Your search resulted in 30 documents. Displaying 25 entries per page.
Organic solvent preservatives. Essays on the ecotoxicology of new formulations
1991 - IRG/WP 3642
The knowledge on the ecotoxicological profile of wood preservatives become more and more important. The acute toxicity against aquatic organisms was examined for oil-borne preservatives, based on combinations of new fungicides (Tebuconazole, Propiconazole, Dichlofluanid) and insecticides (Permethrin, Cyfluthrin). These tests were conducted with fish, daphnia and algae. In principle the different f...
H-W Wegen
Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell
Current models used by the European Health Authorities to evaluate the volatilization of active ingredients from treated wood used inside dwellings. A case study: Volatilization of azaconazole and propiconazole from treated wood
1990 - IRG/WP 3565
The use of wood preservatives inside houses may result in measurable aerial concentrations of active ingredients. These airborne contaminants may be inhaled by the inhabitants over periods lasting from a couple of days to several months. To assess the potential health hazard of preservative residues in the air, various risk-assessment models have been worked out. Three schemes, currently used by t...
A R Valcke, L Van Leemput
Triazoles: Synergism between propiconazole and tebuconazole
1995 - IRG/WP 95-30092
The synergistic action of the two triazoles propiconazole and tebuconazole against wood rotting fungi can clearly be demonstrated by determination of toxic values according to Standard EN 113. The results show that by combining both triazoles a better balanced spectrum of activity can be achieved. The reduction of the toxic values against the white rot fungus Coriolus versicolor (toxic values of t...
H-U Buschhaus, A R Valcke
Physiologic response of Phanerochaete chrysosporium to exposure to triazole fungicides
1994 - IRG/WP 94-10066
Triazoles are increasingly important fungicides which are employed for a variety of applications included wood protection. Several recent studies suggest that white rot fungi are more tolerant of triazole compounds than other wood degrading fungi. Cultural studies using a white rot fungus, Phanerochaete chrysosporium, and 0.2 or 0.8 ppm of tebuconazole or propiconazole suggested that mycelial dry ...
J J Morrell, R K Velicheti
Evaluation of chlorpyrifos and fungicides alone and in combination for control of insects and fungi in wood and wood composites
1998 - IRG/WP 98-30187
Wood composites are rapidly being adapted for use in exterior applications. The incorporation of a preservative system to prevent fungus and insect attack is necessary with most exterior composites. Research studies were reviewed pertaining to organic preservative systems based on Lentrek* insecticide wood treatment which contains the active ingredient chlorpyrifos alone and in combination with te...
M P Tolley, P E Laks, R Fears
Xylophene AS™, the challenge of developing a modern antisapstain formulation for the french market
2000 - IRG/WP 00-30250
In France Sodium Pentachlorophenol (NaPCP) has been used for more than 40 years for the protection of freshly cut and unseasoned lumber. The French sawmill industry requires a protection of 6 months and maximum 10% surface infection by moulds and/or sapstain fungi. However, this active substance did have some serious environmental flaws and no authorisation was granted for a direct contact of NaPC...
E Wozniak, L Cubizolles, N Delourme Fonseca, A R Valcke, J Gors
Experiences with the OECD guideline proposals for the estimation of emissions from preservative-treated wood in the environment
2004 - IRG/WP 04-50209
The practicability of 2 CEN proposals for OECD guidelines on the estimation of emissions from preservative treated wood by laboratory methods for either wood held in storage after treatment and for wooden commodities that are not covered, and are not in contact with ground (guideline 1) or
wooden commodities that are not covered and are in contact with ground, fresh water or seawater (guideline 2...
U Schoknecht, R Wegner, E Melcher
Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz
Which substrate to use in a laboratory test with soft rot micro-fungi: vermiculite or unsterile soil?
1991 - IRG/WP 2372
A draft European Standard is being proposed by CEN TC 38 in which a vermiculite-burial and a soil-burial test to be carried out in succession are required. Various experiments with both procedures were set up with CCA, CC and propiconazole-formulations. The results show that vermiculite and unsterile soil yield comparable threshold values against soft rot. This poses the question of whether a two-...
A R Valcke
A study of the efficacy of antisapstain formulations containing triazole fungicides
1993 - IRG/WP 93-30021
This document gives efficacy data for antisapstain formulations based on triazole fungicides. A rapid (3 week) laboratory screening method was used to determine the efficacy of six triazole fugicides alone and in combination with other fungicides. Field trials were carried out of three promising formulation types, each comprising a triazole compound as the primary fungicide in combination with a s...
R N Wakeling, N P N Maynard, R D Narayan
Suitability of propiconazole (R 49362) as a new-generation fungicide
1989 - IRG/WP 3529
Propiconazole (R 49362), an anti-fungal triazole-compound of Janssen Pharmaceutica, has been extensively tested to determine its potential use as a wood preserving fungicide. Various tests in both private laboratories and official institutes indicate a good activity against Basidiomycetes (brown and white rot) and Ascomycetes (blue stain-in-service). The active ingredient seems very resistant to w...
A R Valcke
Stability, performance and distribution of propiconazole (R 49362) in acceleratedly aged wood
1991 - IRG/WP 3647
The permanency of propiconazole (R 49362 - WOCOSENÔ technical - Janssen Pharmaceutica) in wood was examined in an 18 month storage test, an evaporative ageing study (EN 73), a volatilization stress experiment, and water-leaching studies (EN 84). The biological efficacy against two brown rot fungi: Coniophora puteana BAM Ebw. 15 and Gloeophyllum trabeum BAM Ebw. 109 was assessed according to the E...
A R Valcke, M Stevens
The influence of carrier fluid type on the efficacy of a wood preservative against cavity forming soft rot
2000 - IRG/WP 00-30244
Propiconazole was applied to Scots pine sapwood (Pinus sylvestris) and beech (Fagus sylvatica) using three different carrier systems selected on their varying ability to swell timber. The effects of microdistribution on the activity of cavity forming soft rot fungi were examined to determine the practical benefits of using swelling and non-swelling carriers with this active ingredient. Efficacy of...
P A Hodges
Accelerated testing for out of ground contact using natural biological preconditioning
1996 - IRG/WP 96-20088
Small blocks made of Scots pine sapwood were treated, buried in vermiculite and exposed to natural microbial colonisation during outdoor exposure prior to laboratory decay testing. Periodic microbial isolations, moisture content, permeability and weight loss tests were also conducted. Bacteria and moulds colonised the vermiculite and miniblocks well. Aureobasidium pullulans was common on TnBTO tre...
S Molnar, D J Dickinson, R J Murphy
Microbial ecology of treated lap-joints exposed at Hilo, Hawaii for 12 months
1996 - IRG/WP 96-20089
Lap-joints made from Southern yellow pine treated with ACQ, DDAC or Propiconazole were exposed and sampled over 12 months. TnBTO treated Lap-joints were later exposed as a standard treatment. The moisture content of the joint area remained at 23% to 28%, but, away from the joint, varied between 20% to over 30%. Untreated samples had higher moisture contents and there was little difference between ...
S Molnar, D J Dickinson, R J Murphy
Microbial ecology of treated Lap-joints exposed at Hilo, Hawaii for 24 months
1997 - IRG/WP 97-20107
This paper is a continuation of previous work reported in IRG/WP 96-20089 by Molnar et al. (1996) in which Lap-joints, made from Southern yellow pine and treated with ACQ, DDAC or propiconazole were sampled over 12 months exposure at Hilo, Hawaii. 18 and 24 month samplings have since taken place and are reported here. TnBTO treated Lap-joints made of scots pine which were exposed later as a standa...
S Molnar, D J Dickinson, R J Murphy
The use of organic wood preservatives in ground contact and the suitability of laboratory test procedures to determine their efficacy
1999 - IRG/WP 99-20175
Organic fungicides, such as propiconazole, have proven to be highly effective when used as a co-biocide in recently developed wood preservative formulations. They have however been ineffective when used as a stand alone preservative, particularly when used in ground contact (European Hazard class 4). Previous research, using the test methods of ENV 807 (1993), provided conflicting evidence regardi...
I J Herring, D J Dickinson
Investigation of new wood preservation formulations based on synergies between antioxidant, 2-HPNO and Propiconazole
2006 - IRG/WP 06-30401
Wood degradation by fungi is a complex phenomenon taking place in part through oxidative reactions involving many oxidizing agents like free radicals and hydroperoxide. In order to develop novel and more environmentally benign preservative systems, mixtures of Propiconazole and antioxidants with different stabilization mechanisms were investigated to detect possible synergies allowing to reduce th...
B Bakhsous, S Dumarçay, E Gelhaye, P Gérardin
Wood decay fungi from New Zealand ‘leaky’ buildings: PCR identification and laboratory decay tests of wood preservative-treated Pinus radiata (Part 1)
2007 - IRG/WP 07-10620
Fungi colonising Pinus radiata D. Don framing timber of ‘leaky’ New Zealand buildings were isolated to produce pure cultures. Mycelia from these cultures on agar media were collected to extract DNA. To identify the fungi to the species level, polymerase chain reaction (PCR) with primer pairs ITS1-F and ITS4 were performed followed by sequencing of the internal transcribed spacer (ITS) region. ...
D Stahlhut, R L Farrell, R Wakeling, M Hedley
Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal
Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang
Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen
Degradation of Carbon-Based Preservatives by Black-stain Fungi
2010 - IRG/WP 10-30533
Some black-stain fungi are known to exhibit resistance to carbon-based preservatives. However, the cause of this resistance is unclear. The fungi may have mechanisms to tolerate these chemicals, or they may be able to degrade and detoxify them. Fungi capable of degrading carbon-based preservatives are of interest for possible bioremediation of carbon-based preservative-treated wood at the end of i...
R Stirling, P I Morris
Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites