Your search resulted in 53 documents. Displaying 25 entries per page.
The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie
Microscopic FT-IR depth profiling study of photo-induced degradation in wood
2001 - IRG/WP 01-20229
FT-IR microspectroscopy was used to monitor the changes in the chemical composition at various depths from the photo-irradiated surface of sugi (Cryptomeria japonica D. Don) sapwood. The radially cut wood face was exposed to artificial solar radiation from a xenon light source at 375 Wm-2 (in a 300 - 700 nm spectral range) for up to 600 h. The IR depth profiling spectra showed that the artificial ...
Y Kataoka, M Kiguchi.
A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick
Effect of fungal degradation on the chemical composition of acetylated beech wood
2003 - IRG/WP 03-40267
This study investigated the impact of fungal attack on the chemical composition of acetylated wood. Beech wood acetylated to different degrees was exposed to decay by the white-rot fungus Trametes versicolor under solid-state fermentation conditions. Laboratory soil-bed assays were also conducted to study the degradation of acetylated wood by soft rot fungi and other soil-inhabiting microorganisms...
H Militz, Dong-won Son, L Gómez-Hernández, R Sierra-Alvarez
The influence of UV and IR radiation on leaching of copper and chromium from preservative-treated pine and spruce
1992 - IRG/WP 92-3687
The influence of artifical UV- and IR-radiation on the leaching of copper and chromium components of a CCB-preservative from freshly treated pine and spruce was evaluated. On small pinewood samples it could be shown, that the leaching of copper and chromium can considerabely be reduced by UV-radiation. A Philips HPA lamp type reduced the leaching most effective. IR-radiation lead to higher leachin...
H Militz
Qualitative and quantitative assessment of chemicals used for wood durability improvement by Near Infrared Spectroscopy
2006 - IRG/WP 06-20349
The Near infrared spectroscopy (NIRS) could be a suitable technique to assess chemicals used for wood durability improvement in the forest products industry. NIRS methodology can be used to obtain results more quickly, less costly and without damaging the wood. In this study, wood samples selected from heartwood and sapwood of Maritime Pine (Pinus pinaster) were prepared to assess the artificial d...
S Zahri, F Charrier, H Baillères, B Charrier
Assaying Pentachlorophenol-treated Wood Using XRF
2007 - IRG/WP 07-20362
A study was conducted to evaluate the effect of oil type on the performance of test posts treated with oil-penta and exposed in DeQueen, AR for forty years in ground contact. The original assays for the poles were done by lime ignition, a practice used sparingly today in treating plants or by independent inspectors, in part due to the complicated analysis procedure and chances for error. XRF ins...
H M Barnes, C R McIntyre, D W Bullock , M H Freeman, G B Lindsey
Use of X-Ray Fluorescence (XRF) Spectroscopy to Determine 4,5-Dichloro-2-n-Octyl-4-Isothiazolin-3-one (DCOIT) in Wood
2007 - IRG/WP 07-20373
Organic preservative based systems are being developed as replacements for the metal based systems. Typically the chemical actives of organic preservative systems are analyzed using HPLC or GC. However, these analytical techniques require complex sample processing and involve relatively long analysis times. In addition the equipment requires maintenance and a skilled operator. One organic preser...
P Walcheski, J Ashmore, D M Laganella
Propolis for wood finishing
2008 - IRG/WP 08-30464
Possibilities of use of propolis for finishing of beech, maple and spruce wood were investigated. In the first part of the paper, an overview of propolis composition, properties and applications is given. 33.6 % mixture of propolis with 96 % ethanol was prepared and the ethanol solution of soluble propolis components (29.0 %) was applied to wooden substrates. Thin propolis films were formed on woo...
F Budija, M Humar, B Kricej, M Petric
Near infrared spectroscopy for the quantification of wood preservatives
2008 - IRG/WP 08-20391
Near infrared (NIR) spectroscopy is a rapid, flexible, inexpensive and non-destructive technology that has many applications, including the evaluation of many wood properties. Initial studies have indicated the potential to apply NIRS for the quantification of wood preservatives. However, further evaluation with borate and azole preservative systems has revealed that NIRS technology is challenged ...
A M Taylor, Seung H Baek, Myong K Jeong, J D Lloyd, J J Morrell
Mechanical and chemical properties of blue stained wood
2009 - IRG/WP 09-10686
Discoloration of wood is frequently caused by blue-staining fungi. In the previous researches there was general opinion that blue-stain fungi do not influence mechanical properties. On the other hand, there were some opposite results reported as well. In order to elucidate this issue, specimens made of Pinus sylvestris sapwood were exposed to two the most frequent and important blue stain fungi Au...
M Humar, V Vek, B Bučar
The Use of Micro-Tensile Testing to Assess Weathering Decay and Oxidative Degradation of Wooden Items
2010 - IRG/WP 10-20433
This paper presents a method to study the weathering performance of wooden items and to assess the oxidative degradation of wood via the Fenton reaction. Weathering resistance and photo-stability of wood was tested using pine wood (Pinus sylvestris) veneer strips measuring approximately 60 µm in thickness. The veneer strips were treated using a reactive chemical to impart surface protection. The ...
C Mai, Yanjun Xie, Zefang Xiao, P D Evans, H Militz
Adsorption of ionic liquids by Scots pine wood (Pinus sylvestris L.) and beech (Fagus sylvatica L.): equilibrium and kinetic modeling
2010 - IRG/WP 10-20447
In this paper methods for the adsorption study of quaternary ammonium-based ionic liquids on Scots pine (Pinus sylvestris L.) and beech (Fagus sylvatica L) are presented. Kinetic and equilibrium adsorption of compounds were evaluated. The equilibrium data fitted very well to the Langmuir adsorption models. The highest correlation coefficients determined from the pseudo-second order kinetic model ...
J Zabielska-Matejuk, A Stangierska, M Kot
Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury
Direct estimation of the durability of high-pressure steam modified wood by ESR-spectroscopy
2010 - IRG/WP 10-40508
Heat generated persistent free radicals have been detected by electron spin resonance measurement of thermally modified wood, prepared by high pressure superheated steam treatment. The specific density of these radicals have been correlated with the durability against basidiomycetes, as measured by the European standard EN113 test. In the lower range of specific radical densities, the found correl...
W Willems, A Tausch, H Militz
Silicon compounds as additives improving alkyd-based wood coatings performance
2010 - IRG/WP 10-40531
The reactivity of cellulose with solvent-born alkyd-based wood coatings supplemented with organosilanes was analyzed. Structural analysis of cellulose subjected to the reaction with organosilanes and following extraction with water was performed using Fourier-transform infrared spectroscopy (FTIR). The analyzed IR spectra comprise bands 1250 cm-1 typical for the SiC group and 800 cm-1 typical for ...
B Mazela, I Ratajczak, K Wichłacz-Szentner, P Hochmańska
Classification of wood materials using Fourier Transform Near Infrared Spectroscopy and multivariate analysis
2011 - IRG/WP 11-20471
A distinction between preservative-treated wood and non-treated wood can be demonstrated by the combination of Fourier Transform-Near Infrared Spectroscopy (FT-NIRS) and Multivariate Analysis (MVA). This technique is non-destructive, quick, easy to use and can be portable. The calibration models for different heavy metals are set up using principal component analysis (PCA) to classify species of t...
M A Bouslamti, M A Irle, C Belloncle, V Salvador, S Hulot, B Caron, E M Qannan
NIR spectroscopy for rapid determination of permethrin or bifenthrin retention in P. radiata sapwood
2013 - IRG/WP 13-20507
Near infrared spectroscopy of permethrin or bifenthrin treated radiata pine (P. radiata D.Don) has been used to develop calibration models to later predict the active retention in unknown samples. Calibrations were developed for both a laboratory NIR and a portable NIR using laboratory-prepared calibration samples at a range of target retention levels. Correlations were established between the act...
R Meder, N Ebdon
Antifungal properties and bonding of menthoxymethylimidazolium ionic liquids with Scots pine wood
2013 - IRG/WP 13-30627
Antifungal activities of five chiral ionic liquids - menthoxymethylimidazolium derivates against brown-rot decay fungus (Coniophora puteana), white-rot decay fungus (Trametes versicolor) and blue-stain fungus (Sclerophoma pithyophila) were determined using screening agar-plate method. Results from antifungal tests revealed that 1-butyl-3- menthoxymethylimidazolium chloride exhibited the stronges...
J Zabielska-Matejuk, J Feder-Kubis, A Stangierska
Effectiveness of Copper Indicators in Treated Wood Exposed to Copper Tolerant Fungi
2014 - IRG/WP 14-20554
Wood treated with a copper based wood preservative will typically turn a green color. While the depth of copper penetration can be readily discerned from the green color of the copper it is standard practice in research and commercial treating plants to make use of a color reagent such as Chrome Azurol S, Rubeanic acid or PAN indicator to reveal the penetration more clearly. When copper treat...
L Jin, K Brown, A Zahora, K Archer
Visualization of gold/silver nanostars in wood by surface enhanced Raman spectroscopy
2014 - IRG/WP 14-30653
Nanotechnology is a fast growing up-to-date technology and ventures expeditiously in the wood preservative market. However, there is still a huge lack of understanding about the interaction and incorporation of nanoparticles (NSs) in wood. Surface-enhanced Raman scattering (SERS) offers unique advantages as an analytical tool with a high selectivity and sensitivity without matrix interference. Her...
C Geers, L Rodríguez-Lorenzo, M Placencia Peña, P Brodard, T Volkmer, B Rothen-Rutishauser, A Petri-Fink
A review on prediction methods of wood natural durability
2017 - IRG/WP 17-10892
Natural durability of timber may be defined as “inherent ability of timber to attack by wood destroying organisms (bacteria, fungi, insects, marine borers) without preservative treatment. On the base of biological tests, EN-350-2 standard (Afnor, 1994), describe the classification of wood species according to their natural durability. But these specifications are not adapted in the case of wood ...
N Amusant, C Flora, J Beauchène, E Houël, C Duplais
Monitoring of wood biodeterioration by infrared spectroscopy
2017 - IRG/WP 17-20607
The susceptibility of wood to deterioration by rotting fungi is intrinsically related to its chemical composition and the environmental conditions at its place of use, and if not detected in time, can cause enormous financial losses. The process of wood biodeterioration by decay fungi can be evaluated through laboratory accelerated test, in specific field tests, or through non-destructive techniqu...
E Meneses Oliveira, A Florian da Costa, J W Batista Braga
Natural durability, ethanol-toluene extractives and phenol content prediction of eight wood species from Madagascar using NIRS multispecific models
2018 - IRG/WP 18-10926
Madagascar has nearly 4000 species of trees and shrubs, but wood properties of only 200 species have been studied. Some properties, such as the natural durability or chemical composition are of importance for adequate and optimal use of these timber species. Since durability tests take long time and chemical analyzes can be very expensive, alternative methods such as near infrared spectroscopy (NI...
A R Razafimahatratra, H Rakotovololonalimanana, M-F Thévenon, C Belloncle, G Chaix, T Ramananantoandro
Difference of wood decay manner between brown-rot species
2019 - IRG/WP 19-10938
Wood blocks (Cryptomeria japonica) which were decayed by a Polyporales white-rot fungus (Trametes versicolor) and brown-rot fungi (Fomitopsis palustris, F. pinicola, and Wolfiporia cocos), respectively, were analyzed by X-ray diffraction and infrared spectroscopic methods followed by multivariate analysis. In the analyses, the differences in the cellulose crystallinities and infrared spectral patt...
R Kondo, Yo Horikawa, S Nakaba, K Ando, M Yoshida