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Laboratory evaluation of borate formulations as wood preservatves to control the subterranean termite coptotermes acinaciformis (isoptera: Rhinotermitidae) in Australia
2001 - IRG/WP 01-30266
The termiticidal efficacy of Borocol (sodium octaborate tetrahydrate), boric acid, bore-ester-7 and tri- methyl borate was evaluated in laboratory bioassays against Coptotermes acinaciformis (Froggatt). Seasoned sapwood blocks of Pinus radiata D. Don, and Eucalyptus regnans (F. Muell) were impregnated with the various borate compounds. There were marked differences in mass loss and mortality rate ...
B M Ahmed, J R J French, P Vinden


Comparison of the effects of borate, germanate and tellurate on fungal growth and wood decay
1992 - IRG/WP 92-1533
The tetra-hydroxy borate ion is known to undergo complexation with polyols and has been shown to inhibit dehydrogenase enzymes in this way. It has been previously suggested that this complexation is responsible for the inhibition of fungal growth and the protection of boron treated timber. Other ions that have the ability to complex with polyols have also been shown to inhibit dehydrogenase activi...
J D Lloyd, D J Dickinson


Inorganic preservatives in wood dust - Cause of nasal cancer?
1997 - IRG/WP 97-50085
Since 1985 dust particles from beech and oak trees have been classified by the Senate Commission of the German Research Council (DFG) as being ,,working materials which are definitely carcinogenic to humans". All other wood dusts, including those from softwoods, are classified as being materials ,,with reasonable suspicion of carcinogenic potential". The carcinogenic principle of action continues ...
A O Rapp, K Brandt, R-D Peek, U Schmitt


The probable mechanism of action of boric acid and borates as wood preservatives
1990 - IRG/WP 1450
The tetrahydroxyborate ion [B(OH)4-] acts by complexation with poly-ols and probably attacks decay fungi through extracellular substrate sequestration; intracellular substrate sequestration; enzyme inhibition; and change in membrane function. Work was carried out to investigate this further and to try to explain certain phenomena observed in the area of boron preservation. The effect of Na borate ...
J D Lloyd, D J Dickinson, R J Murphy


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


Borates as wood preservatives - an environmental, health and safety perspective
1993 - IRG/WP 93-50001-03
Boron compounds are highly effective wood preservatives and have an established safe use in the timber treatment industry. Their widespread background occurrence in nature, low acute mammalian toxicity and useful properties make them versatile active ingredients within today's environmentally aware society. A critical review of health, safety and environmental data on the borates, their u...
J B Rainer


Resistance of wood inorganic material composites against decay fungi and subterranean termites
1996 - IRG/WP 96-40062
Double diffusion process was applied to the treatment of small sound sapwood specimens [20(T) x 20(R) x 10(L) mm³] of Cryptomeria japonica D. Don. The specimens were consecutively dipped in the two kinds of acqueous solutions to form water insoluble deposits within the wood after an expected reaction between the solutes. Following the comparison of deposits formed and treating conditions (tempera...
K Tsunoda, T Yoshimura, M Takahashi, S Hirao, H Usui


Borate diffusion in wood from rods and liquid product. Application to laminated beams
1988 - IRG/WP 3482
In the aim to use borate preservatives (fused rods and boracol) in fields of building construction other than external joineries, tests of diffusion of borate rods and secondary boracol, were carried out on different species of woods exposed to different moisture conditions. Tests were also applied on laminated beams very often subjected to high moisture contents and thus decay of rot fungi. Diffu...
D Dirol


Termites in Uruguay; control, prevention and environment
1991 - IRG/WP 1474
When Prof. La Fage's questionaire on termites was received by 1987, few were aware of termite damage in Uruguay and infestations were not much reported. Further contacts between scientists, operators and homeowners, are now shaping the real threat of termite attack. Before letting the problem faIl in the hands of the layman, with all ist environmental risks, it seemed reasonable to: 1) re...
A Aber, G Baillod


The Protection of Wood with Oxy-aluminium Compounds
2002 - IRG/WP 02-30286
Wood inorganic composites (WICs) containing aluminium compounds were developed and tested in relation to some essential requirements of preservative treated wood. Four different oxy-aluminium treatments were developed and identified according to the final insoluble compounds formed (sodium aluminate, aluminium hydroxide, magnesium aluminate and aluminium borate) in wood. Vacuum impregnation or dou...
F A Ximenes, P D Evans


Emissions from the combustion of wood treated with organic and inorganic preservatives
1994 - IRG/WP 94-50019
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of usage. To obtain more information about the emission properties of treated wood, different materials were incinerated in different furnaces after mixing with ...
T Salthammer, H Klipp, R-D Peek, R Marutzky


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Leachabilty and efficacy of fatty acid derived boron esters as wood preservatives - leachability and efficacy of fatty acid derived boron esters as wood preservatives
2004 - IRG/WP 04-30351
Borates have many advantages as wood preservatives. However, boron is susceptible to depletion under humid conditions and this restricts its outdoor use. In order to reduce boron leachability in treated wood, one of the anticipative approaches is to use organic fixed boron-based preservatives. This study investigated the leachability of six boron ester compounds as potential preservatives. Scots p...
A Mohareb, J Van Acker, M Stevens


Alternatives to preliminary oven-drying prior to spot-testing treated timber for borate or TBTN preservative penetration
1995 - IRG/WP 95-20067
Commonly-used penetration test procedures for timber treated with borate or organotin wood preservatives demand preliminary oven-drying before application of the spot-testing reagent(s), in order to achieve reliable results. The delay of 12 hours or more during oven drying is often a nuisance. Modifications to the spot-testing procedures, involving alternative solvents and acidification conditions...
M J Kennedy, A Zosars, J Norton


The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform...
E Melcher, H-W Wegen


Movement of borates in a range of timber species at various moisture contents
1998 - IRG/WP 98-30181
Borate-based wood preservatives are used in industrial pre-treatment as well as remedial treatment of timbers in situ. In both of these areas, understanding the mobile nature of these compounds is important in optimizing the main benefits of borates. Considerable work has been conducted on movement of borates in dip-diffusion treatment of freshly felled wood, as well as focusing on subsequent diff...
M W Schoeman, J D Lloyd, M J Manning


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Mobility of zinc borate wood composite preservative
1997 - IRG/WP 97-30153
Zinc borate (ZB) is being used as an antifungal and insecticidal wood preservative for flake/strand-based composites. Data is reported on the laboratory and field leaching behavior of ZB when contained in apen flake composites. In general, the performance results correlate with leaching hazard. Although the boron in ZB is more resistant to depletion than in sodium borates, the ZB boron will deplet...
P E Laks, M J Manning


Remedial ground-line treatment of CCA poles in service. A progress report after 28 months' testing
1988 - IRG/WP 3481
Remedial treatments of CCA-treated poles in service with incipient soft rot were carried out with boron rods, boron/glycol solution, boric acid paste, copper/creosote paste and a commercial product (DFCK paste) respectively. The micro-flora before remedial treatment and 6 months after as well as the spread of chemicals in the poles were reported in Document No: IRG/WP/3388. In this progress report...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Basidiospore germination threshold against borate in-vitro may vary between liquid and agar media
1992 - IRG/WP 92-2405
The concentration of disodium octaborate (BAE) which prevented mycelial growth of a common brown rot and 3 white rot fungi was compared to that required to prevent basidiospore germination on malt extract agar. Spore germination sensitivity was lower (50%) for only one of the white rot fungi. However, when spore germination thresholds were tested in malt extract-borate solutions in well slides (no...
E L Schmidt, Ya-Lih Lin


Remediation of environmental impacts related to inorganic wood preservative chemicals using in-situ geochemical fixation
2001 - IRG/WP 01-50166-17
Use of the inorganic wood preservative chemical chromated copper arsenate (CCA) has resulted in several documented cases of soil and ground water contamination at wood treatment plants due to spills or releases of the treatment chemical. The most significant impact from releases of CCA to the environment is related to hexavalent chromium contamination of ground water. This is due to the relative s...
R M Thomasser, J V Rouse


Borates as wood preserving compounds: The status of research in the United States
1989 - IRG/WP 3542
This paper describes the extensive, on-going cooperative research effort among government and university research laboratories and industry to fully evaluate the potential for borates as wood preservatives in the United States. Research is discussed in terms of laboratory evaluations, field testing and mill trials, pilot plant pressure treatment studies, and remedial treatments. Future research pl...
H M Barnes, T L Amburgey, L H Williams, J J Morrell


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Accidental mold/termite testing of high density fiberboard (HDF) treated with borates and N’N-naphthaloylhydroxylamine (NHA)
2003 - IRG/WP 03-10462
High density fibreboard (HDF) was made from beech and pine furnish (50:50) and treated with boric acid (0.1-3%), borax (0.1-3%) or N'-N-(1,8-naphthalyl) hydroxylamine (NHA) (0.1-1%) prior to gluing with urea formaldehyde (UF) resin in order to determine resistance to Eastern subterranean termites (Reticulitermes flavipes Kollar), the most economically important termite species in North Am...
S N Kartal, H H Burdsall Jr, F Green III


International standardisation: a hypothetical case study with stand-alone borate wood preservatives
1998 - IRG/WP 98-20147
The possibility of developing wood preservation standards with a global remit has a number of obvious advantages as well as far reaching ramifications, many of which are undefined as yet. The commercial implications of adopting international standards are clearly considerable, but equally, such a development is likely to focus attention on the conceptual differences in the way that different regio...
M W Schoeman, J D Lloyd


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