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Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are repor...
A Pizzi, W E Conradie, A Jansen


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


Changes in pore structure and cell wall volume in wood decayed by brown- and white-rot fungi
1991 - IRG/WP 1501
Sweetgum (Liquidambar styraciflua L.) wood blocks were decayed by Postia (=Poria) placenta or Phanerochaete chrysosporium in soil-block cultures. Decay was terminated at various weight losses, and the pore volumes available to probes of various molecular weight and diameter were determined by the solute exclusion technique (Stone, J.E. and A.M. Scallan. 1968. Cellulose Chem. Technol. 2, 343-358.)....
D S Flournoy


Soft rot decay in acetylated wood. Chemical and anatomical changes in decayed wood
2002 - IRG/WP 02-40231
Acetylated Beech (Fagus sylvatica) and Scots Pine (Pinus sylvestris) wood were studied in soil beds under laboratory conditions for longer periods. High mass losses and dynamic MOE losses were measured in non-acetylated wood and at lower weight percent gains (WPG). Rapid losses of lignin, holocellulose and ?-cellulose occurred in non-acetylated beech wood and no losses were detected at the highest...
B Mohebby, H Militz


The role of oxidation in wood degradation by brown-rot fung
1992 - IRG/WP 92-1562
Brown-rot fungi are suggested to degrade cellulose by oxidation with hydrogen radicalsformed eg. in the conversion of hydrogen peroxide in the Fenton type reactions. The stuctural changes in the holocellulose in wood induced by Fenton's reaction on wood components are very similar to those caused by brown-rot fungi. In this work the effect of the Fenton reaction on wood components was stu...
A-C Ritschkoff, J Pere, J Buchert, L Viikari


FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem


Micromorphological and chemical changes of archaeological woods from wrecked ship's timbers
1987 - IRG/WP 4136
Micromorphological and chemical alterations of sea-waterlogged woods obtained from the ship-wrecked materials which had been submerged in Yellow Sea for over 700 years were investigated. The woods were deteriorated in varying degrees by marine organisms depending on species and parts of the woods. Under the light and scanning electron microscope the morphological characteristics of deteriorated wo...
Y S Kim


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel