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Properties of cellulose degraded by the brown rot fungus, Postia placenta
1988 - IRG/WP 1350
To gain further understanding of the nature of the cellulose depolymerizing agent or agents of brown-rot fungi, brown-rotted cellulose was chemically and physically characterized. Various culture conditions, such as low nitrogen and elevated oxygen levels, did not induce degradation of cellulose by Postia placenta in liquid cultures. Therefore, brown-rotted cellulose for analysis was prepared by a...
T L Highley, R E Ibach, T K Kirk


A laboratory evaluation of tributyltin ethanesulphonate as an aqueous fungicide in wood preservation
1983 - IRG/WP 3229
Toxic limit data, using both leached and unleached wood test blocks, are reported for aqueous solutions of tributyltin ethanesulphonate against four Basidiomycete fungi, Poria placenta, Gloeophyllum trabeum, Coriolus versicolor and Coniophora puteana. An in situ study of the tributyltin compound in Scots pine and ponderosa pine sapwood has been carried out, using the technique of 119mSn Mössbauer...
R Hill, P J Smith, J N R Ruddick, K W Sweatman


EPR observation of Mn(II) in decayed wood
2002 - IRG/WP 02-10443
Preliminary Electron Paramagnetic Resonance (EPR) studies of copper/chromium (CC) treated spruce wood, subjected to laboratory soil decay test showed increased intensities of Mn(II) EPR signal in partially decayed specimens. Several reasons might be responsible for this phenomenon: Mn(II) could originate from the wood after being released from the typical ligand binding, from reduction of other Mn...
M Petric, M Humar, P Kalan, F Pohleven, U Schoknecht, M Šentjurc


Preliminary observations on tributyltin treated Scots pine sapwood using 119Sn (Mössbauer and NMR) spectroscopic techniques
1984 - IRG/WP 3312
119mSn Mössbauer data are presented for bis(tributyltin) oxide, tributyltin ethanesulphonate, bis(tributyltin) carbonate and tris(tributyltin) phosphate, both in the pure form and in Scots pine sapwood. The structures proposed for these compounds, in the solid state, are supported by 119Sn nuclear magnetic resonance spectroscopy.
R Hill


Uptake of copper by mycelium of wood decay fungi growing on copper S-substituted thioglycolate containing nutrient media
1998 - IRG/WP 98-10291
Mycelia of Trametes versicolor, Coniophora puteana and Poria monticola were grown on potato dextrose agar (PDA) media, containing various concentrations of copper N,N-dimethyldithiocarbamoylacetate (which may be regarded as a copper S-substituted thioglycolate). The tested copper compound revealed relatively low fungicidal activity. After 13-18 day growing period, we determined concentrations of a...
M Humar, M Petric, F Pohleven, P Kalan


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


A spectroscopic investigation of copper ethylenediamine fixation in wood
1999 - IRG/WP 99-20160
The fixation reaction which take place between copper ethylenediamine (Cu-en) solution and wood were expolored using X-ray photoelectron spectroscopy (XPS) and Fourier Transformed Infrared Spectroscopy (FTIR). The FTIR spectra revealed that copper reacts with the carboxylic acid and phenolic groups in wood to form stable complexes. The copper ethylenediamine complexes formed in wood were identifie...
Xiao Jiang, J N R Ruddick


Chemical reactions involved in furfurylation of solid wood - An investigation by ATR-IR spectroscopy
2006 - IRG/WP 06-40347
Wood modification with furfuryl alcohol (FA) has gained renewed interest during the last five to ten years because of advances in process technology and because of increased focus on the environmental hazards of traditional wood impregnation. The reaction mechanisms involved in the furfurylation process are not yet understood in detail. In the work presented here, the chemical reactions and their ...
T Mark Venås, L Garbrecht Thygesen, S Barsberg


Assaying Pentachlorophenol-treated Wood Using XRF
2007 - IRG/WP 07-20362
A study was conducted to evaluate the effect of oil type on the performance of test posts treated with oil-penta and exposed in DeQueen, AR for forty years in ground contact. The original assays for the poles were done by lime ignition, a practice used sparingly today in treating plants or by independent inspectors, in part due to the complicated analysis procedure and chances for error. XRF ins...
H M Barnes, C R McIntyre, D W Bullock , M H Freeman, G B Lindsey


Use of X-Ray Fluorescence (XRF) Spectroscopy to Determine 4,5-Dichloro-2-n-Octyl-4-Isothiazolin-3-one (DCOIT) in Wood
2007 - IRG/WP 07-20373
Organic preservative based systems are being developed as replacements for the metal based systems. Typically the chemical actives of organic preservative systems are analyzed using HPLC or GC. However, these analytical techniques require complex sample processing and involve relatively long analysis times. In addition the equipment requires maintenance and a skilled operator. One organic preser...
P Walcheski, J Ashmore, D M Laganella


Photo-degradation of modified and non-modified wood, coated with water borne acrylic coatings during artificial light exposure
2007 - IRG/WP 07-30416
A series of experiments were carried out to investigate photo-degradation of thermally modified (at 210oC and – 0.9 bars for two hours) and non-modified spruce wood (Picea abies L (Karst)), coated with transparent and semitransparent (with 3% pigment content) acrylic coatings during artificial UV light irradiation for 200 hours. Photo-degradation was evaluated in terms of colour changes througho...
M Deka, M Tomažic, M Petric


Multivariate analysis of infrared spectra for the prediction of the mechanical performance and dimensional stability of thermally modified wood
2007 - IRG/WP 07-40367
The use of calibrated mid-infrared Fourier transform (FTIR) spectroscopy for predicting the main bending strength parameters of thermally modified wood is described for the first time. The analysis is based on the handling of OSC-filtered FTIR data from control and treated wood samples, using partial least squares (PLS) regression. Sets of Norway spruce, Scots pine and Beech wood samples were th...
M M González-Peña, M D C Hale


Investigation of chemical changes in acetylated beech wood during weathering
2009 - IRG/WP 09-40460
In this study Beech wood (Fagus orientalis) acetylated and has been subjected to a variety of artificial weathering conditions (water only, light only, water and light together)in difference times (0,50,150 and 300 h), then wood surface analyzed using Fourier Transform Infrared spectroscopy (FTIR).Results shown that weathering process affected the functional groups on the wood surface. Light and w...
M Akhtari, M Arefkhani


Photostabilization of Wood with Higher Molecular Weight UV Absorbers
2010 - IRG/WP 10-30524
Higher molecular weight UV absorbers were created by reacting the epoxy-functionalized UV absorber 2-hydroxy-4(2,3-epoxypropoxy)-benzophenone (HEPBP) with maleic, phthalic or succinic anhydride. The ability of the UV absorbers to photostabilize wood was then examined. FTIR-spectroscopy confirmed that HEPBP reacted with phthalic anhydride to create a polyester that preserved the UV-absorbing benzop...
P D Evans, M J Chowdhury


Direct estimation of the durability of high-pressure steam modified wood by ESR-spectroscopy
2010 - IRG/WP 10-40508
Heat generated persistent free radicals have been detected by electron spin resonance measurement of thermally modified wood, prepared by high pressure superheated steam treatment. The specific density of these radicals have been correlated with the durability against basidiomycetes, as measured by the European standard EN113 test. In the lower range of specific radical densities, the found correl...
W Willems, A Tausch, H Militz


Silicon compounds as additives improving alkyd-based wood coatings performance
2010 - IRG/WP 10-40531
The reactivity of cellulose with solvent-born alkyd-based wood coatings supplemented with organosilanes was analyzed. Structural analysis of cellulose subjected to the reaction with organosilanes and following extraction with water was performed using Fourier-transform infrared spectroscopy (FTIR). The analyzed IR spectra comprise bands 1250 cm-1 typical for the SiC group and 800 cm-1 typical for ...
B Mazela, I Ratajczak, K Wichłacz-Szentner, P Hochmańska


Cell wall properties of softwood deteriorated by fungi: combined chemical analyses, FT-IR spectroscopy, nanoindentation and micromechanical modelling
2013 - IRG/WP 13-20527
Mechanical properties of wood are determined by its inherent hierarchical microstructure, starting at the nanometer scale, where the elementary components cellulose, hemicelluloses, and lignin build up the wood cell wall material. Fungi cause degradation and decomposition of these components and, thus, alter the mechanical properties of wood. The aim of this study is to gain new insight into these...
L Wagner, T K Bader, K de Borst, T Ters, K Fackler


Effectiveness of Copper Indicators in Treated Wood Exposed to Copper Tolerant Fungi
2014 - IRG/WP 14-20554
Wood treated with a copper based wood preservative will typically turn a green color. While the depth of copper penetration can be readily discerned from the green color of the copper it is standard practice in research and commercial treating plants to make use of a color reagent such as Chrome Azurol S, Rubeanic acid or PAN indicator to reveal the penetration more clearly. When copper treat...
L Jin, K Brown, A Zahora, K Archer


Visualization of gold/silver nanostars in wood by surface enhanced Raman spectroscopy
2014 - IRG/WP 14-30653
Nanotechnology is a fast growing up-to-date technology and ventures expeditiously in the wood preservative market. However, there is still a huge lack of understanding about the interaction and incorporation of nanoparticles (NSs) in wood. Surface-enhanced Raman scattering (SERS) offers unique advantages as an analytical tool with a high selectivity and sensitivity without matrix interference. Her...
C Geers, L Rodríguez-Lorenzo, M Placencia Peña, P Brodard, T Volkmer, B Rothen-Rutishauser, A Petri-Fink


The potential of 2D NIR imaging for wood protection research
2015 - IRG/WP 15-20566
Investigating wood and wood-based materials using infrared spectroscopy has since long been explored. Recently, image-based systems have been developed that are used in food and pharmaceutical industries for rapid screening. Such hyperspectral cameras are able to collect spatial and spectral information simultaneously, resulting in a volume with a spectral profile for each pixel of the image. We p...
J Van den Bulcke, N Defoirdt, W Li, J Van Acker


Diagnosis and control of pathology of wood used in the Alahambra Palace, Santiago de Chile
2015 - IRG/WP 15-40711
In 2008, the National Monuments Council, invites bids for the work control termite infestation in the Alhambra Palace, located in Santiago. As part of this service our company decides to make a pathological diagnosis to allow us to make the minimum of damage to the building but maximum control first. The collection of information in the field, the use of advanced technologies and our experience an...
J Poblete Escanilla, P Astaburuaga Merino


Foundation piles: analysis of beech wood decay in service life conditions
2016 - IRG/WP 16-10858
Wood piles foundation system was largely used over decades. Thus, numerous buildings over the world are based on this constructive system. In the context of reduction of CO2 emissions in the building field of constructions, substitution of concrete by wood as material for foundation piles seems to be a promising alternative. However, fluctuation of the water table level in soil may promote fungal ...
Q Kleindienst, A Besserer, M-L Antoine, C Perrin, J-F Bocquet, L Bléron


A review on prediction methods of wood natural durability
2017 - IRG/WP 17-10892
Natural durability of timber may be defined as “inherent ability of timber to attack by wood destroying organisms (bacteria, fungi, insects, marine borers) without preservative treatment. On the base of biological tests, EN-350-2 standard (Afnor, 1994), describe the classification of wood species according to their natural durability. But these specifications are not adapted in the case of wood ...
N Amusant, C Flora, J Beauchène, E Houël, C Duplais


Comparison of 1H qNMR and NIR spectroscopic methods to predict heartwood decay resistance in Dicorynia guianensis Amsh
2017 - IRG/WP 17-20601
Dicorynia guianensis is by far the most exploited wood in French Guiana, as it is an abundant tree species associated with good technological properties. However, the decay resistance of D. guianensis wood against lignivorous fungi pathogens is sometimes variable. Therefore, the development of tools to predict the decay resistance of D. guianensis heartwood is relevant in wood science and agrofore...
C Flora, G Frédéric, M-F Thevenon, Y Estevez, C Duplais, N Amusant


Profiling fungal degradation of Scots pine sapwood by short wave infrared hyperspectral image analysis
2020 - IRG/WP 20-20667
Hyperspectral image analysis of Scots pine sapwood wood affected by decay fungi has been carried out as part of a Ph.D. thesis within the project Remote Inspection of Wooden Utility Poles (RIWUP). In a lab experiment, Petri-dishes with Scots pine sapwood samples on malt agar medium were infected with two types of decay fungi, a brown rot and a white rot. The wood samples were scanned with a HySpe...
A Jochemsen, G Alfredsen, I Burud


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