IRG Documents Database and Compendium


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Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Pest control products act. An overview of regulation of heavy duty wood preservatives
1995 - IRG/WP 95-50040-30
The regulation of pesticides in Canada is carried out under the authority of the Pest Control Products Act and Regulations. Products which control, prevent, destroy, mitigate, attract or repel a pest are required to undergo a presale assessment for safety, merit and value. This review will determine whether a product, when used according to label directions, can be used both safely and will be eff...
K McCullogh


EPA’s Current Views on Heavy-Duty Wood Preservative Regulation
2003 - IRG/WP 03-50206
This paper describes the current EPA system for regulating pesticides and wood preservatives. In particular it focuses on the voluntary phase-out of CCA for residential uses after December 30, 2003, which was agreed between the CCA manufacturers and EPA. Even though the EPA reached an agreement with industry to phase out CCA for residential uses, EPA is continuing the most rigorous risk assessmen...
F T Sanders


An Update on the Status of Industrial Heavy-Duty Preservatives in Europe
2022 - IRG/WP 22-30762
Creosote has been used for over 150 years for preservation of heavy duty industrial timbers such as railway sleepers, utility poles, and agricultural posts. The regulatory regimes in place today across Europe (eg EU & GB Biocidal Products Regulation (BPR)) require a detailed assessment of the environmental and human health properties of wood preservatives at both the active substance and product l...
S Uphill, H Griffiths, M Giannuzzi, A Hughes


Possible regulatory status of treated wood waste and implications
1998 - IRG/WP 98-50101-07
In relation to the European Community or the French regulations, treated wood waste can get two different regulatory status: <<recycled product or fuel>> or <<waste>>. Then, into the waste status, two categories are possible for these residues: <<domestic waste and assimilated>> or <<hazardous waste>>. These different status and categories are import...
G Deroubaix


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Removal of heavy metals from treated wood using biological methods
2005 - IRG/WP 05-50226
Heavy metals were removed from wood treated with copper based preservatives using brown-rot fungus Fomitopsis palustris. The amount of effective elements removed by treatment methods was examined. The relationship between oxalic acid concentration and the amount of heavy metals removed from each treated wood was also investigated. The relationship between fungus weight and removal rate was also in...
Dong-won Son, Dong-heub Lee


Effect of EDTA on removal of CCA from treated wood
2002 - IRG/WP 02-50182
Since substantial amounts of chromated copper arsenate (CCA) remain in the wood for many years, the disposal of CCA-treated wood causes escalating environmental concerns. Additionally, wood waste is generated when treated wood is put into service, for which environmentally benign disposal technologies need to be developed. Novel approaches to remove copper, chromium, and arsenic from CCA-treated w...
S N Kartal


HCB - a new preservative combination for wood pole maintenance
1996 - IRG/WP 96-30122
New combination of heavy creosoted boron (HCB) applied on hardwood and softwood logs at different moisture content revealed successful diffusion of boron in all sapwoods within 7 days and in all sapwoods plus hardwoods within 15 days. The new cost effective paste sterilizes wood through diffusion and suitable for pole maintenance at groundline and above groundline e.g. cut ends, drilled holes, woo...
A K Lahiry


Bioassays for rapid assessment of heavy metal toxicity in seawater
1998 - IRG/WP 98-50112
In evaluating the effect of CCA leachate on the establishment of fouling communities on wood exposed in the sea, three organisms were assessed as biological indicators of heavy metal toxicity. These were two macroalgae, Fucus serratus and Undaria pinnatifida. and the motile protist thraustochytrid, Schizochytrium aggregatum. The choice of these organisms for the tests carried out was based on the ...
C J Brown, R L Fletcher, R A Eaton


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


Emissions from the combustion of wood treated with organic and inorganic preservatives
1994 - IRG/WP 94-50019
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of usage. To obtain more information about the emission properties of treated wood, different materials were incinerated in different furnaces after mixing with ...
T Salthammer, H Klipp, R-D Peek, R Marutzky


Production, function and neutralization of oxalic acid produced by the dry rot fungus and other brown rot fungi
1987 - IRG/WP 1330
The formation of oxalic acid by the wood-destroying fungi causing brown rot, is found to be the key which by hydrolysing the hemicellulose brings the cellulose in the tracheid wall in contact with the cellulase enzymes and yeld watersoluble sugars leaving only a lignin skeleton. To control the pH in the substrate the excess oxalic acid is precipitated to water insoluble calcium oxalate by the dry ...
J Bech-Andersen


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Effect of Heavy Metals on the Expression of Manganese Dependent Peroxidases of Phanerochaete chrysosporium
2010 - IRG/WP 10-10722
This work is part of an ongoing investigation that studies the application of a solution rich in Zn and Mn, obtained from a recycling process, as a preservative for wood. The effects of Zn2+ and Mn2+ on the enzyme-expression level of manganese-dependent peroxidase (MnP) from Phanerochaete chrysosporium was studied by real-time PCR. The glyceraldehyde 3-phosphate dehydrogenase gene (gpd) was used a...
C Ibáñez, M Rabinovich, M Barraco, G Gecchetto, M Cerdeiras


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong