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Classification of wood materials using Fourier Transform Near Infrared Spectroscopy and multivariate analysis
2011 - IRG/WP 11-20471
A distinction between preservative-treated wood and non-treated wood can be demonstrated by the combination of Fourier Transform-Near Infrared Spectroscopy (FT-NIRS) and Multivariate Analysis (MVA). This technique is non-destructive, quick, easy to use and can be portable. The calibration models for different heavy metals are set up using principal component analysis (PCA) to classify species of t...
M A Bouslamti, M A Irle, C Belloncle, V Salvador, S Hulot, B Caron, E M Qannan


A comparison of inductively coupled plasma spectroscopy and neutron activity analysis for the determination of concentrations in wood
1993 - IRG/WP 93-10048
As wood decays the ionic composition changes, with increases often being seen in the concentrations of Ca, Mg, Fe, Mn and sometimes K. The concentration of eight cations in red spruce sapwood and heartwood samples was determined independently by inductively coupled plasma spectroscopy (ICP) and by neutron activation analysis (NAA) as part of an effort to standardize our analytical procedures and c...
J Jellison, J Connolly, K C Smith, W T Shortle


Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Formation of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) during the combustion of impregnated wood
1995 - IRG/WP 95-50040-19
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) a...
T Salthammer, H Klipp, R-D Peek


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


Uptake of copper by mycelium of wood decay fungi growing on copper S-substituted thioglycolate containing nutrient media
1998 - IRG/WP 98-10291
Mycelia of Trametes versicolor, Coniophora puteana and Poria monticola were grown on potato dextrose agar (PDA) media, containing various concentrations of copper N,N-dimethyldithiocarbamoylacetate (which may be regarded as a copper S-substituted thioglycolate). The tested copper compound revealed relatively low fungicidal activity. After 13-18 day growing period, we determined concentrations of a...
M Humar, M Petric, F Pohleven, P Kalan


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Silicon compounds as additives improving alkyd-based wood coatings performance
2010 - IRG/WP 10-40531
The reactivity of cellulose with solvent-born alkyd-based wood coatings supplemented with organosilanes was analyzed. Structural analysis of cellulose subjected to the reaction with organosilanes and following extraction with water was performed using Fourier-transform infrared spectroscopy (FTIR). The analyzed IR spectra comprise bands 1250 cm-1 typical for the SiC group and 800 cm-1 typical for ...
B Mazela, I Ratajczak, K Wichłacz-Szentner, P Hochmańska


Effect of acetylation on decay resistance of wood against brown-rot, white-rot and soft-rot fungi
1989 - IRG/WP 3540
Effect of acetylation on decay resistance of wood was investigated using wood blocks of Cryptomeria japonica, Pinus densiflora, Albizia falcata and Fagus crenata. Blocks were treated with uncatalyzed acetic anhydride for different lengths of time and exposed to Tyromyces palustris, Serpula lacrymans, Coriolus versicolor and unsterilized soil. The action of OH-radical on acetylated wood was also ex...
M Takahashi, Y Imamura, M Tanahashi


Detection of feeding behaviour of termites using AE monitoring
1991 - IRG/WP 1514
Using acoustic emission (AE) monitoring, the feeding activity of the termite inhabiting a wood specimen was investigated. The amplitude and the rate of AE from the specimen of Coptotermes formosanus Shiraki was larger than that of Reticulitermes speratus Kolbe. The AE event rate was higher in the specimen with soldiers than without soldiers. The AE event rate decreased according to the resistance ...
Y Imamura, M Tokoro, M Owada, Y Fujii, M Noguchi


Modélisation sur maquette du rejet accidentel d'un gaz toxique et inflammable dans l'atmosphere - Emission de type "bouffée d'oxyde d'éthyléne [Water model simulation of toxic and flammable gases in the environment on industrial sites - Puff of ethylen oxide]
1990 - IRG/WP 3576
M Milhe


Rates of emission from CCA-treated wood in the marine environment: measurement, modelling and requirements for further research
2001 - IRG/WP 01-50166-12
Accurate estimates of rates of emission of leachate from preservative treated wood are crucial for realistic predictions of the environmental impact of its use in maritime construction. Estimates are available for some commonly used preservatives, but these vary widely. Though variable, these measurements suggest that emission generally decreases exponentially with time. Part of the variation is d...
S M Cragg, C J Brown, R A Albuquerque, R A Eaton


An insight into brown rot decay of timber as revealed by 13C CP/MAS NMR
1985 - IRG/WP 1259
L E Leightley


A review of environmental emissions from building and construction materials in comparison with preserved wood
2005 - IRG/WP 05-50224-11
A review of the public domain literature concerning emissions to the environment from materials which are used in the construction of buildings (e.g. Concrete, Asphalt, Galvanised Steel), in comparison with preserved wood, and a review of the approaches taken by the construction sector in assessing the risk from environmental emissions, in comparison with the approaches taken by the wood preservat...
E F Baines


Utilization of plasma treatments in the field of wood protection
2021 - IRG/WP 21-40912
Plasma treatments have been used for modification of surfaces of wood and wood-based materials for some decades and solutions were developed to apply it for wood protection. This contribution aims to present the background, introduce the available plasma technology, and to give an overview on the typical applications and benefits....
S Dahle, H Militz


Exploring the potential for plasma-assisted coating at atmospheric pressure for wood protection
2023 - IRG/WP 23-40982
J Profili, G Laroche


Quantitative determination of Chromium: A comparison of three instruments
1995 - IRG/WP 95-50053
A comparison is made between three instruments for measuring levels of chromium in the leachate of copper-chrome-arsenic (CCA) treated timber. These include an atomic absorption spectrophotometer, an inductively coupled plasma spectrometer and the RQflexâ. The RQflexâ is a new hand-held instrument which measures chromium by dipping a ReflectoquantÒ strip into the leachate and inserting the stri...
S Walley, P R S Cobham, P Vinden


Methane emission by termites, Coptotermes formosanus Shiraki
1995 - IRG/WP 95-10099
Association of methanogenic bacteria only with the smallest-sized symbiotic protozoa Spirotrichonympha leidyi Koidzumi was evidenced by epifluorescence microscopic observations. Workers, which were collected from a laboratory colony and placed in a test container with water supply emitted methane at a relatively constant rate with a peak of 0.76 nmol/termite/hr within the first 72 hrs after the in...
K Tsunoda, W Ohmura, M Tokoro, T Yoshimura


Use of fluorescent-coupled lectins as probes for studying fungal degradation of wood
1986 - IRG/WP 1288
The ability of the fluorescent-coupled lectins wheat germ agglutin (WGA) and Concanavalin A (Con A) to react with selected Basidiomycetes, Ascomycetes, and Fungi Imperfecti was evaluated using pure cultures of 35 fungi grown on malt extract agar. WGA, which binds specifically to the n-acetylglucosamine residues found in fungal chitin, reacted with nearly all hyaline fungal structures but did not r...
J J Morrell, R L Krahmer, L C Lin


Effect of Trichoderma harzianum on induction of laccase by Trametes versicolor on ponderosa pine sapwood
1996 - IRG/WP 96-10177
Trichoderma harzianum has long been studied as a possible biocontrol agent against wood degrading fungi, and has provided varying degrees of protection in several European field trials. In laboratory trials, however, this fungus appears to be less active against white rot fungi. This characteristic was studied using a wood wafer sandwich procedure which simultaneously expose ponderosa pine sapwood...
E A Canessa, J J Morrell


Measurement of VOC emissions from curative treated wood: A new emission test chamber
2001 - IRG/WP 01-50166-13
A poor indoor air quality (IAQ) is now recognized as a potential factor affecting occupants health. There are three basic strategies to improve IAQ: source control, improvement of the ventilation and use of air cleaners. Usually, the most efficient way to improve IAQ is to eliminate the different pollutant sources or to reduce their emissions. In order to precisely measure emissions from building ...
F Maupetit, O Ramalho, C Yrieix


Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley


How to determine what is a realistic emission from treated wood - basic reflections
1998 - IRG/WP 98-50105
Emissions from treated wood occur by evaporation and by leaching. Up to date by far more experience exists on leaching tests than on evaporation test. The methods applied will be of interest to give answers to the questions about the quantity of possible emissions. Standardisation on leaching started very early. One of the first attempts to quantify the effect of leaching on the remaining efficacy...
H Willeitner, R-D Peek


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


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