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Improving the weather resistance of glue-laminated jarrah and karri
1994 - IRG/WP 94-40017
Surface modification and dimensional stabilisation significantly increased the dry and wet shear strength of karri and jarrah lap-shear specimens (laminates) bonded with resorcinol formaldehyde. The combination of surface modification (sanding/sodium hydroxide treatment), and furfurylation produced the highest dry and wet shear strengths. Acetylated laminates had the lowest dry bond strength, but ...
J Balfas, P D Evans


Thermal modification of non-durable wood species 1. The PLATO technology: thermal modification of wood
1998 - IRG/WP 98-40123
The PLATO technology is an innovative upgrading technology with low environmental impact, which can be applied to fast grown and non-durable wood species. This technology is based on a thermal modification of solid wood without the addition of chemicals (e.g. preservatives), consisting of a hydrothermal treatment, followed by drying and curing. The PLATO technology results in a substantial improve...
M J Boonstra, B F Tjeerdsma, H A C Groeneveld


Improvements of stability and durability of beechwood (Fagus sylvatica) by means of treatment with acetic anhydride
1991 - IRG/WP 3645
In the present investigations, beechwood (Fagus sylvatica) was treated with non-catalysed acetic anhydrid at 120°C and some physical- and biological parameters of the treated wood were compared with those of non-treated wood. The radial and tangential shrinkage and swelling, respectively, and the absorption capacity of the acetylated wood against moisture is considerably lower. The durability aga...
H Militz


Preliminary results of the treatment of wood with chlorosilanes
1981 - IRG/WP 3172
It is clear from the initial data reported here that the treatment of pine sapwood with chlorosilanes under the reaction conditions employed did not significantly reduce the decay by both white rot and brown rot fungi. Only the dichlorosilane compounds showed to possess some protective action against fungal attack. Before drawing conclusions on the application of organosilicon compounds as potenti...
M Stevens


Influence of concentration, catalyst, and temperature on dimensional stability of DMDHEU modified scots pine
1998 - IRG/WP 98-40119
Dimethyloldihydroxyethyleneurea (DMDHEU) is being used in textile industry to improve wrinkle recovery. Trials on solid wood have been performed to minimise swelling of the wood. This paper focuses on the effect of various types and concentrations of catalyst and reaction temperature on the dimensional stability of Scots pine. Three different catalysts, NKS (based on magnesium chloride), 3282 (bas...
M Van der Zee, E P J Beckers, H Militz


Modified Wood – Methods, testing and applications: Outcomes of the EU-Thematic Network
2003 - IRG/WP 03-40268
In the last decade, interest in the development of wood modification systems has increased in Europe. Alongside several industrial initiatives for heat treatments, there have also been scaling up and pilot plant projects for chemical wood modification. Between 2000 and 2003, the European Commission funded the "Thematic Network on Wood Modification". This paper will feature the modification process...
D Jones, W Homan, J Van Acker


Determination of the water sorption properties and preliminary results from field tests above ground of thermally modified material from industrial scale processes
2004 - IRG/WP 04-40279
In this study the differences in moisture behavior and durability above ground of heat treated wood originating from different European industrial heat treatment plants by means of the water sorption properties as well as field tests were examined. The manufacturers of heat treated material were: PLATO Hout B.V./Netherlands, Thermo Wood (Premium wood)/ Finland and Menz Holz/ Germany, where Oil-...
C R Welzbacher; A O Rapp


Fenton's reagent as a modification tool in brown-rot decay
1996 - IRG/WP 96-10155
A biomimetic approach was used to clarify the role and importance of the Fenton-type reaction in the carbohydrate degradation by brown-rot fungi. Spruce sawdust and microcrystalline cellulose were modified in the H2O2/Fe(II) treatment. The degree of hydrolysis of the pretreated spruce sawdust was clearly increased with the complete cellulase (Econase), purified endoglucanase from Trichoderma reese...
M Rättö, A-C Ritschkoff, J Buchert, L Viikari


Steam/hold/APM boron treatment - Treatability trials with green gauged radiata pine
1987 - IRG/WP 3439
Freshly sawn 100 x 50 mm radiata pine was green gauged, steam conditioned and preservative treated with a mixture of borax and boric acid using a modified Alternating Pressure Method (APM) treatment schedule. A 12 hour holding period between steam conditioning and treatment resulted in the necessary moisture loss and moisture re-distribution to facilitate treatment to NZ Timber Preservation Author...
P Vinden


Studies on the resistance of DMDHEU treated wood against white-rot and brown-rot fungi
2005 - IRG/WP 05-10566
Beech wood (Fagus sylvatica) modified with the textile finishing agent 1,3 dimethylol-4,5-dihydroxyethylen urea (DMDHEU) has shown to improve durability against the white-rot fungus Trametes versicolor. In a mini-block test, the weight loss over eight weeks of incubation decreased with increasing weight percent gain (WPG) of DMDHEU. At 25% WPG, no significant weight loss was observed, while untrea...
P Verma, C Mai, A Krause, H Militz


Efficacy of anhydrides as wood protection chemicals
1997 - IRG/WP 97-30162
Wood samples treated with anhydrides of various compositions have been examined for their decay resistance and moisture behaviour. For this purpose two brown rot fungi (Coniophora puteana and Gloeophyllum trabeum) and two white rot fungi (Trametes versicolor and Pycnoporus sanguineus) were used in conventional and modified soil block tests. The modified soil block tests conformed to the method as ...
S C Forster, M D C Hale, G R Williams


The effects of chemical modification on the physical properties of alder and spruce particleboards
2005 - IRG/WP 05-40300
In this paper, it was aimed to improve some physical properties of chemically modified particleboard, made from spruce and alder species, spreading widely at Black sea region in Turkey. Spruce and alder chips were reacted with acetic, succinic, maleic and phthalic anhydrides at constantly heat for 3 hours then, hot pressed at 150 °C by using Phenol formaldehyde (PF) resin. Target board density wa...
E Dizman, Ü C Yildiz, H Kalaycioglu, S Yildiz, A Temiz, E D Gezer


Sphaeroma terebrans Bate: A note on distribution and preservative tolerance in Florida coastal waters
1987 - IRG/WP 4135
Treated test panels were installed in January 1984 in a Florida estuary where Sphaeroma terebrans had severely damaged pilings treated with copper chromate arsenate (CCA). Test treatments were CCA at three retentions, coal-tar creosote at three retentions, creosote with chlorpyrifos, dual treatment with CCA and creosote, and three types of chemical modification of the wood test panels. We describe...
B R Johnson, E D Estevez, S A Rice


The biological effectiveness of wood modified with heptadecenylsuccinic anhydride against two brown rot fungi: Coniophora puteana and Gloeophyllum trabeum
1992 - IRG/WP 92-3705
A modified soil block test was carried out using wood samples reacted with heptadecenylsuccinic anhydride (ASA). This modification gave good resistance to decay brought about by the brown rot fungi Coniophora puteana and Gloeophyllum trabeum during the twelve week exposure period. Results indicated that there was a good correlation between increased loading of modifying reagent and an increase in ...
C Codd, W B Banks, J A Cornfield, G R Williams


Modification of wood by graft treatment
2003 - IRG/WP 03-40257
New water-repellent systems for wood are needed to improve the weathering characteristics. This study found that treatment of wood with chemical grafting systems imparted substantial water repellency. Different direct oxidative grafting systems were examined. Specifically, KMnO4, Fe(NH4)(SO4)2·12H2O, Fe2(SO4)3·5H2O, and (NH4)2Ce(NO3)6 were used as initiators and styrene as the monomer. All the...
M M Morshed, D D Nicholas, C Pittman Jr, T Schultz


Investigation of the suitability of silver fir (Abies alba Mill.) for thermal modification
2004 - IRG/WP 04-40275
In this study the suitability of silver fir (Abies alba Mill.) was examined for thermal modification. Comparative experimental investigations were performed with silver fir and Norway spruce (Picea abies Karst.) after thermal treatments. Besides properties, which characterize the quality of heat treatments, like dimensional stability and resistance against fungal attack, strength properties of the...
C Brischke, A O Rapp


Effect of some resin treatments on fungal degradation reactions
1999 - IRG/WP 99-10318
The effect of impregnation of wood with vegetable oil, tall oil and two water soluble on fungal degradation reactions was assessed by hydrolysis and enzyme activity measurements. The experiments were carried out by using isolated enzyme preparations and a living brown-rot fungus Poria placenta. The results indicate that the inhibitory effect of treatments was clearly directec towards the enzymatic...
A-C Ritschkoff, M Rättö, A J Nurmi, H Kokko, A O Rapp, H Militz


Tunnelling bacteria
1983 - IRG/WP 1186
The micromorphology of decay in wood caused by a certain group of single-cell bacteria, called tunnelling bacteria (TB), is described. TB are characterised by their tunnelling ability within the secondary cell walls of wood fibres. Pure cultures of TB have not yet been obtained although the typical decay patterns can be reproduced using mixed bacterial cultures. Some indications of lignin degradin...
T Nilsson, G F Daniel


Influences of the hydro-thermal treatment on physical properties of beech wood (Fagus orientalis)
2005 - IRG/WP 05-40303
Influences of the hydro-thermal treatment on physical properties of beech wood were studied. Wood specimens (2×2×2cm) were treated in two steps. At first step, samples were treated at 160,180 & 200ºC for 4, 5 & 6 hours. At second step, treated samples were cured based on their first step treatment temperatures (160,180 & 200ºC) for 16 hours. The treated samples were soaked in water...
B Mohebby, I Sanaei


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Thermal modification of non-durable wood species 2. Improved wood properties of thermal treated wood
1998 - IRG/WP 98-40124
Properties of wood treated in a new heat-treatment process called the PLATO-process have been studied. Several wood species have been treated using this new thermal modification process using a range of process conditions (mainly time and temperature). In this study the characteristics of the treated wood were determined using samples from whole planks treated on pilot plant scale. The modified ch...
B F Tjeerdsma, M J Boonstra, H Militz


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Dimensional stability and decay resistance of wood upon modification with some new type chemical reactants
1994 - IRG/WP 94-40028
Solid wood of home grown species can be upgraded by chemical modification with environmentally acceptable chemicals. The best kwown example of modification reaction is acetylation with acetic anhydride. A continued search for reactive chemicals other than acetic anhydride is ongoing, aiming at the improvement of technical properties of wood. This contribution deals with the results of a screening ...
P Goethals, M Stevens


Assessing the bioresistance conferred to solid wood by chemical modification
1997 - IRG/WP 97-40099
The chemical modification of wood using straight chain alkyl anhydrides can considerably enhance its durability. This paper presents an assessment of the effectiveness of these modifiers in improving the biological resistance of a susceptible softwood when exposed to four different basidiomycete fungi, soft rots and the larvae of the house longhorn beetle (Hylotrupes bajulus). It was clear that so...
E D Suttie, C A S Hill, D Jones, R J Orsler


Rapid fixation of Chromated Copper Arsenate (CCA) wood preservatives by microwave treatment
2000 - IRG/WP 00-40184
Rapid microwave heating of freshly chromated copper arsenate (CCA) treated timber indicates that rapid preservative fixation is possible within approximately 40 seconds. The leaching of CCA was evaluated using simulated rainfall. Cost analyses indicates that microwave fixation using an on-line conveyor belt fixation process with an output of 4m3/hour using a microwave power supply of 230 kW costs ...
G Torgovnikov, P Vinden, E Mapanda, P R S Cobham


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