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Long term performance of CCA preservatives in ground contact
2000 - IRG/WP 00-30223
Copper-chrome-arsenate (CCA) preservatives have been use extensively in New Zealand since the mid-1950s for a wide range of ground contact uses, radiata pine being the main species treated. They have been the subject of a comprehensive field testing programme in up to five sites in New Zealand, the earliest tests being established in 1955. Main factors affecting performance have been formulation t...
M E Hedley, D R Page, B E Patterson


Examination of the Pilodyn as a non-destructive test method for detecting decay in CCA treated eucalypt poles
1982 - IRG/WP 2177
Below groundline condition of 274 CCA treated eucalypt poles comprising 13 different species was examined using 6 and 12 Joule Pilodyn units with 2 and 2.5 mm diameter pins. The data obtained was used to calculate regressions of density on pin penetration. A decrease in density was accompanied by an increase in pin penetration. The best correlation was found using the 6 Joule, 60 x 2.5 mm² diamet...
L E Leightley


The possible significance of the lignin content and lignin type on the performance of CCA-treated timber in ground contact
1988 - IRG/WP 1357
The lignin in wood samples of Alstonia scholaris, Octomeles sumatrana and a Simaruba species have been analysed. These timbers are characterised by a high lignin content and low syringyl:guaiacyl ratios. Decay tests with two soft rot fungi showed that the timbers were less susceptible than timbers with a low lignin content and higher syringyl:guaiacyl ratios. Numerous data for field performance of...
T Nilsson, J R Obst, G F Daniel


A termite field test with diffusion treated lumber
1991 - IRG/WP 3648
Douglas fir lumber, diffusion treated with concentrated sodium octaborate solutions, was tested against Coptotermes formosanus in an above ground field test wherein the samples were not exposed to a direct leaching hazard during the test period. After 2.5 years exposure, the untreated control samples were almost completely destroyed while poorly treated controls pressure treated with chromated cop...
K J Archer, D A Fowlie, A F Preston, P J Walcheski


Development of a turbidity method for the determination of water repellent in CCA treatment solutions
2000 - IRG/WP 00-40177
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground exposures. However, they are also used in pole treatments to improve the climbing characteristics and in low VOC millwork ...
P J Walcheski, L Jin


Service life of pressure treated deckings of spruce in direct contact with the ground
1988 - IRG/WP 3463
For decking outdoors in Sweden, pressure treated Scots pine (Pinus sylvestris L.) is used, on account of its treatability. The feasibility of using instead the refractory Norway spruce (Picea abies Karst.) is tested in a field trial. The spruce decks were treated together with pine decks with an ordinary Bethell process. As yet, after more than four years of exposure, neither in the battens nor in...
J B Boutelje, T Sebring


BRE Experience in monitoring decay in out-of-ground exposure trials
1995 - IRG/WP 95-20077
The outdoor field trial has always been regarded as the ultimate test of performance for assessing the effectiveness of a wood preservative. For this reason, the Building Research Establishment (BRE) has invested much effort in such trials over many years. Emphasis in early trials was on ground contact tests which were the basis both for assessing the likely performance of a preservative in protec...
J K Carey, R J Orsler


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


Alternatives to CCA for ground contact protection of timber: a perspective from UK on performance and service life expectations
2002 - IRG/WP 02-30289
The proposed amendment to the European Union's Marketing and Use Directive (1976/769/EEC) in respect of arsenic in CCA wood preservatives seeks to restrict the use of CCA across the European Union. CCA is an extremely important wood preservative in the UK from the manufacturing of the product to the extent of use of CCA-treated timber. Based on our experience and judgement on the use of ...
E D Suttie, A F Bravery, T B Dearling


The field performance of CCA-C treated sawn refractory softwoods from North America
1997 - IRG/WP 97-40085
Approximately 15% of the total volume of wood treated in the United States consists of difficult to treat softwoods known as "refractory softwoods". The long term positive performance record of CCA treated sawn material is based upon the testing of yellow pine sapwood stakes with only limited field data available for sawn refractory softwoods. As a result, the existing North American wood preserva...
M J Richards, W S McNamara


Application of a novel strength evaluation technique during screening of wood preservatives
1986 - IRG/WP 2262
The effectiveness of CCA and ACA in treated aspen mini stakes tested using a novel bag procedure, with unsterile soil fortified with Chaetomium globosum and Ceratocystis albida, is reported. Good agreement between toxic limits determined using the standard weight loss procedure, and those determined by the strength technique were found, with some indication that the strength loss method is more se...
J N R Ruddick


Comparison of methods for monitoring CCA fixation
1994 - IRG/WP 94-40023
The CCA fixation status in the outer 12.5 mm of pole sections of southern pine (Pinus sp.), red pine (Pinus resinosa) and lodgepole pine (Pinus contorta var. latifolia) were followed during fixation at 21°C under non-drying conditions by the following procedures: - Qualitative CrVI indication by the chromotropic acid spot test. - Quantitative CrVI in the expressate by the diphenylcarbazide method...
P A Cooper, Y T Ung, G Zanjani


Laboratory testing of wood natural durability - In soil-bed assays
1998 - IRG/WP 98-20141
Laboratory methods for assessing wood decay resistance are being investigated in the framework of an ongoing European research project. This paper summarizes the main results obtained for soil-bed tests based on the European prestandard ENV 807-Test 2. The data suggest that this testing methodology is suitable for evaluating the natural durability of timber species in soil-contact under conditions...
R Sierra-Alvarez, I Le Bayon, J K Carey, I Stephan, J Van Acker, M Grinda, G Kleist, H Militz, R-D Peek


On the occurrence of Phialophora species in preservative treated wood in ground contact
1977 - IRG/WP 163
Phialophora is a fairly large genus comprising about thirty described species. They are widespread in very diverse environments, such as soil, sea water, wood and wood pulps. Some species are known as parasites on plants and animals, including man. Phialophora species were early known for their ability to produce blue stain in timber. Later it was discovered that several species were able to produ...
T Nilsson, B Henningsson


The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley


A non-pressure method of protection based on hurdle theory to control the spectrum of internal environmental factors which affect the decay of poles in soil contact
1993 - IRG/WP 93-20005
A field trial was conducted to establish whether superficial barrier linings on poles in soil contact could function as environmental hurdles against the growth of biological agents and thus provide preventative methodology to preclude premature failure of vineyard poles under flood-irrigation. Assessment after 52 weeks exposure to the prevailing conditions and sub-tropical environment showed that...
A A W Baecker


Performance of different treatments and finishes on wood out of ground contact. Preliminary results
1984 - IRG/WP 2221
Pinus and Eucalyptus L-joints treated with CCA, a water dispersable PCP and untreated ones were painted according to seven different finish's schedules and exposed at two sites in State of Sao Paulo. After ten months of exposure, it was possible to verify that preservative treatment improve the performance of both wood and finish. It was also possible to observe that wood substrate, prese...
S Milano


Effect of climate, species, preservative concentration and water repellent on leaching from CCA-treated lumber exposed above ground
2001 - IRG/WP 01-50178
Few studies have examined leaching of chromated copper arsenate (CCA) from treated wood in above ground exposures due to the assumption that leaching is less severe compared to wood in continuous contact with soil or water. However, a significant portion of CCA treated wood is used for above ground applications, exposing considerable volumes of the preservative to precipitation and potential leach...
J L Taylor, P A Cooper


Pentachlorophenol and tributyltin oxide - the performance of treated Pinus radiata after 12 years' exposure
1986 - IRG/WP 3361
Pinus radiata samples were impregnated with a range of light organic solvent preservatives and copper/chrome/arsenic salt and exposed with no surface coating both in and above ground for 12 years. Inspection of the test samples revealed that some formulations of light organic solvent preservatives will give good fungal protection and reduce splitting in Pinus radiata exposed externally without a s...
R S Johnstone


Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz


The evaluation of the effectiveness of wood preservatives by means of IUFRO's method for field tests with wooden stakes
1985 - IRG/WP 3348
Pinus elliottii and Eucalyptus saligna stakes treated with CCA-A, CCA-C, CCB, Cashew Nut Shell Oil and Benzotar solutions were exposed in seven test sites in Sao Paulo State, Brazil. After five years of exposure, between oil-borne preservatives Benzotar show better performance than CNSL (cashew nut shell liquid), and within waterborne preservatives the performance of CCB is not so good as that of ...
G A C Lopez, A M F Oliveira, E S Lepage


Effectiveness of wood preservatives by IUFRO's method
1984 - IRG/WP 3305
Pinus elliottii and Eucalyptus saligna stakes treated with 4.9; 6.9; 9.6 and 13.5 kg/m³ of CCA-A, CCA-C and CCB and with 30-50; 60-80; 90-110 and 120-140 kg/m³ of Benzotar and CNSL (cashew-nut shell liquid) were exposed in seven test sites in Sao Paulo State, Brazil. After 4 years it was concluded that the mean useful life of untreated Pinus elliottii stakes was 8 months and of untreated Eucalyp...
G A C Lopez, E S Lepage, O B Neto


A laboratory bioassay method for testing preservatives against the marine borers Limnoria tripunctata, L. quadripunctata (Crustacea) and Lyrodus pedicellatus (Mollusca)
1990 - IRG/WP 4159
A laboratory culture and bioassay method is described for the marine borers Limnoria tripunctata, Limnoria quadripunctata, and Lyrodus pedicellatus. The methods were tested in a bioassay using established marine preservatives. The attack produced on blocks treated with CCA or creosote in some ways paralleled the attack found in the sea. Limnoria tripunctata attacked treated and untreated pine bloc...
L J Cookson


Development of a mini-block test method for the rapid evaluation of preservative performance against Basidiomycte fungi
1991 - IRG/WP 2379
Screening procedures for new biocides used as wood preservatives can be a time consuming process using conventional Basidiomycete assay procedures. This is due mainly to the long exposure periods required to achieve adequate levels of decay (weight loss) in the test blocks. A number of alternative methods have been developed but most utilise artificial substrates such as filter paper or agar in wh...
J Brown, S Caswell, G R Williams


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