Your search resulted in 73 documents. Displaying 25 entries per page.
Tributyltin compounds in wood preservation: Health and safety aspects
1986 - IRG/WP 3396
The toxicity of organotin compounds of the general formula RnSnX(4-n) depends strongly on the type of organic substituent R and on the degree of substitution n. The residues X, not bound through a tin-carbon bond, are however of much smaller influence. Furthermore, there is evidence that hydrolysis of tributyltin esters will occur under environmental as well as under physiological conditions to TB...
H Schweinfurth, P Günzel, H A B Landsiedel, R Lang, R Reimann, C Schöbel, F Siegmund
The effectiveness of three tributyltin compounds in beech against soft rot fungi using a soil-bed technique: A preliminary report
1986 - IRG/WP 3390
The effectiveness, towards soft rot fungi, of bis (tributyltin) oxide, tributyltin ethanesulphonate (TBTES) and benzyltributylammonium tributyldichlorostannate in both leached and unleached beech stakes is compared to that of a CCA preservative (Tanalith CT 106), using a soilbed technique. In addition, the effect of test solvent (water or toluene) on the performance of TBTES is evaluated. Total ti...
R Hill, A H Chapman, B Patel, A Samuel, J K Carey
A bioassay for appraising preservative protection of wood above ground
1978 - IRG/WP 2124
A bioassay, using the mold fungus Aspergillus niger, gave results that were correlated with amounts of pentachlorophenol and tributyltin oxide in pine sapwood treated with solutions ranging in strength from 0.016 or below to 5%. Limited bioassay estimates of penta in commercially treated millwork corresponded to estimates by lime ignition. The assay fungus exhibited somewhat greater tolerance of t...
T C Scheffer, L Gollob
Pentachlorophenol and tributyltin oxide - the performance of treated Pinus radiata after 12 years' exposure
1986 - IRG/WP 3361
Pinus radiata samples were impregnated with a range of light organic solvent preservatives and copper/chrome/arsenic salt and exposed with no surface coating both in and above ground for 12 years. Inspection of the test samples revealed that some formulations of light organic solvent preservatives will give good fungal protection and reduce splitting in Pinus radiata exposed externally without a s...
R S Johnstone
Proposals for further co-operative studies on determining toxic values against wood-destroying Basidiomycetes
1985 - IRG/WP 2237
Document IRC/WP/2194 reported the status of the programme of co-operative experiments up to and including December 1982. During discussions at IRG-13 in Turkey members endorsed the decision to complete the programme of tests and conduct repeat tests. At IRG-14 in Brisbane the report was noted but no further action agreed. At IRG-15 in Sweden a number of interested parties in the European/Scandinav...
A F Bravery
Co-operative research project on L-joint testing. Progress report to March 1986
1986 - IRG/WP 2272
Further sets of data received from CTFT (France) after 18 months exposure, BAM (Germany) after 18 months exposure, STU (Sweden) after 9.5 months exposure and TI (Denmark) after 12 and 17.5 months exposure are presented and discussed in conjunction with data previously reported. The new data are generally in agreement with those presented previously and indicate the major difference between the co-...
J K Carey, A F Bravery
Co-operative research project on L-joint testing. Progress report to March 1985
1985 - IRG/WP 2236
It was originally intended that each participant would expose L-joints in the main trial on 1 April 1983 with the first sampling at 8 months (1 December 1983) and the second sampling at 18 months (1 October 1984). In the event, some participants have had to vary this schedule. Results after the first sampling have been received from CTFT (8 months), BAM (12 months) and Sipad-IRC (8 months) and aft...
J K Carey, A F Bravery
Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland
Simulation test of subchronic inhalation toxicity of TBTO vapours in the air
1987 - IRG/WP 3454
The test was carried out in a wainscotted room of a normal size. Wooden panelling had been treated with one coat of basic preserving agent and, after the installation, with 2 coats of stain. Laboratory animals (rats) were kept in this room for 90 days. For the same period a control group of test animals was kept in a room of equal size where there was no panelling. During the test, concentration o...
V Skubic, S Kobal, J Stupar, R Ajlec, J Korošin, G R Pecenko
Preliminary testing of an improvised wood preservative mixture applied against dry wood beetles
1986 - IRG/WP 1308
An improvised wood preservative mixture was preliminarily tested in situ against some dry wood beetles which had infested structural timbers in a semi-finished building. The results obtained should encourage further research towards mobilizing/improvising locally available resources in the face of scarce standard wood preservatives, against the background of a dilemma in wood utilization in the de...
M O Akanbi, E M Bayode, A A Alabi, J Gbadebo
Chemical and biological investigations of double-vacuum treated windows after 5 years in service
1983 - IRG/WP 3219
In 1980 The Swedish Wood Preservation Institute initiated an investigation to study the degradation of TBTO and possible fungal attack in double-vacuum treated window joinery in service during 5 years. A hospital in Gothenburg was chosen that was built during 1969 to 1976. Both untreated and double-vacuum treated windows of Pinus sylvestris were used. A brown alkyl oil type paint (Nordsjö system ...
J Jermer, M-L Edlund, B Henningsson, W Hintze, S V Ohlsson
The detection of organic solvent preservatives in wood by thin-layer chromatography
1975 - IRG/WP 357
A simple and rapid method for the detection of common organic solvent wood preservative materials is described. The method uses thin-layer chromatography after leaching of the preservative from sections of timber with chloroform. RF values and the sensitivity of the method are discussed and a routine procedure for identification of the organic and organometallic preservatives is proposed. Methods ...
B G Henshaw, J W W Morgan, N Williams
Fungal detoxification of organotin biocides
1985 - IRG/WP 1258
The ability of a range of wood decaying fungi to inactivate bis(tri-n-butyltin) oxide (TnBTO) in the extracellular growth medium, in stationary liquid culture was determined. A distinction between the ability to tolerate the fungicide and to inactivate it was made: the white-rot organism Coriolus versicolor being the most efficient inactivator. In an attempt to determine the extracellular agents r...
P S Belford, D J Dickinson
Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda
Preliminary observations on tributyltin treated Scots pine sapwood using 119Sn (Mössbauer and NMR) spectroscopic techniques
1984 - IRG/WP 3312
119mSn Mössbauer data are presented for bis(tributyltin) oxide, tributyltin ethanesulphonate, bis(tributyltin) carbonate and tris(tributyltin) phosphate, both in the pure form and in Scots pine sapwood. The structures proposed for these compounds, in the solid state, are supported by 119Sn nuclear magnetic resonance spectroscopy.
R Hill
Accelerated testing for out of ground contact using natural biological preconditioning
1996 - IRG/WP 96-20088
Small blocks made of Scots pine sapwood were treated, buried in vermiculite and exposed to natural microbial colonisation during outdoor exposure prior to laboratory decay testing. Periodic microbial isolations, moisture content, permeability and weight loss tests were also conducted. Bacteria and moulds colonised the vermiculite and miniblocks well. Aureobasidium pullulans was common on TnBTO tre...
S Molnar, D J Dickinson, R J Murphy
Information from the COIPM Wood Group
1988 - IRG/WP 4146
Abstract from the COIPM minutes: Wood in marine environment:
Mrs Gambetta stated that the main item discussed by the Group was the collaborative work to test the durability of heat shrinkable polyolephin sheating materials for the protection of wood against marine organisms. The work began last year when wood samples were sent out to the participants. Three samples of Pinus sylvestris wrapped in ...
A Gambetta
Chemical and biological investigations of double-vacuum treated windows after 7½ years in service
1985 - IRG/WP 3339
Earlier investigations of double-vacuum treated windows after five years in service have shown that tributyltin oxide (TBTO) degrades to di- and monobutyltin compounds and that the resistance of the wood against decay decreases. An investigation 2.5 years later of the same windows shows that the degradation of TBTO proceeds fast. After 7.5 years in service only 15-35% of the remaining organotin co...
M-L Edlund, J Jermer, B Henningsson, W Hintze
Field test of wood preservatives with Nasutitermes rippertii RAMBUR in Cuba
1996 - IRG/WP 96-10181
A field test of wood preservatives was carried out with Nasutitermes rippertii RAMBUR in the vicinity of the Material Testing Centre „Alexander von Humboldt" in Santiago de las Vegas/ Havana (Cuba) for 12 and 24 months. Test specimens of Pinus sylvestris L., Picea abies (L.) Karst. and Fagus sylvatica L. with dimensions of 25 x 25 x 490 mm³ were arranged vertically or horizontally in a circle o...
W Unger
Microbial ecology of treated lap-joints exposed at Hilo, Hawaii for 12 months
1996 - IRG/WP 96-20089
Lap-joints made from Southern yellow pine treated with ACQ, DDAC or Propiconazole were exposed and sampled over 12 months. TnBTO treated Lap-joints were later exposed as a standard treatment. The moisture content of the joint area remained at 23% to 28%, but, away from the joint, varied between 20% to over 30%. Untreated samples had higher moisture contents and there was little difference between ...
S Molnar, D J Dickinson, R J Murphy
A bioassay of remedially treated pole material
1987 - IRG/WP 3453
Stubs prepared from treated and untreated utility poles were installed in a test plot and pressure spade treated at the groundline with one of four preservative greases. At one and three year intervals, core samples were removed from the stubs and the improvement in the preservative efficacy due to the greases was assessed. The bioassay investigation showed that only bis(tributyltin) oxide (TBTO) ...
J N R Ruddick, L Parker
Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard
Validity of above ground testing according to ENV 12037
2008 - IRG/WP 08-20379
The standard ENV 12037 for testing of treated and untreated wood (lap-joint) exposed above ground
was issued in 1996 by The European Committee for Standardization. A draft for the development of the standard was presented by CEN-TC 38/WG 25/DOC N 076 in 2002. For a test to become valid the median rating of decay for untreated control replicates (Scots pine sapwood) must be equal or greater than ...
Ö Bergman, U Råberg, N Terziev