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Tebuconazole - A new triazole fungicide for wood preservation
1990 - IRG/WP 3629
The main cause of economic damage to timber and millwork worldwide are Basidiomycetes (brown and white rot). After testing a wide range of triazole derivatives for their effectiveness against decay fungi, Tebuconazole, a triazole compound, was selected. The physico-chemical, toxicological and ecotoxicological data of this substance are described. Tebuconazole is unleachable, light-stable, heat-sta...
R Gründlinger, O Exner


Which substrate to use in a laboratory test with soft rot micro-fungi: vermiculite or unsterile soil?
1991 - IRG/WP 2372
A draft European Standard is being proposed by CEN TC 38 in which a vermiculite-burial and a soil-burial test to be carried out in succession are required. Various experiments with both procedures were set up with CCA, CC and propiconazole-formulations. The results show that vermiculite and unsterile soil yield comparable threshold values against soft rot. This poses the question of whether a two-...
A R Valcke


Suitability of propiconazole (R 49362) as a new-generation fungicide
1989 - IRG/WP 3529
Propiconazole (R 49362), an anti-fungal triazole-compound of Janssen Pharmaceutica, has been extensively tested to determine its potential use as a wood preserving fungicide. Various tests in both private laboratories and official institutes indicate a good activity against Basidiomycetes (brown and white rot) and Ascomycetes (blue stain-in-service). The active ingredient seems very resistant to w...
A R Valcke


Stability, performance and distribution of propiconazole (R 49362) in acceleratedly aged wood
1991 - IRG/WP 3647
The permanency of propiconazole (R 49362 - WOCOSENÔ technical - Janssen Pharmaceutica) in wood was examined in an 18 month storage test, an evaporative ageing study (EN 73), a volatilization stress experiment, and water-leaching studies (EN 84). The biological efficacy against two brown rot fungi: Coniophora puteana BAM Ebw. 15 and Gloeophyllum trabeum BAM Ebw. 109 was assessed according to the E...
A R Valcke, M Stevens


Performance of Oriented Strandboard, Medium Density Fiberboard, Plywood, and Particleboard Treated with Tebuconazole in Supercritical Carbon Dioxide
2005 - IRG/WP 05-30364
The performance of oriented strandboard (OSB), medium density fiberboard (MDF), particleboard and plywood treated with tebuconazole using supercritical carbon dioxide was investigated over a 48 month exposure under harsh above ground conditions in Hilo, Hawaii. Samples treated to low retentions (<0.20 kg/m3) tended to experience decay at rates that were only slightly lower than those found wit...
J J Morrell, M N Acda, A R Zahora


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


The influence of carrier fluid type on the efficacy of a wood preservative against cavity forming soft rot
2000 - IRG/WP 00-30244
Propiconazole was applied to Scots pine sapwood (Pinus sylvestris) and beech (Fagus sylvatica) using three different carrier systems selected on their varying ability to swell timber. The effects of microdistribution on the activity of cavity forming soft rot fungi were examined to determine the practical benefits of using swelling and non-swelling carriers with this active ingredient. Efficacy of...
P A Hodges


Accelerated testing for out of ground contact using natural biological preconditioning
1996 - IRG/WP 96-20088
Small blocks made of Scots pine sapwood were treated, buried in vermiculite and exposed to natural microbial colonisation during outdoor exposure prior to laboratory decay testing. Periodic microbial isolations, moisture content, permeability and weight loss tests were also conducted. Bacteria and moulds colonised the vermiculite and miniblocks well. Aureobasidium pullulans was common on TnBTO tre...
S Molnar, D J Dickinson, R J Murphy


Microbial ecology of treated lap-joints exposed at Hilo, Hawaii for 12 months
1996 - IRG/WP 96-20089
Lap-joints made from Southern yellow pine treated with ACQ, DDAC or Propiconazole were exposed and sampled over 12 months. TnBTO treated Lap-joints were later exposed as a standard treatment. The moisture content of the joint area remained at 23% to 28%, but, away from the joint, varied between 20% to over 30%. Untreated samples had higher moisture contents and there was little difference between ...
S Molnar, D J Dickinson, R J Murphy


Microbial ecology of treated Lap-joints exposed at Hilo, Hawaii for 24 months
1997 - IRG/WP 97-20107
This paper is a continuation of previous work reported in IRG/WP 96-20089 by Molnar et al. (1996) in which Lap-joints, made from Southern yellow pine and treated with ACQ, DDAC or propiconazole were sampled over 12 months exposure at Hilo, Hawaii. 18 and 24 month samplings have since taken place and are reported here. TnBTO treated Lap-joints made of scots pine which were exposed later as a standa...
S Molnar, D J Dickinson, R J Murphy


The use of organic wood preservatives in ground contact and the suitability of laboratory test procedures to determine their efficacy
1999 - IRG/WP 99-20175
Organic fungicides, such as propiconazole, have proven to be highly effective when used as a co-biocide in recently developed wood preservative formulations. They have however been ineffective when used as a stand alone preservative, particularly when used in ground contact (European Hazard class 4). Previous research, using the test methods of ENV 807 (1993), provided conflicting evidence regardi...
I J Herring, D J Dickinson


Investigation of new wood preservation formulations based on synergies between antioxidant, 2-HPNO and Propiconazole
2006 - IRG/WP 06-30401
Wood degradation by fungi is a complex phenomenon taking place in part through oxidative reactions involving many oxidizing agents like free radicals and hydroperoxide. In order to develop novel and more environmentally benign preservative systems, mixtures of Propiconazole and antioxidants with different stabilization mechanisms were investigated to detect possible synergies allowing to reduce th...
B Bakhsous, S Dumarçay, E Gelhaye, P Gérardin


Quantitative Determination of Cyproconazole in Wood treated with Tanalith CY
2007 - IRG/WP 07-20369
The HPLC method has been widely applied to quantitative determination of cyproconazole in preservative solutions. However, HPLC assay has not been successfully employed to determine cyproconazole content in treated wood. Some extractives from treated wood hinder cyproconazole determination because they have a similar retention time to that of cyproconazole on an HPLC chromatogram. In addition, ...
I Momohara, T Miyauchi, M Mori


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen


The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston


Mould resistance of bamboo timber treated with tebuconazole-loaded micells
2012 - IRG/WP 12-30586
In this paper both anti-mould test through inhibition zone and mould resistance test on bamboo samples were carried out evaluate mould resistant effect of tebuconazole (TBA) loaded micells. Results showed that TBA loaded micells prepared with a ratio of TBA to PEG113-b-PCL28 50:25 had the best mould resistance, followed by micells prepared with a ratio of TBA to PEG113-b-PCL28 50:50. PEG113-b-PCL2...
Sun Fangli, Chen Anliang, Bao Binfu, Zhou Yueying, Zhang Shaoyong, Zhang Xu


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Biological Performance of Triadimefon in combination with Tebuconazole in laboratory and field tests
2015 - IRG/WP 30668
The usage of Triazole-combinations for wood preservatives is common practice in several countries. Especially the combination of Tebuconazole and Propiconazole is preferred for this application due to its broad spectrum of efficacy against wood destroying fungi. 1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butanon, also known as Triadimefon provides a good efficacy against the wood destr...
P Meckler, T Jaetsch


Monitoring uptake and penetration of pesticides during impregnation of pine (Pinus sylvestris) and spruce (Picea abies) wood with bio-based microemulsion gel formulations
2020 - IRG/WP 20-30756
Even in dry state wood is susceptible to biological degradation. Preservation against biological decay in exposed conditions is conventionally achieved by impregnating the wood with pesticides applied at professional and industrial levels. Impregnation of wood with preservatives is a complex process that involves wood macro- and microstructure, and the physical characteristics of woods. Here we fo...
D Messaoudi, K Ruel, J-P Joseleau


Efficiency of three resin fractions from Aucoumea Klaineana Pierre, Canarium schweinfurthii Engl and Dacryodes edulis (G. Don) H. J. Lam from Gabon combined with Tebuconazole as wood preservatives
2022 - IRG/WP 22-10998
Pure resins from Aucoumea Klaineana, Canarium schweinfurthii and Dacryodes edulis were harvested and then hydro-distilled to obtain essential oils and purified resins fractions. Due to the potential leaching and volatility hazards of the compounds that constitute these fractions, resins and essential oils were combined with tebuconazole to produce both antifungal and anti-termite wood preservative...
W F Bedounguindzi, K Candelier, P Edou Engonga, S Dumarcay, M-F Thevenon, P Gerardin


Long-term field performance of a carbon-based preservative in ground contact test conditions
2023 - IRG/WP 23-30781
Carbon-based preservatives have demonstrated reasonable long-term field performance in above ground testing. This study examines the performance of a carbon-based preservative formulation containing quaternary ammonium compounds and tebuconazole as a treatment for three softwood species exposed in ground contact at two sites in Canada. The treatment was associated with improved decay resistance an...
C Wilson, J Zhang, R Stirling


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