IRG Documents Database and Compendium


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Solvent drying and preservation of timber
1977 - IRG/WP 381
Processes which combine drying and preservation are first reviewed. Some preliminary experiments are then described in which blocks of green Sitka spruce sapwood were immersed, in a solution of tributyltin oxide (TBTO) in methanol at 60°C. Satisfactory penetration of the preservative and exchange of methanol and water occurred in a few hours. The methanol was removed rapidly from the wood by evap...
J A Petty


JWPA method for testing effectiveness of surface coatings with preservatives against decay fungi
1981 - IRG/WP 2164
In 1979 JWPA established a new method for testing effectiveness of surface coatings in accordance with practical use of preservative-treated lumber. Comparing the new testing method with JIS A 9302, a few new trials - size of wood specimen, weathering procedure, and decay-test procedure - are incorporated....
K Tsunoda


Improved techniques designed for evaluation of fungicides in soil for control of dry rot fungus Serpula lacrymans
1985 - IRG/WP 2238
Improved techniques provide a laboratory method for the evaluation of chemicals in soil for control of dry rot fungus Serpula lacrymans. Results with their application to three chemicals were reported. These techniques are useful to eliminate chemicals lacking the necessary toxicity and weatherbility for dry rot control when the chemicals have been applied to the soil....
M Takahashi, K Nishimoto


Studies on accelerated ageing procedures with TBTO-treated wood
1985 - IRG/WP 2244
The efficacy of various procedures for accelerated ageing of organotin based wood preservatives in treated wood has been investigated. It was found that leaching of the treated wood samples in water according to the European Standard EN 84 was not satisfactory for organotin based preservatives and is probably also unsuitable even for other types of organic solvent preservatives. Keeping tributylti...
J Jermer, M-L Edlund, B Henningsson, W Hintze


The evaluation of synergistic effects of chemicals on fungicidal efficacy in crossed-paper tests
1991 - IRG/WP 2383
The mixing effects of wood preservatives were evaluated using the crossed-paper technique. Two filter paper strips (0.7 x 8 cm²) were treated by soaking with different chemicals [fungicides, a termiticide (chlorpyrifos or phoxim), a surface-active agent, a synergistic agent, and a stabilizer], and placed at right angles to each other on a fully grown mycelial mat of a test fungus in a Petri dish....
Dong-heub Lee, K Tsunoda, M Takahashi


Detoxification of preservatives: Tri-n-butyltin oxide as a biocide
1982 - IRG/WP 1156
T E Dudley-Brendell, D J Dickinson


Surveillance médicale des personnels exposés aux produits de préservation du bois
1990 - IRG/WP 3588
J-C Aubrun


A direct basidiomycetes test methodology. Report on an EWPM ring test
1988 - IRG/WP 2306
Results of an EWPM-ring test using a direct basidiomycetes test methodology are reported. The test is caracterized by using big test blocks and infestation by infected wood under unsterile conditions. The test procedure needs further development work, but the results are so promising that co-operation with CEN and EHC is initiated with the purpose of recognition and standardization....
B Jensen


Fungicidal combination products
1987 - IRG/WP 3426
Due to the increased pressure on some of the established fungicides used in wood preservation, possible alternative products become more interesting. The requirements for new chemicals are mainly lower toxicity and greater environmental acceptability. However the efficacy to target organisms should be as good as that of the currently used ones, preferably better. A possibility for progress in this...
H A B Landsiedel


Accelerated ageing of preservatives in treated wood
1988 - IRG/WP 3476
New preservatives are tested in the laboratory and often in field tests before they are used commercially. Some preservatives, however, tested in the laboratory do not show the expected stability when used in service. The differences between laboratory tests and practical use can never be completely eliminated but must be minimized as far as possible by relevant testing methods. Studies of the eff...
M-L Edlund, B Henningsson, B Jensen, C-E Sundman


Co-operative research project on L-joint testing. Progress report to March 1988
1988 - IRG/WP 2315
Further sets of data received from CTFT (France), BAM (Germany) and PRL (UK) after 46-48 months exposure and STU (Sweden) after 22 months exposure are presented and discussed in conjunction with data reported previously. Colonisation and attack of the L-joints has progressed with increasing exposure period. The new data are generally in agreement with those presented previously and the major diffe...
J K Carey, A F Bravery


An investigation into the stability of TBTO in LOSP-treated radiata pine
1987 - IRG/WP 3459
Nuclear magnetic resonance (NMR) spectroscopy and reverse phase paper chromatography were used to characterise the organotin compounds found in radiata pine treated with bis (tri-n-butyl) tin oxide (TBTO). Preliminary results indicate that the preservative is remarkably unstable in wood after light organic solvent preservative (LOSP) treatment. Significant decomposition of TBTO occurs in a matter ...
K J Archer, R Meder


Biological and chemical observation on the early fungal colonization of TBTO treated Swedish redwood stakes
1984 - IRG/WP 3311
Data on the early fungal colonization of Swedish redwood stakes, impregnated with 1% TBT0 / 0.5% dieldrin solution, both by double vacuum impregnation and immersion processes are presented. Results of chemical analyses of wood samples from the outer 1 mm of separate painted and unpainted stakes, exposed over the same twelve month period, are also discussed....
R Hill, A H Chapman, A Samuel, K Manners, G Morton


The window joinery test hut
1975 - IRG/WP 257
D F Purslow


Some experiments with hexabutylditin against fungi
1977 - IRG/WP 388
The investigation was carried out in 1972 and 1973 to collect experimental data about the poisonousness of hexabutylditin (HBDT) against the woodrotting fungi Coniophora puteana (Coniophora cerebella), strain 15, and Chaetomium globosum, strain hexabutylditin was being manufactured by the Organisch Chemisch Instituut (O.C.I.) TNO, at Utrecht....
J W P T Van der Drift


Spot-tests for TnBTO and AAC preservatives
1984 - IRG/WP 3279
Nineteen indicator systems were examined as potential alternative spot-tests for preservative penetration in TnBTO- (bis-tributyltin oxide) or AAC- (alkyl ammonium compound) treated wood. Results indicated phenylfluorone as an acceptable alternative to pyrocatechol violet for assessment of TnBTO, and cobaltous thiocyanate or a bromocresol green/quinine sulphate mixture as alternatives to bromophen...
D V Plackett


Analysis of organotin fungicides in wood preservative solutions and double-vacuum treated wood
1983 - IRG/WP 3250
A new analytical method using high-performance thin-layer chromatography (HPTLC), for the assay of organotin compounds in preservative-treated wood, is presented. The organotin compounds are extracted from the ground wood sample with a mixture of hydrochloric acid and ethanol. After HPTLC-separation, exposure of the thin-layer plate to ultraviolet light, and dipping of the plate into a 0.1% pyroca...
W Hintze, S V Ohlsson


The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of t...
S J Blunden, R Hill


Tests on preservation of wood against marine borers
1976 - IRG/WP 417
The Instituto del Legno has carried out for some years a series of trials about the biodeterioration of wood in the sea. The investigations included the settlement and activity of marine borers, the natural durability of indigenous and tropical woods and the preservation of wood for marine use. This paper reports the trials on the effectiveness of some preservatives in protecting wood against mari...
A Gambetta, E Orlandi


Collaborative tests on the influence of solvent and drying method on the toxic limit of wood preservatives against Basidiomycetes
1974 - IRG/WP 248
Seven institutes from five countries, Austria, England, France, Germany and the Netherlands have collaborated in a study on the influences of solvent and drying method on the toxic limits of wood preservatives against Basidiomycetes tested according to the agar-block method. Two preservatives, a 25% pentachlorophenol-concentrate and tributyltinoxide were applied to pine sapwood and beech and teste...
T Hof


Use of the Pilodyn to assess deterioration of treated aspen waferboard after 30 months of outdoor exposure
1986 - IRG/WP 2254
Samples of preservative treated aspen waferboard exposed outdoors for 30 mo. were compared using pin penetrations of the 6 Joule Pilodyn. These results correlated well with rankings of treatment performance based on more laborious standard mechanical tests, and demonstrate the potential for use of the Pilodyn as a tool to evaluate wood composites in test exposures with minimal destruction....
E L Schmidt, M G Dietz


Germination of basidiospores on preservative treated wood after leaching or natural weathering
1981 - IRG/WP 2150
In tests of residual toxic efficacy after leaching or natural weathering, spore germination with Gloeophyllum trabeum has proved to be a less reliable criterion of attack than when used with unaged preservative treatments. Since spores sometimes prove more tolerant than their parent mycelium, their use should be continued....
J K Carey


The influence of formulation on the behaviour of LOSP's during industrial impregnation of spruce
1986 - IRG/WP 3387
Evidence is presented that the comparative behaviour of two LOSP formulations during impregnation treatment of spruce cannot be predicted purely on the basis of their physical characteristics (viscosity, surface tension and contact angle) nor on the extent of their 'passive' penetration into pine sapwood....
L D A Saunders, D M Zuvencko


A natural exposure weathering test for the evaluation of preservative performance
1992 - IRG/WP 92-2400
Natural exposure weathering tests were carried out by externally exposing treated wood samples for varying periodes of time up to 36 months. In the laboratory these samples were assayed for residual preservative effeciveness using Coniophora puteana FPRL 11E. The results indicated a loss in efficacy over and above that determined using artificial ageing procedures such as EN73 (evaporative ageing)...
J Brown, G R Williams


TBTO absorption and penetration in pine joinery treated by various processes
1989 - IRG/WP 3523
Matched sections of several White pine (Pinus strobus) and Ponderosa pine (Pinus ponderosa) mouldings were treated with TBTO by Double vacuum, modified empty-cell, 15 second dip and several preheating treatments followed by a 15 s dip treatments. As expected the double vacuum and empty-cell (batch) treatments resulted in much greater retentions and penetrations than the dip treatments. The absorpt...
P A Cooper, Y T Ung


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