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Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 and 250 oC by TGA removed water and creosote (6.6 – 9.3 wt%) from the creosote-treated crosstie materials, and water and CuNap components (21.2 – 23.3 wt%) from the CuNap-treated crossties. Temperature at 300 oC removed a shoulder DTG peak at 305 - 325 oC and weight loss accounted for 25.5 wt% in the creosote-treated tie and 30.6 wt% in the CuNap-treated tie. Temperature at 200 – 300 oC by Py-GC/MS desorbed creosote-derived chemicals such as naphthalene, acenaphthene, fluorine, anthracene, fluoranthene, pyrene and other polycyclic aromatic hydrocarbon (PAHs) derived from the creosote-treated tie; and mineral oil (alkane hydrocarbons such as tetradecane, nonadecane, hexadecane and octadecane, and heptacosane) from the CuNap-treated ties. Pyrolysis of the wood tie with elevated temperature produced a high amount of carbohydrate- and lignin-derived compounds from wood ties. Fast pyrolysis of the 200 oC-treated crossties by Py-GC/MS produced a high fraction of creosote- and CuNap compounds most of which were then not subsequently recovered through fast pyrolysis of the 250 and 300 oC-treated samples. Fast pyrolysis of the thermally preservatives-removed tie samples produced high anhydrosugars such as levoglucosan and low acetic acid, furfural and ketones as well as high pyrolytic lignin-derived compounds, which shows good potential for phenolic-based chemical production. The results demonstrate that a thermal preservative-removal step (similar to a torrefaction step) can successfully remove valuable creosote and CuNap components for re-use as preservatives and subsequently supply a clean wood without significant levels of contaminant hazardous air pollutants for use as boiler fuel, more efficient pyrolysis to produce higher quality bio-oil, gasification or other uses.
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe
Effects of Bio-oil Obtained from Laurel (Laurus nobilis) Residues on Biological, Physical, and Mechanical Properties of Treated Wood
2016 - IRG/WP 16-30692
In this study, the effects of bio-oil obtained from Laurel (Laurus nobilis) residues on biological (decay, insect, termite resistance), physical (water absorption, tangential and radial swelling), and mechanical properties (MOE, MOR and CSPG) of treated wood samples were studied. The bio-oil used in this paper was produced by the help of fixed bed reactor type pyrolyzer. GC/MS analysis showed that the main constituents of bio-oils are furan compounds. The results indicated that the samples treated with bio-oil had lower water absorption and swelling rates than that of the control group. The lowest water absorption result (45%) for the bio-oils studied was obtained for the samples treated with 20% bio-oil after 48 h exposure in water. Decay resistance of treated wood samples with bio-oil against white rot (Trametes versicolor) and brown rot (Postia placenta, Gloephyllum trabeum, Coniophora puteana) fungi was carried out according to EN 113. Prior to decay test, samples were leached according to AWPA E11. Decay test results showed that treated samples had some efficiency against white and brown rot. In addition, bio-oil at the tested concentration did not give an adequate protection against insect and termite test. Strength test results show that treatment with bio-oil generally decreases mechanical properties of wood.
S Akbas, A Temiz, N Terziev, M H Alma, S Palanti, E Feci
Chemical composition and performances of slow pyrolysis by-product from sugarcane bagasse for wood protection
2020 - IRG/WP 20-30752
Pyrolysis distillate or bio-oil, a by-product of biomasses’ slow pyrolysis in the char-making process, has been traditionally used as bio-pesticides by Asian farmers. Due to its large composition of bio-active chemicals, bio-oil obtained from various biomass has become of interest in many applications, including wood protectants. This study aims to characterize the chemical composition of bio-oil obtained from the slow pyrolysis of sugarcane bagasse at the temperatures of 400 °C and 500 °C, along with the efficacy test against two Basidiomycete fungi (Coniophora puteana, a cubic rot, and Trametes versicolor, a fibrous rot) and subterranean termites (Reticulitermes flavipes). The test on wood was also conducted by impregnating the bio-oil to the beech wood samples. Treated samples were dried at various temperatures (ambient, 40°C, 60°C, 80°C and 103°C), and leached before being exposed to termites R. flavipes. Gas Chromatography-Mass Spectrometry (GC/MS) analysis revealed that bio-oil is composed mainly of oxygenated compounds such as carboxylic acids, alcohols, aldehydes, ketones, furans, and anhydrosugars. In contrast, about 40% of the bio-oil consisted of water. At the concentration of 0.25% (v/v), bio-oil were observed to be able to inhibit the growth of both Basidiomycete fungi, when performing inhibition growth tests in Petri dishes. Further, no termites survived when exposed to a filter paper with a 10% concentration of bio-oil. All the wood samples have been shown durable against R. flavipes. However, bio-oil remains leachable from the wood, which indicates that future studies should be conducted in order to find out how to decrease its leachability.
F D Boer, M-F Thévenon, J-M Commandre, M Fournier
Field test evaluation of preservatives and treatment methods for fence posts
1985 - IRG/WP 3347
This work presents the field test results after fifteen years exposure of Eucalyptus saligna fence posts treated with six different preservatives and five treatment methods. All the combinations with oil-borne preservatives presented the best results and among the waterborne preservatives, the fence posts treated by immersion method were with the lowest performance in the field test.
G A C Lopez, E S Lepage
Fire resistance of preservative treated fence posts
1994 - IRG/WP 94-30033
Pine fence posts were pressure treated separately with CCA-C, CCA-wax, CCA-oil and creosote. Treated posts and untreated controls were planted in the ground in a randomised block design, weathered for six months and then subjected to a controlled burning test using two fuel loads. Creosote treatment increased the time that posts were alight whereas CCA treatment had no such effect. However, CCA treated posts smouldered until destruction of the majority of the posts occurred. Posts treated with CCA-oil took longer for destruction to occur than posts treated with CCA-C or CCA-wax. Creosote treated posts and untreated controls did not show prolonged smouldering and consequently were not destroyed by the burning test, although their strength was reduced. A high fuel load increased the time that posts were alight and smouldering, and for CCA treated posts decreased their time to destruction.
P D Evans, P J Beutel, C F Donnelly, R B Cunningham
Principles and procedure of the planeing test
1981 - IRG/WP 2162
Small end-sealed samples of pine-sapwood (1.5 x 2.5 x 5 cm³) are treated by brushing and afterwards different parts of the treated surface are removed. The remaining part of the sample is tested against either insects or fungi. If no attack occurs sufficient amounts of biocides have been penetrated at least beyond the zone which has been removed. In spite of some problems the test seems the only suitable method, to evaluate organic solvent preservatives, mainly those containing resins, for simple treating methods.
H Willeitner, M Gersonde
Inspection results of preservative treated stakes, maximum 33 years in field
1992 - IRG/WP 92-3690
Since in 1958, we have undertaken field experiments in Japan. For these field experiments, we used sapwoods of Japanese cedar called Sugi (Cryptomeria japonica) because of majority of plantation forest soft wood species in Japan. For some preservatives, we added sapwood of Japanese beech called Buna (Fagus crenata), a main Japanese hard wood species. Dimensions of these specimens were 30 x 30 x 600 mm³ (T x R x L). About 30 preservatives mainly water born but 20% of oil born preservatives included, were examined for this test. We checked the damage rating every year by the observation. The service life of the preservative treated stakes were estimated at the period when the average damage rating of stakes were reached beyond 2.5 . Creosote oil, creosote oil mixed heavy oil (75:25 and 50:50) and creosote oil mixed coal tar (75:25 and 50:50) are still sound conditions for 33 years. CCA (JIS K 1554 Type 1) 2% and Tancas C 2% are still sound conditions for 28 years. Because of soft rot, the treated Buna specimens were shorten as ones of treated Sugi.
K Suzuki, K Yamamoto, M Inoue, S Matsuoka
Modelling of PCP migration in the environment: Feeding the models with laboratory data
1993 - IRG/WP 93-50001-08
In 1989, Hydro-Québec began a study program on pentachlorophenol (PCP) to ensure safe use of the product at all stages. One of the aspects of the study is the creation of a predictive system for evaluating the behavior of PCP and oil migration from wood poles to the environment. This system comprises four mathematical models for predicting PCP and oil migration in and on the surface of the pole, in soil and in groundwater, and for predicting runoff. Laboratory experiments aimed at quantifying and supplying the input for each model have been designed. A method of analyzing both PCP and oil in water. wood and soil has been developed. The radial and longitudinal distributions of PCP and oil concentrations have been established for several combinations of wood species and treatments. Laboratory setups and preliminary results are presented.
A Besner, P Tétreault, R Gilbert
A new ground-contact wide-spectrum organic wood preservative: DNBP
1986 - IRG/WP 3358
A new organic wood preservative, which 25 years field tests have proved to be of efficiency and effectiveness comparable to CCA wood preservatives for ground-contact applications, is presented. Physical and chemical tests, supporting the long term field test results as well as indicating the characteristics of this preservative, are also presented.
W E Conradie, A Pizzi
Fungus cellar and stake tests with tall oil derivatives. Progress Report after 5 years' testing
1987 - IRG/WP 3442
Two derivatives of tall oils have been tested for five years in fungus cellar and stake tests. The samples were relatively quickly attacked on the surface by decay fungi, mainly soft rot, but the decay has progressed very slowly. The performance of the stakes in the tests has so far been equivalent or even better than some CCA preservatives and creosote.
J Jermer, Ö Bergman, T Nilsson
Comparison of decay rates of preservative-treated stakes in field and fungus cellar tests
1980 - IRG/WP 2135
With the exception of acid-copper-chromate, zinc-chrome-arsenate, and sodium pentachlorophenoxide, the relative performance of preservatives in the fungus cellar was similar to that in the field.
M E Hedley
Effects of various preservative treatments on the mechanical and physical properties of plywood
1993 - IRG/WP 93-40007
The technical properties of plywood are related to both the intrinsic characteristics of its composing wood species and the quality and performance of the glue bond which acts as an interface between veneer sheets. Consequently mechanical and physical testing and glue bond strength analysis offer an appropriate means for studying the effect of preservative treatments on the overall quality of plywood. A range of boards was treated with waterborne and oilborne preservatives. Changes in modulus of elasticity, modulus of rupture and tensile strength were noted as well as variations in physical properties. Analysis of the glue bond strength was done by shear strength testing and determination of the amount of wood failure after different ageing procedures.
J Van Acker, M Stevens
Utility, deterioration and preservation of marine timbers in India
2005 - IRG/WP 05-40314
Timber is extensively used in India in the marine environment for various purposes due to its several advantages over modern materials. Infact, its use is increasing in recent years, finding wider and wider applications and this scenario is not going to change in the near future. Though, the bio-deterioration problem is found very severe in tropical waters, still indigenous methods are widely employed for the protection of fishing craft and the present level of chemical treatment is well below 5% of total timber used. This is due to socio economic problems of the potential timber user groups, unavailability of treatment plants in the coastal areas, lack of awareness in user groups, etc. In this paper, types of fishing craft used in the country, timber uses in the marine environment, bio-deterioration losses, research conducted on bio-deterioration aspects at various places and methods applied for the protection of wooden structures are presented.
B Tarakanadha, M V Rao, M Balaji, P K Aggarwal, K S Rao
Improved resistance of Scots pine and Spruce by application of an oil-heat treatment
2000 - IRG/WP 00-40162
Spruce (Picea abies L. Karst.) and Scots pine (Pinus sylvestris L.) were subject to a heat treatment which was carried out in an oil-bath. The aim was to improve the dimensional stability of the treated wood and its resistance against fungi. The bath of vegetable oil provides a uniform heat transfer at temperatures of 180°C, 200°C and 220°C and protects the submersed wood from oxygen. Heat treatment in air atmosphere was also carried out at the same temperatures for comparison. Wood treated in hot oil was more equal in its appearance than wood heated in hot air. The treatment of spruce and pine in the oil-bath resulted in a better resistance against Coniophora puteana in a lab test according to EN 113 compared to the treatment in air atmosphere. In order to achieve the wanted upgrading effect, certain changes of mechanical properties and colour must be accepted. However, the strength loss caused by the heat-treatment in oil was less severe than in air atmosphere. Since all materials and the energy used in the process originate from renewable resources, the oil-heat-treatment appears to be environmentally friendly. All in all, the heat treatment in oil might be a promising approach to upgrade wood for outdoor use.
M Sailer, A O Rapp, H Leithoff
Wood preservation in the Australian beekeeping industry
1988 - IRG/WP 3473
This paper reports the results of a survey of Australian commercial beekeepers working 200 or more hives in June/July 1985. Nine hundred and forty seven apiarists were asked to participate and to provide information on their wood preservation methods, painting procedures and maintenance of bee boxes. Three hundred and eighty-four apiarists returned completed questionnaires (41%). The main wood preservatives used are copper naphthenate solutions (45%), linseed oil (8%), copper chromated arsenate (3%), hot wax (9%), copper naphthenate solution in linseed oil (3%), linseed oil/wax mixtures (3%) and paint (23%). The majority of apiarists (96%) paint treated bee hives, but there is considerable variation in wood preservative treatment procedures and paint application. Most wood preservative treatments (95%) are of the 'do-it-yourself' variety, radiata pine being the most utilized timber. The bottom boards of bee hives are considered the most susceptible to wood decay and subterranean termite damage, as are cleats, stands or any wood in ground contact.
P J Robinson, J R J French
Determination of toxic limits of wood preservatives towards wood-destroying Basidiomycetes. Investigation on the effect of the use of two impregnated wood blocks and of one impregnated and an untreated block respectively in Kolle jars on the toxic limits of wood preservatives
1973 - IRG/WP 225
Preventing fungal attack of freshly sawn lumber using cinnamon extracts
2007 - IRG/WP 07-30432
The potential for using cinnamon oil as an anti-mold and stain compound was investigated on ponderosa pine sapwood. Cinnamon oil was highly effective when used in ethanol, but its activity declined when it was mixed with only water. Attempts to enhance water solubility with surfactants improved solution stability, but had no apparent effect on biological activity. Further studies with other co-solvents are planned
Shujun Li, C Freitag, J J Morrell
Chapter 6 - Preservatives of bamboo
2007 - IRG/WP 07-10635-06
Almost all currently available oil-borne, water-borne and compound types of preservatives suitable for the preservation of bamboo or wood have been described along with their classifications, applications, formulations, merits and demerits, history of invention or discovery and development. The preservatives suitable for wood are also considered suitable for bamboo.
A K Lahiry
Effects of some essential oils on wood destroying organisms
1993 - IRG/WP 93-10047
Three wood destroying fungi: Botryodiplodia theobromae Pat. (stain), Gloeophyllum sepiarium (brown rot), and Pycnoporus sanguineus (white rot) were exposed to six plant essential oils: the peppermint, kaffir lime or leech lime, lavender, tarragon, holy basil, and the eucalyptus. The peppermint oil showed most effective to inhibit fungal growth, while eucalypus oil was the least effective. The other oils inhibition rate varied according to the species of fungi. In the experiment of the powder post beetles Heterobostrychus aequalis Waterh., the insects were killed within three days in the oil of tarragon, eucalyptus and holy basil, while in lavender oil they could live to ten days the same as controls. But on the contrary in the oil of peppermint and kaffir lime, some of them could even lived longer than the controls.
K Atisongkroh, C Anantachoke, P Lekuthai, S Pensook, T Kittirattrakarn
Biological effectiveness of ground-contact wood preservatives as determined by field exposure stake tests
1984 - IRG/WP 3297
Field exposure tests conducted on stakes treated with different creosotes, mixtures of creosote and waxy oil as well as different CCA wood preservatives over a period of 25 years, gave the following results: The CCA preservatives provided excellent biological protection to treated stakes, especially against fungal attack. The CCA Type I, currently approved for use under South African conditions is not inferior to the CCA Type II during long-term ground-contact exposure if the active elemental contents and effective retentions are taken into consideration. The creosotes provided good protection against termite attack but showed fairly poor fungal resistance during long-term ground-contact exposure under wet conditions. The addition of waxy oil greatly improved the effectiveness of creosotes against fungal attack. The CCA preservatives proved to be a better overall ground-contact preservative compared with the creosotes.
W E Conradie, A Pizzi
Wood preservation in Kenya
2000 - IRG/WP 00-40191
Current research on wood preservation in Kenya is mainly on the development of biological control of wood-destroying termite species, using mycoinsecticides. The major research institutions include the Kenya Agricultural Research Institute (KARI), Kenya Forestry Research Institute (KEFRI), Moi University and the International Centre for Insect Physiology (ICIPE). Training institutions include Forestry Training College, Forest Products Training Institute and Moi University. A number of publications, mostly an biological control of termites, are available and they range from workshop and conference proceedings to theses and journal publications. Wood-destroying termite species include several genera in Macrotermitidae and one drywood termite genus. Wood preservation facilities are available in Kenya, mainly for assorted timber products, sleepers and utility poles. The major preservatives used are CCAs, PCP and Creosote oil. There are still no set standards, specifications and requirements for wood preservatives and little, if any information exists on the marketing aspects of wood preservatives. The yet to be established Industrial Chemicals Act and the recently introduced Environmental Management and Coordination Bill (1999) may be able to handle regulatory, environmental, health and safety aspects of wood preservation in Kenya.
The distribution of introduced acetyl groups and a linseed oil model substance in wood examined by microautoradiography and ESEM
2000 - IRG/WP 00-40169
Microautoradiography, a photographic method that shows the localization of substances labelled with radioactive isotope, and Environmental Scanning Electron Microscopy (ESEM) were combined to enhance sensitivity, resolution and reliability for examination of the distribution of introduced substances in wood. The preparation of microautoradiographs is less complicated when investigated with ESEM and the preparation of ESEM-samples is quick and easy compared to a conventional SEM. When investigating microautoradiographs with ESEM, the wood structure is observed underneath the almost transparent photographic film. Silver grains, indicating the location of studied substances, are clearly distinguish from the wood material. The technique was used in two case studies for examination of cell wall penetration and distribution in pine sapwood. The distribution of acetyl groups, introduced by acetylation with acetic anhydride, and the distribution of a linseed oil model substance, triglycerol trioleate, were examined. Examinations of introduced acetyl groups showed an even distribution of acetyl groups in the wood cell wall at acetylation level of about 5, 15 and 20% (weight gain). Examination of the linseed oil model substance, glycerol trioleate, showed the presence of the model substance on applied surfaces, in rays and in lumen of some latewood cells. No cell wall penetration was observed.
Effects of artificial UV weathering and soft rot decay on heat treated wood
2005 - IRG/WP 05-40302
Oil and inert gas oven heat treated pine wood strips 100 µm thick were mildly heat treated (200°C, 30 mins linseed oil, 120 mins oven). Following treatment, specimens were exposed to UV weathering (300 hours) and decay by the soft rot fungus, Chaetomium globosum. The effects of each treatment were assessed by zero span tensile testing, microscopy and by FTIR. Tensile testing of heat treated strips showed greater strength losses in the oil treated samples (73%) than in the oven treated samples (26% loss). Heat treatment darkened the wood strips but this was photo-bleached on exposure to UV artificial weathering. The UV exposure caused some loss in tensile strength (35%) but the additional effects of UV on the tensile strength were less in heat treated wood (oil 15%, oven 18%). The combined effects of UV and fungi on the tensile strengths were less severe for treated wood than in untreated wood, (oil 4%, oven 18%) thus some protection was afforded by the heat tretaments. Exposure of untreated wood strips to the soft rot fungus caused some loss in tensile strength (32%), but heat treated wood showed small but not statistically significant gains in tensile strength after fungal exposure (oil, gain 30%, oven, gain 3%). Microscopic examination confirmed that a soft rot was minimal in heat treated samples, i.e. it was mainly confined to wood cell wall penetration. The combined effects of UV and fungi caused further losses of tensile strength in both oven and oil heat treated samples, but this loss was less severe than that which occurred in untreated controls. However, due to the severity of the initial losses caused by the oil heat treatment, the highest losses overall were in those oil heat treated samples exposed to UV (82%) and UV and decay (78%). Microscopic examination revealed that decay was more advanced in UV exposed samples. The FTIR spectra of oven heat treated samples did not show any change, while the oil heat treated samples increased absorbance at 1737cm-1 and 1450cm-1 relating to the presence of oil. Following fungal decay, no changes were observed, this corresponds with the cavity attack by soft rot fungi, which leave adjacent portions of cell wall material untouched. The ultra violet exposure affected the spectra of all specimens, increasing the absorbance at 1737cm-1. This relates to photo-degradation of the hemicelluloses, forming new carbonyl groups. In the UV exposed untreated wood there were also increases in absorbance at 1510 and 1160cm-1 relating to alterations in lignin structure.
M D C Hale, S C Ghosh, M J Spear
Studies on the fungicidal effectiveness of a petrol derived product as a creosote alternative
1986 - IRG/WP 3384
This work, appears first because of the necessity to find out a profitable use for a residual product of the petrol pyrolisis, and second, because the lack of high natural durability wood used until now-a-days to build posts and sleepers in creosote lacking countries. Our main objective was pointed to the characterization of this new product and to find out the effectiveness against the wood-destroying fungi, compared to the creosote response.
A M Navarrete, M T De Troya.
Preservative effectiveness of medium temperature creosote oil
1990 - IRG/WP 3597
Medium temperature creosote oil (MTC) was prepared by removing light naphthalene oil and heavy anthracene oil from the coal tar by means of fractional distillation. We conducted the effectiveness test of MTC in accordance with the JWPA method for testing effectiveness of surface coatings with preservatives against decay fungi. The soil treatment test against Serpula lacrymans was also carried out with Kanuma-soil. Preservative effectiveness of MTC was sufficient for wood against Tyromyces palustris and Serpula lacrymans. The hyphal growth of Serpula lacrymans to the treated layer with MTC from the nutrient one is suppressed in the soil treatment test.
S Doi, A Yamada, Y Suda