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Soluble nutrient influences on toxicity and permanence of CCA preservatives in wood
1980 - IRG/WP 3144
The influence of soluble carbohydrate and nitrogenous components concentrated at evaporative surfaces of wood on the toxicity and permanence of CCA preservatives has been examined using soil-burial techniques. Nutrient concentrations in lime (Tilia vulgaris Hayne) have been shown to be associated with reduction of toxic limits of preservatives to an extent in which a 100% increase in preservative ...
B King, G M Smith, A Bruce


Difference of CCA efficacy among coniferous wood species
1990 - IRG/WP 3601
Wood blocks of Cryptomeria japonica, Tsuga heterophylla, and Pinus radiata successively extracted with n-hexane, ether, and methanol were treated with various concentrations of CCA type 3, which were subjected to the decay by Tyromyces palustris. The weight loss were different among species and kinds of extraction. Cryptomeria japonica treated with CCA had higher fungal resistance than Tsuga heter...
K Yamamoto, M Inoue


Changes in fat and moisture contents, and nitrogen fixation in laboratory maintained termites
1984 - IRG/WP 1242
Orphaned groups of termites of Coptotermes acinaciformis and Mastotermes darwiniensis were maintained in the laboratory for several months on two dietary regimes, and changes in their fat contents, moisture contents and nitrogen fixation rates were examined. There were no significant feed or feed time effects for either species. For Coptotermes acinaciformis, there was a highly significant time ef...
J R J French, P J Robinson, L G Turner, P J Pahl


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


Proposed methodology for the assessment of safety indexes
1990 - IRG/WP 3562
Safety Indexes (SI)s are developped on the same concept as Efficacy Indexes (EI)s: EIs are retentions of wood preservatives (percentages of the critical values "efficacy") which are presumed efficient for a given biological class of risk. In the same way, SIs are retentions of wood preservatives (percentages of the critical values "safety") which are taken as acceptable for human health and the ge...
G Ozanne


Application of radio frequency heating to accelerate fixation of CCA in treated round-wood
1999 - IRG/WP 99-40133
The potential of radio frequency heating to accelerate the fixation of chromated copper arsenate (CCA) in treated round-wood was assessed. Pre-dried Douglas-fir and western red cedar round-wood sections were pressure treated with CCA in a pilot plant retort, after which they were placed individually in a pilot radio frequency (RF) chamber. Based upon the color reaction of chromotropic acid with he...
Fang Fang, J N R Ruddick


Problems of fixation of CCA-preservatives in palm-wood
1985 - IRG/WP 3338
Palm-wood may be used for posts and poles where it needs proper treatment for long time use. Based on observations by W. Killmann on low CCA-fixation in palm-wood, samples of Jubaea-palm grown in a Greenhouse at Hamburg, have been treated in two different series with a 4% solution of CCA-type B. After 1-16 weeks of storage the blocks were split into sticks of 1-2 mm² and leached. In all series 50...
H Willeitner, K Brandt


Radical changes in the requirements for more safe pressure impregnation in the Nordic countries in 1988
1990 - IRG/WP 3581
After introduction of quality control schemes and standards in the Nordic countries during the seventies, the first radical change of the standards and practice of work took place after pressure from the labor unions and authorities in 1988 and 1989 in Denmark and in Sweden. A new class of preservation with less retention for out of ground contact use was introduced, fixation times were prolonged ...
B Moldrup


Accelerated fixation of CCA in borak bamboo (Bambusa balcooa Roxb.) of Bangladesh
2001 - IRG/WP 01-40193
CCA-C fixation study on impregnated (6% CCA solution), then boiled, oven-dried, normal, air-dried and steamed bamboo slices of air-dried borak bamboo (Bambusa balocca Roxb) of Bangladesh, revealed almost complete fixation in steamed (accelerated fixation) and air-dried (3 weeks, slow fixation) bamboo slices compared to moderate to slow fixation in boiled, oven-dried, normal and 24h air-dried slice...
A K Lahiry


A discussion of current theories concerning CCA fixation
1983 - IRG/WP 3238
The understanding of the fixation mechanism of CCA and related preservatives in wood has been greatly improved by a significant series of recent scientific papers. In view of recent concerns in New Zealand regarding the long-term efficacy of CCA in high decay-hazard situations, it was considered appropriate to review this recent work and to contrast it with theories presented by previous workers....
D V Plackett


A simple leaching procedure for in-plant monitoring of CCA fixation
1993 - IRG/WP 93-30023
A simple leaching test is described to quantitatively estimate the extent of fixation of chromated copper arsenate (CCA) preservative treated wood products. It is based on the reaction between diphenylcarbazide and unreacted hexavalent chromium leached from borings taken from treated wood during the fixation process. The test requires about 20 minutes to complete and can be set up in a treating pl...
P A Cooper, Y T Ung


Assessment of losses of wood preservatives from treated wood by leaching into the environment
1993 - IRG/WP 93-50001-13
Wood preservative chemicals may be lost from treated timber by leaching into water or soil. The degree to which this might occur and its effect on the environment is difficult to assess quantitatively due to the absence of appropriate test methods. This paper describes work to assess test methodology capable of allowing the rates of loss of wood preservative from treated timber to be quantified. T...
R J Orsler, G E Holland


Nitrogen content of soils at field sites
1981 - IRG/WP 1133
Nine participants in the Collaborative Field Experiment submitted samples for nitrogen analysis to this laboratory as requested by Leightley (IRG/WP/3162). These arrived in a variety of conditions e.g. wet, dried, sterilised and unsterilised and sometimes spent a considerable time in transit. Soils varied in cellular fraction organic matter content, some were obviously sieved prior to postage whil...
B King, G Mowe


nvestigation of anomalous fixation and leaching of CCA-treated red maple
2004 - IRG/WP 04-30341
The fixation of CCA-C preservative was investigated in red maple sawdust (Acer rubrum L.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. The effect of water-soluble extractives on the course of fixation was evaluated comparing the non-extracted with pre-extracted samples treated to 6.4 and 30 kg/m3. Leaching of the CCA components was monitored after complete fixation for all retentions. Fix...
S Radivojevic, P A Cooper


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 5. Treatment of Sitka spruce and Scots pine
1999 - IRG/WP 99-40136
The suitability of the MPP Process for CCA treatment and accelerated fixation of species other than Radiata pine was assessed by pilot plant trials on UK-grown Sitka spruce (Picea sitchensis) and Scots pine (Pinus sylvestris). Pressure and vacuum kickbacks of spruce (14 l/m3) and Scots' pine (122 l/m3) were both substantially lower than that generated during treatment of radiata pine (369...
M E Hedley, K Nasheri, G Durbin


Proposals for a vermiculite burial soft rot test method
1980 - IRG/WP 283
J G Savory, J K Carey


A short note on fungal decay in K33-treated poles
1982 - IRG/WP 1169
Soft rot cavities and erosion of the lumen have been found in K33-treated Pinus sylvestris poles from the years 1956-66 by microscopic studies. Poor treatment quality has been proved for some of these poles. The microscopy showed an unusual pattern of attack, and pre-treatment decay is suspected but not yet proved. Sounding the poles and using the Pilodyn indicated decay, but poking did not. Quant...
H Friis-Hansen


Collaborative soft rot tests: Results of analyses of soil samples
1976 - IRG/WP 263
C R Levy


The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures....
P Vinden


The influence of previous anti-blue-stain preservative treatments on the fixation of CC in spruce
1997 - IRG/WP 97-30134
Freshly cut and kiln dried spruce boards were treated with 4 different anti-blue stain preservatives (ABP). After a period of 10 days allowing the samples to dry and fixate, the samples were treated with CC (chromium, copper formulation) using a vacuum pressure cycle. After impregnation the wood was steam fixed. A submersion leaching test showed differences in the leachable quantity of copper and ...
M Van der Zee, W J Homan


A fixation model, based on the temperature dependence of CCA-C fixation
2000 - IRG/WP 00-40163
A model was prepared for the fixation of 1% CCA-C in red pine that allows the prediction of extent of fixation based on the temperature history of the treated wood following pressure treatment. The reaction kinetics of the rapid initial reaction and the slower main reaction were characterized using the Van t'Hoff equation. The initial reaction could be represented by a 10th order chemical...
P A Cooper, K M F Kazi, Jianbin Chen, Y T Ung


Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


The variation in electrical resistance in the CCA-treated wood during the fixation
1989 - IRG/WP 3554
The curve commonly used in Scandinavia for describing the fixation period at different temperatures for CCA-impregnated wood is based on investigation by Dahlgren on the pH-variations in a mixture of sawdust and preservative solution. As far as we know there is no such investigation on solid wood. We have therefore measured the electrical resistance in CCA-treated solid wood to see if this will di...
F G Evans, B Nossen


CCA fixation experiments. Part 1
1989 - IRG/WP 3504
A method of squeezing solution from CCA treated wood that has not been dried at various times after treatment appears to be useful in following the fixation of CCA in wood. Experiments confirm that temperature governs the rate of fixation....
W S McNamara


Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles


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