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Aspects of diffusion of boron through wood
1984 - IRG/WP 3298
Boron compounds have been shown to be toxic to a wide range of wood destroying insects and fungi. They are cheap, have low mammalian toxicity and their application in the treatment of wood does not demand specialized equipment. These attributes make them specially attractive to developing countries. Currently, however, little is known about the mechanism of diffusion of boron through wood. Effective treatment with boron preservatives requires good understanding of how the preservatives diffuse through wood. This paper presents a research proposal with the overall objective of determining the relative importance of structural wood components in determining diffusion rates.
S Iddi

New technique to analyze impregnation processes
1988 - IRG/WP 2304
Equipment has been developed to measure liquid flow in wood during impregnation processes. Basic principles of flow measurements using directly heated negative temperature coefficient thermistors, and some characteristics of the hardware developed are presented in this paper.
J P Hösli

Direct measurement of fluid flow within wood
1986 - IRG/WP 2248
The problematics of fluid flow mechanism within wood using a permeability concept are highlighted, and the non-feasibility of a practical and versatile model is explained. An alternative method using a negative temperature coefficient thermistor to measure flow velocity directly is presented. The method has been verified in living trees and shows extreme sensitivity for flow above 1 meter/hour. For measuring lower velocities, the method needs improvement.
J P Hösli

Creosote movement from treated wood immersed in fresh water: Initial PAH migration
2003 - IRG/WP 03-50201
Creosote has a long history of successful use as a wood preservative, but polycyclic aromatic hydrocarbons (PAHs) in this preservative have raised environmental concerns, particularly when creosote-treated wood is used in aquatic environments. A number of models have been developed to predict the risk of creosote use in aquatic environments, but one limitation of these models is a lack of data on the initial rates of creosote migration from treated wood. We examined the effect of flow rates on creosote migration from freshly treated wood immersed in fresh water. Creosote component levels declined to a steady state within 7 days, suggesting that creosote migration decreased sharply after an initial spike. The data will be used to enhance existing predictive models.
Sung-Mo Kang, J J Morrell, J Simonsen, S T Lebow

The treatment of sawn whitewood with organic solvent wood preservative
1982 - IRG/WP 3192
The impregnation schedules approved in the UK for the treatment of sawn European whitewood (Picea abies) with organic solvent borne preservatives result in comparitively high loadings relative to the limited depth of penetration they achieve. Results are presented, which show how substantial reduction in the overall loading may be achieved without concomitant reduction in penetration. A model for organic solvent behaviour is postulated as a basis to account for these findings.
L D A Saunders

Efficiency of wood impregnation processes
1980 - IRG/WP 3151
Many wood impregnation processes have been in use for a very long time, up to 150 years, but they have not been progressively modified. This paper considers impregnation processes in relation to current requirements, particularly impregnation efficiency and energy consumption. The term 'pore' is used throughout in its physical sense and is not confined to botanical 'pores'. SI units are used and, for convenience, atmospheric pressure is assumed to be exactly 100 N/m²; complete vacuum is 0 N/m². These observations and conclusions summarise an extensive programme of investigation at Penarth Research Centre involving creosote and water-borne preservatives, as well as a range of organic solvent preservatives.
B A Richardson

A novel solvent penetration assessment technique for wood preservativation treatments using waterborne systems
1990 - IRG/WP 2346
Solvent and hence solute (a.i.) penetration during any wood preservation treatment cycle and the flow pathways taken by the solvent in the wood are crucial elements in determining the adequacy of any treatment. Inadequate solvent penetration into specimens or an inappropriate tissue throughflow pattern during impregnation will markedly affect the distribution pattern achieved by many non-diffusible preservative systems. There is to date no direct method of determining the pathways liquid solvents take during their penetration into wood. Currently used methods, such as directional gas permeability measurements are indirect and only provide indications of the relative potential for certain pathways in the wood to be used during liquid impregnation of wood. The following work describes the development and experimental trial of a technique using cryogenic electron microscopy for the direct visual determination of water penetration into samples of Pinus patula and its potential for use in Eucalyptus grandis.
A J Pendlebury, J Coetzee, E Sorfa, A Botha

Methods for improving preservative penetration into wood: a review
2002 - IRG/WP 02-40227
Pressure treatment technologies have been available since the mid-1830's, but the processes used for wood treatment are still largely unable to overcome the fundamental limitations of flow through semi-permeable pit membranes. Instead, methods have arisen that attempt to improve treatability of the wood including incising, compression rolling, through boring, or radial drilling. Other approaches have altered the characteristics of the treatment fluid primarily by reducing viscosity. None of these methods has been completely successful. This paper reviews the methods employed to improve preservative penetration in wood and outlines research needs for addressing treatment of refractory wood species.
J J Morrell, P I Morris

Evaluation of fluid distribution in pressure treated wood in different flow directions
2004 - IRG/WP 04-40281
Among different methods, polymerization technique was chosen to study distribution of fluid through cell types in treated wood. Red maple wood specimens with the size of 2 by 2 by 4 cm (radial, tangential and longitudinal, respectively) were prepared. Styrene monomer was used as the fluid for impregnation; because its physical properties such as surface tension, specific gravity and viscosity fall between those of many preservatives. Before impregnation, apart from the uncoated specimens, some samples were coated with epoxy resin such that lateral flow along with longitudinal flow could be studied. Full cell process with the exception of final vacuum was applied for impregnation. Thin sections from the treated wood were prepared to be microscopically examined for distribution study. The results indicated uniform fluid distribution in lateral flow (both in radial and tangential) and non-uniform distribution in longitudinal flow as well as flow in uncoated specimens. Since uniform distribution of preservative among different cell types is very important, it is recommended that in some cases such as poles, piles, posts and sleepers, end coating of wood should be done before impregnation.
A Omidvar, M H Schneider

Permeability measurements on surface layers for detecting wood with abnormally high permeability
1988 - IRG/WP 2298
Wet storage of timber during the warm period of the year may lead to an increased permeability of the wood, an undesirable phenomenon for several wood industries and also for many end-uses. Neither before nor after drying, such wood with "wet storage damage" can be visually distinguished from wood with a normal permeability. A non-destructive method for inspecting the permeability of surface layers has been tested and has proved to be useful for detection of damage to timber due to wet storage. The principle of the method is that air from a compressor is pressed into the wood via a nozzle and that the air flow and/or pressure decrease is recorded. A large air flow or a large pressure decrease indicates high permeability.
J B Boutelje, G Hägglund

Radial flow of Bornmullerian fir (Abies bornmulleriana Mattf.) as affected by wood tapering and the condition of end wall structure of uniseriate ray parenchyma cells
2008 - IRG/WP 08-40441
Amenability to radial permeability of Bornmullerian fir (Abies bornmulleriana Mattf.) was studied on the base of the effects of wood tapering and the structure of end walls of uniseriate ray parenchyma cells. The results showed that the most remarkable culprits of the greatest fluid uptake (as the percentage of void volume filled by the fluid in the radial flow direction, RVVF%) are the lesser wood tapering and a slight inclination of the end walls. It was also noticed that the thinner end walls having the larger apertures of the simple pits influence to RVVF%. It could be therefore stated that both wood tapering and the situation of the end walls of uniseriate ray parenchyma cells were the most important factors for regulating radial flow for Bornmullerian fir.
I Usta, S Aslan

Barefoot-heat-impact of oil-heat-treated wood: An important thermal property of decking boards
2009 - IRG/WP 09-40458
In this study the phenomenon of sensual heat impression was examined, when walking with bare feet on sun exposed wood based decking boards. A suitable method for measuring the heat flux from decking boards into an artificial foot was developed. The method and measuring device is described as well as results from measuring three different decking board materials: Oil-heat-treated spruce (OHT), untreated Bangkirai, and solid Wood Polymer Compound (WPC). The spruce OHT decking boards showed the lowest surface temperature after exposure to light (OHT 67°C, Bangkirai 76°C, WPC 85°C) and also caused the lowest temperature in the artificial foot (OHT 39.8 °C; Bangkirai 47.5 °C; WPC 52.3 °C). The measured heat flow density of the OHT decking boards was the lowest; the heat flow density of Bangkirai was three times and of WPC four times higher. The data obtained mirrored well the subjective sensation when walking on the three different materials with bare feet. After exposure to artificial solar radiation the OHT-spruce decking caused a feeling, which can be described as “conveniently warm”, whereas Bangkirai and in particular the solid WPC caused pain to the bare skin.
A O Rapp, C R Welzbacher, C Brischke

Danish wood preservatives approval system with special focus on assessment of the environmental risks associated with industrial wood preservatives
2001 - IRG/WP 01-50166-01
The following is a description of the procedure used by the Danish Environmental Protection Agency to assess the environmental risks associated with preservatives used in the pressure impregnation of wood. The risk assessment covers issues considered to be of significance for the environment and which are adequately documented so as to allow an assessment. Such issues are persistence and mobility in soils, bioaccumulation and the impact on aquatic and terrestrial organisms. Unless required in special circumstances, the assessment does not apply to birds and mammals as the normal use of preservative treated wood is not expected to involve any noteworthy exposure of these groups. Approval of wood preservatives will be based on a general assessment of the environmental risk associated with the normal use of wood treated with the preservative in a realistic worst case situation. The assessment may address other aspects such as disposal and total life cycle.
J Larsen

Data sheet on wood-boring insects. Apate monachus Fabricius. 2. Position systématique, nomenclature, identification et distribution - Espèces végétales attaquée
1981 - IRG/WP 1105
R L A Damoiseau

Confocal laser scanning microscopy of a novel decay in preservative treated radiata pine in wet acidic soils
1997 - IRG/WP 97-10215
Light microscopy of radiata pine (Pinus radiata D. Don) field test stakes (20x20x500mm3) exposed in wet acidic (pH 3-4) soil for 12 - 24 months showed predominance of an unusual type of decay characte-rised by tunnelling attack of wood cell walls. After two years decay was moderate to severe in wood treated to ground contact CCA specifications and also equivalent retentions of creosote, and a number of new generation preservatives. Relative to other New Zealand temperate test sites and also an Australian tropical site, the New Zealand acidic soil test site was very aggressive. Correlative scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM) were used to elucidate the micromorphology of this attack. Tunnels of diameter 0.2-5 µm were present throughout all layers of the cell wall, and their orientation was not related to cellulose microfibril orientation. They also showed no preference for particular cell wall layers, indicating a lignin degrading capability. CLSM images showed that living, connecting fungal hyphae were present in the cell lumina and tunnels. This type of attack was predominant in wood that was highly saturated with water whereas wood that was less moist was predominantly attacked by classical white rot. Ongoing isolation and incubation studies in conjunction with further microscopy should enable identification of the fungal species involved.
R N Wakeling, Ying Xiao, A P Singh

Effect of acetylation on decay resistance of wood against brown-rot, white-rot and soft-rot fungi
1989 - IRG/WP 3540
Effect of acetylation on decay resistance of wood was investigated using wood blocks of Cryptomeria japonica, Pinus densiflora, Albizia falcata and Fagus crenata. Blocks were treated with uncatalyzed acetic anhydride for different lengths of time and exposed to Tyromyces palustris, Serpula lacrymans, Coriolus versicolor and unsterilized soil. The action of OH-radical on acetylated wood was also examined using Fenton's reagent. The enhancement of decay resistance by acetylation was revealed clearly for all cases of exposures but varying with fungal and wood species used. For a brown-rot fungus Tyromyces palustris, the weight loss reached almost nil in all woods at 20 WPG (weight percent gain) of acetylation, after the striking decrease from 10 to 15 WPG. For a white-rot fungus Coriolus versicolor, it was counted until 12-15 WPG in the perishable hardwoods used, but not in a softwood Cryptomeria japonica, even at 6 WPG. In cases of another brown-rotter Serpula lacrymans and soil burial, effect of acetylation was intermediate between Tyromyces palustris and Coriolus versicolor. Anti-degradation mechanism by acetylation was discussed, from these weight loss - weight gain relationships, and the IR-and 13C-NMR spectral analyses of fungus-exposed wood.
M Takahashi, Y Imamura, M Tanahashi

The IRG..Chanelling information and ideas into the mainstream of wood preservation technology
1985 - IRG/WP 5241
IRG Secretariat

Wood preservation in Poland
2004 - IRG/WP 04-30362
Dynamic growth of market demand for wooden elements and articles, generated in Poland increase of interest in industrial preservation. Today, Poland is a substantial producer and exporter of wood made products. Majority of exported wood - approximately 70% - is scotch pine (Pinus silvestris L.), which, due to its natural durability, requires preservation.
A Kundzewicz

Wood preservatives: Field tests out of ground contact. Brief survey of principles and methodology
1976 - IRG/WP 269
This paper contains the following spots: 1.: The general need for field tests. 2.: Interests and limits of field tests in ground contact. 3.: Various methods in use for out-of-ground contact field tests. 4.: Fungal cellar tests are they an alternative to above-ground decay exposure tests? 5.: Conclusions.
M Fougerousse

The effect of certain wood extractives on the growth of marine micro-organisms
1977 - IRG/WP 438
S E J Furtado, E B G Jones, J D Bultman

Management of the wood and additives wastes in the wood processing industries: Problematics and technical answers review
1996 - IRG/WP 96-50073
Management pathways for pure wood subproducts are well known and used; but as soon as additives like preservatives, glues, varnishes or coatings are present within the wood wastes, their disposal or valorization becomes more tricky. The different kinds of mixed wood wastes of the wood processing industries, from the sawmill to the furniture manufacture, are identified herewith and their diversity is examined. These wastes can be classified according to their danger characteristics, taking into account the type of additives, their concentration, their availability for the environment, the physical state of the waste. Different disposal pathways are then considered. Combustion, with the possibility of energetic valorization seems the best answer for a major part of these wastes. But this is only possible if good combustion conditions are defined, so that no harmful products are emitted. Moreover, these conditions must be affordable on the technical and economical point of view. Then, some wastes cannot be burned in such a simple way, and need a larger approach, which is presented in this document.
S Mouras, G Labat, G Deroubaix

Biological screening assays of wood samples treated with creosote plus chemical additives exposed to Limnoria tripunctata
1980 - IRG/WP 408
Laboratory methods for exposure of treated wood coupons to Limnoria tripunctata are described. Chemical additions to creosote were screened using this method. Three pesticides, Endrin, Kepone, and Malathion proved particularly effective. The addition of varying percentages of naphthalene to creosote using several treatment methods are currently being assayed. Results to date show that the coupons treated by the empty cell method have better performance than those prepared by the toluene dilution method. The naphthalene coupons treated by the full cell method show no attack after six months' exposure.
B R Richards, D A Webb

Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi had a greater ability to reduce the diffusion of copper ions than ECMM which had been subject to dialysis to remove soluble, low molecular weight components. The ‘insoluble’ fraction of ECMM for both species was more effective than the ‘soluble’ fraction at reducing the diffusion of copper ions. It is concluded that ECMM confers some protection to hyphae against the toxic effects of copper ions on growth in vivo and that this due to the binding of copper ions to both the polysaccharide and to low molecular weight components of the ECMM
D Vesentini, D J Dickinson, R J Murphy

Improvements of monitoring the effects of soil organisms on wood in fungal cellar tests
1996 - IRG/WP 96-20093
Accelerated testing the durability of preservative treated timber in a so called "fungal cellar" or "soil-bed" to evaluate its performance in ground contact is widespread practice. In order to obtain a more accurate and reproducible estimate of preservative performance, several institutes, among them the BAM in Berlin, have routinely carried out static bending tests in addition to visual examination. These tests were usually performed with a defined maximum load or deflection path regardless of the remaining degree of elasticity of the test specimens. Recent studies at the BAM revealed that by modifying the method, i.e. by restricting the applied load to the non-destructive interval for each individual test specimen, the calculated modulus of elasticity (MOE) reflect the changing strength properties caused by biological deterioration and allow within a relatively short time valuable predictions on the service life of the treated timber in soil contact.
I Stephan, S Göller, D Rudolph

Working Group I Sub-group 5 'Insects in dry wood'. Plan for data sheets
1982 - IRG/WP 1173
S Cymorek

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