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Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Understanding of the effect of ancestral and natural saltwater treatment on durability, fibers densification and chemical modification of palm wood
2018 - IRG/WP 18-10921
The palm-tree sector plays a very important role on both the socioeconomic and ecological levels, in Tunisia. There are three million trees in Tunisian palm plantations, ensuring a potential significant wood production, mainly in the craft and furniture industries. In the past, Date Palm wood (Phoenix dactylifera L.,) was also used as structural material. Its low natural durability and its low m...
M T Elaieb, A Namsi, M Tella, M-F Thévenon, K Chandelier


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


The influence of chemical and thermal modification on homogeneity between sapwood, heartwood, and transition wood of short rotation teak
2023 - IRG/WP 23-40961
Short rotation teak wood has low quality especially in durability. Heartwood presents sufficient natural durability and poor impregnability; meanwhile, most sapwood requires special treatment to increase its durability. The objective of this work was to investigate the effect of thermal or chemical treatment on homogenization between sapwood, heartwood, and transition wood for some selected proper...
R Martha, B George, W Darmawan, P Gerardin


The impact of pre-drying on treatment level variations of esterified solid wood analysed by X-ray densitometry
2023 - IRG/WP 23-40977
Wood modification requires homogenous treatment levels within the wood matrix to prevent insufficiently treated areas being subject to biodeterioration. Esterification of wood by citric acid and sorbitol can show differences in density caused by uneven chemical distribution during the curing phase and can be detected by x-ray densitometry. This study used density profiling to investigate the influ...
A Treu, S O Amiandamhem, E Larnoy


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


The effect of certain wood extractives on the growth of marine micro-organisms
1977 - IRG/WP 438
S E J Furtado, E B G Jones, J D Bultman


Biological screening assays of wood samples treated with creosote plus chemical additives exposed to Limnoria tripunctata
1980 - IRG/WP 408
Laboratory methods for exposure of treated wood coupons to Limnoria tripunctata are described. Chemical additions to creosote were screened using this method. Three pesticides, Endrin, Kepone, and Malathion proved particularly effective. The addition of varying percentages of naphthalene to creosote using several treatment methods are currently being assayed. Results to date show that the coupons ...
B R Richards, D A Webb


Results of chemical analyses in the field of wood preservation in the Bundesanstalt für Materialprüfung
1973 - IRG/WP 321
The results of qualitative and quantitative chemical analyses of wood preservatives are often the basis for evaluating the various works in the field of wood preservation. In the past 10 to 15 years a number of such works was carried out in the Bundesanstalt fur Materialprüfung, Berlin-Dahlem, dealing with the identification and effectiveness of wood preservatives and with methods of wood preserv...
H J Petrowitz


Protocol for evaluation and approving new wood preservative
1985 - IRG/WP 2159
M E Hedley, J A Butcher


Di-sodium fluorophosphate, a new fluorine containing, water-borne wood preservative
1986 - IRG/WP 3373
The physical, chemical properties of Di-sodiumfluorophosphate (Na2PO3F) are compared with those of a trade-mark SF-salt. The opposition of biological activity and toxicological data showed that Di-sodiumfluorophosphate may be a suitable alternative to SF-salts ( based on MgSiF6)....
D Seepe, W Metzner


Discussion of diiodomethyl p-tolyl sulfone (Amical® 48) as a fungicide for wood preservatio
1987 - IRG/WP 3425
The effectiveness of diiodomethyl-p-tolyl sulfone (Amical® 48) as a fungicide for preservation of wood is supported by a discussion of results from the literature and current research programs....
J M Stamm, K J Littel, F M H Casati, M B Friedman


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