rot fungi on its selected physical properties
2004 - IRG/WP 04-40292
At the Faculty of Wood Sciences and Technology a fungal delignification of normal and tension beech wood by erosive and lignin-selective strains white-rot fungi has been studied. The pre-treatment of both kind of wood samples was accompanied by partial delignification and apparent changes of their physical properties influencing the polar liquids penetration....
R Solár, S Kurjatko, M Mamonová, J Hudec


Surveillance médicale des personnels exposés aux produits de préservation du bois
1990 - IRG/WP 3588
J-C Aubrun


Studies on accelerated ageing procedures with TBTO-treated wood
1985 - IRG/WP 2244
The efficacy of various procedures for accelerated ageing of organotin based wood preservatives in treated wood has been investigated. It was found that leaching of the treated wood samples in water according to the European Standard EN 84 was not satisfactory for organotin based preservatives and is probably also unsuitable even for other types of organic solvent preservatives. Keeping tributylti...
J Jermer, M-L Edlund, B Henningsson, W Hintze


Resistance of Alstonia scholaris vestures to degradation by tunnelling bacteria
1992 - IRG/WP 92-1547
Electron microscopic examination of vessels and fibre-tracheids in the wood of Alstonia scholaris exposed to tunnelling bacteria (TB) in a liquid culture showed degradation of all areas of the secondary wall. The highly lignified middle lamella was also degraded in advanced stages of TB attack. However, vestured pit membranes and vestures appeared to be resistant to degradation by TB even when oth...
A P Singh, T Nilsson, G F Daniel


The evaluation of synergistic effects of chemicals on fungicidal efficacy in crossed-paper tests
1991 - IRG/WP 2383
The mixing effects of wood preservatives were evaluated using the crossed-paper technique. Two filter paper strips (0.7 x 8 cm²) were treated by soaking with different chemicals [fungicides, a termiticide (chlorpyrifos or phoxim), a surface-active agent, a synergistic agent, and a stabilizer], and placed at right angles to each other on a fully grown mycelial mat of a test fungus in a Petri dish....
Dong-heub Lee, K Tsunoda, M Takahashi


Fungicidal combination products
1987 - IRG/WP 3426
Due to the increased pressure on some of the established fungicides used in wood preservation, possible alternative products become more interesting. The requirements for new chemicals are mainly lower toxicity and greater environmental acceptability. However the efficacy to target organisms should be as good as that of the currently used ones, preferably better. A possibility for progress in this...
H A B Landsiedel


A direct basidiomycetes test methodology. Report on an EWPM ring test
1988 - IRG/WP 2306
Results of an EWPM-ring test using a direct basidiomycetes test methodology are reported. The test is caracterized by using big test blocks and infestation by infected wood under unsterile conditions. The test procedure needs further development work, but the results are so promising that co-operation with CEN and EHC is initiated with the purpose of recognition and standardization....
B Jensen


The present classification of wood degradation factors
1994 - IRG/WP 94-10071
The revised version of classification of wood degradation factors is presented after discussion and remarks sended by IRG-Members. The classification contains the biotic and abiotic factors in two aspects: etiological and symptomatical....
J Wazny


Airborne algae as a wood degradation factor
1992 - IRG/WP 92-1549
The occurrence of airborne (aerophytic) algae on wood is a very frequent phenomenon. However, there is currently a lack of information concerning their effect on the wood tissue. Some important genus of algae infesting wood under natural conditions are listed, as well as the results of experimental studies in the "in vitro" culture concerning the effect of two selected algal species on some physic...
K J Krajewski, J Wazny


Studies of the distribution and degradation of tributyltin naphthenate in double-vacuum treated wood
1983 - IRG/WP 3230
The effects of forced solvent evaporation by kilning redwood (Pinus sylvestris) that has been double-vacuum treated with tributyltin naphthenate (TBTN) have been investigated. Contrary to previous studies reported, it has been shown that forced evaporation can have a considerable influence on the losses of the fungicide. It has been found that, whether the solvent is allowed to evaporate slowly or...
J Jermer, M-L Edlund, W Hintze, S V Ohlsson


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