IRG Documents Database and Compendium


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Evaluation of rapid methods for detecting wood preservatives in waste wood
1994 - IRG/WP 94-50024
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Several analytical methods are available for the detection of most elements in wood preservatives. Industrial process conditions, however, demand methods with very short turn around times. In this research several methods of analysis were judged on their speed and accuracy. A num...
W J Homan, H Militz


Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


The variability of preservative distribution in test blocks
1973 - IRG/WP 220
The techniques for the assessment of likely effectiveness of preservative systems have long been the subject of much discussion. The whole field has recently been reviewed by Hilditch and Hamblyn (1971) who described in detail many of the laboratory test procedures used, but who also indicated the deficiencies in many of these techniques. It has long been the view of many associated with the wood ...
F W Brooks, M R Gayles, R W Watson


Laboratory evaluation of chlorothalonil against the Formosan subterannean termite
1992 - IRG/WP 92-1559
The fungicide chlorothalonil was evaluated as a wood preservative to prevent attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Southern yellow pine wafers treated with chlorothalonil (CTL) in P9 oil, CTL + chlorpyrifos in P9 oil, or CTL in xylene were conditioned by evaporative aging at 40° C for 4 weeks and exposed to termite attack in a mod...
J K Grace, P E Laks, R T Yamamoto


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Use of X-Ray Fluorescence (XRF) Spectroscopy to Determine 4,5-Dichloro-2-n-Octyl-4-Isothiazolin-3-one (DCOIT) in Wood
2007 - IRG/WP 07-20373
Organic preservative based systems are being developed as replacements for the metal based systems. Typically the chemical actives of organic preservative systems are analyzed using HPLC or GC. However, these analytical techniques require complex sample processing and involve relatively long analysis times. In addition the equipment requires maintenance and a skilled operator. One organic preser...
P Walcheski, J Ashmore, D M Laganella


Preparation of Calibration Standards for the Analysis of Pentachlorophenol in Treated Wood by X-ray Fluorescence
2016 - IRG/WP 16-20591
The primary purpose of this project was to develop a method for preparing calibration standards that can be used by the wood treating industry to calibrate X-ray fluorescence instrumentation. Calibration standards of penta/P9-oil in southern yellow pine that cover the retention range of 0.2 to 0.9 pcf (0.6 to 1.9 %) were successfully prepared. A detailed procedure for mixing penta in treating sol...
L L Ingram Jr, H M Barnes, R Shmulsky, D Jeremic


Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete


Monographic information on Schizophyllum commune
1975 - IRG/WP 118 E
D Dirol, M Fougerousse


Comparative studies on the distribution of lignin and CCA elements in birch using electron microscopic X-ray microanalysis
1987 - IRG/WP 1328
The microdistribution of metal preservatives in treated wood has received considerable research over the last two decades. Despite this, little effort seems to have been made to try and correlate the distribution of CCA elements with respect to naturally occurring wood cell wall components in wood. In the present preliminary study an attempt is made to relate the distribution of lignin in-situ wit...
G F Daniel, T Nilsson


Ultrastructural and TEM-EDAX studies on the degradation of CCA treated radiata pine by tunnelling bacteria
1985 - IRG/WP 1260
An ultrastructural study was carried out on bacterial attacked Pinus radiata stakes treated with a high level (24.7 kg/m³) of Tanalith NCA preservative. The purpose of the investigation was to determine whether the organism possessed intracellular and/or extracellular detoxification mechanisms in order to overcome the high levels of copper, chrome and arsenic present within the wood fibre walls. ...
G F Daniel, T Nilsson


A fixation model, based on the temperature dependence of CCA-C fixation
2000 - IRG/WP 00-40163
A model was prepared for the fixation of 1% CCA-C in red pine that allows the prediction of extent of fixation based on the temperature history of the treated wood following pressure treatment. The reaction kinetics of the rapid initial reaction and the slower main reaction were characterized using the Van t'Hoff equation. The initial reaction could be represented by a 10th order chemical...
P A Cooper, K M F Kazi, Jianbin Chen, Y T Ung


Detection of defects in standing poles by X-ray techniques
1980 - IRG/WP 2132
The application of X-ray techniques to wood pole inspection procedures has been evaluated. Internal defects were accurately identified using X-ray inspection methods. These methods and their possible influence on the safety and economic aspects of wood pale utilization are discussed....
W D Gardner, R S Johnstone, W Pitt


New developments in wood preservation
1974 - IRG/WP 335
Most of the developments in wood preservation in recent years have been stimulated by changing circumstances, particularly the increasing interest in reducing hazards and environmental, pollution but also the serious difficulties that are now being encountered in obtaining economic supplies of established preservatives. There is perhaps a danger that new controls to reduce pollution dangers may be...
B A Richardson


X-ray analysis of selected anatomical structures in copper/chrome/arsenic treated wood
1973 - IRG/WP 320
Application of analytical electron microscopy to problems in wood preservation has been very limited. Indeed, less than ten workers appear to have published their results using the technique, and of these' only two papers deal with energy dispersion procedures in the scanning electron microscope; the others employ the more familiar wavelength dispersive methods of the electron probe....
H Greaves


A wood preservative for the future: Copper dimethyldithiocarbamate
1994 - IRG/WP 94-30045
The development of a new wood preservative, copper dimethyl-dithiocarbamate (CDDC) is reviewed in this paper. CDDC is formed in situ by dual pressure treatments. Laboratory and field efficacy trials, physical and chemical properties of the preservative solutions and treated wood, and plant handling characteristics of the system are examined....
D K Stokes, M H Freeman, T L Woods, R D Arsenault


Monographie de Schizophyllum commune
1975 - IRG/WP 118
D Dirol, M Fougerousse


Bacterial staining of samba (Triplochiton scleroxylon)
1988 - IRG/WP 1362
Red- and green-stained areas on Samba wood have been tested by IR, X-ray and Neutron Activation Multielement Analysis. No difference could be seen between stained and unstained areas. The red- and green-staining seem to be related to the bacteria Pseudomonas aeruginosa which were isolated from both red- and green-stained areas on the wood surfaces....
K Hansen


Water sprinkled pine wood: A microscope study on boards showing streaking
1993 - IRG/WP 93-10033
Boards sawn from the outer sapwood of pine lumber previously water sprinkled for periods of 10-18 weeks and kiln dried, showed streaking after staining. Two types of enhanced stain uptake were noted: 1) a more concentrated and localized form after 10 weeks and 2) a more diffuse type which developed in later stages of water sprinkling. Areas showing enhanced stain uptake were examined using light a...
G F Daniel, T Elowson, T Nilsson, A P Singh, K Liukko


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 9: Report of third inspection (2 years) in Italy
1980 - IRG/WP 461
The wood samples were submerged in the sea at Follonica, Italy, in April 1977. Follonica, latitudine 42°55' North and longitude 10°45' East, is situated on the Tyrrhenian sea. The recorded temperature varies between 13°C to 25°C, salinity 37-38% and pH about 8. The inspections were carried out after 6 months (10/1977), 1 year (4/1978) and 2 years (4/1979)....
A Gambetta, E Orlandi


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