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A theoretical-industrial correlation and perspective on copper-based wood preservatives - a review of thermodynamic and kinetic aspects on copper-wood fixation mechanism
2009 - IRG/WP 09-30499
Copper was and it will continue to remain one of the key active component in wood protection industry. Over the past decades, a significant effort from R&D teams in industry, academia and research institutes was directed toward understanding the copper-wood fixation mechanism, optimising the copper retentions in the wood and reduce leaching in order to maximized performance, prolong the lifetime o...
R Craciun, M Maier, J Habicht


Natural compounds: A review of their use for wood protection
2010 - IRG/WP 10-30545
A lot of research in the field of wood protection has focused on natural compounds but very few of these have been implemented by industry. This review is an attempt to bring together information from selected area of work: - A brief review of the work done on natural products as organic biocides for wood protection. - Table containing information on natural products, their use as organic biocid...
T Singh, A P Singh


Using plant oils as hydrophobic substances for wood protection
2010 - IRG/WP 10-30550
The increased interest to use oils as hydrophobic agents and the current debate about the further use of creosote emphasises the urgent need of better understanding of plant and other oils as wood protectors. The present study sheds light on the hydrophobic properties and distribution of various plant oils in the anatomical structure of Scots pine sapwood. Oil retentions from approximately 70 to 5...
D Panov, N Terziev, G Daniel


Characterization of wood modification prepared by in situ polymerization with pre-polymer and the mechanism of modification
2013 - IRG/WP 13-40633
Chemical modification of wood is a potential way to obtain high quality wood. In this study, the fast-growing poplar was impregnated with modifier using a pulse-dipping machine by in situ polymerization. Fungal decay analysis, mechanical properties and dimension stability of the natural and modified woods were investigated. The wood samples were also characterized by X-ray diffraction (XRD) Therma...
Qian Lang, Zeng Bi, Junwen Pu


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Screening method to test efficacy of fumigants against fungi and preliminary data on the efficacy of sulfuryl fluoride
2014 - IRG/WP 14-20551
Methyl bromide is being phased out and there is an urgent need to find a suitable replacement that is effective in reducing exotic pest establishments via trade in wood products. Efficacy data for established phytosanitary fumigants were mostly developed for arthropods and nematodes, and limited information exists for plant pathogens. Increased interest in developing a fast screening process for f...
A Uzunovic, A Mukherjee, R Mack, P Elder, S Myers


Modern Instrumental Methods to Investigate the Mechanism of Biological Decay in Wood Plastic Composites
2014 - IRG/WP 14-40674
Various instrumental techniques were used to study the fungal decay process in wood plastic composite (WPC) boards. Commercial boards exposed near Hilo, Hawaii (HI) for eight years in both sun and shadow locations were inspected and tested periodically. After eight years of exposure, both boards were evaluated using magnetic resonance imaging (MRI), while a selected area of the board exposed in sh...
G Sun, R Ibach, M Gnatowski, J Glaeser, M Leung, J Haight


Fungicidal Effect of Tobacco Stalks (Nicotiana tabacum L.) Against Brown Rot Fungi “Coniophora puteana”
2016 - IRG/WP 16-10865
In this study it was investigated that the fungicidal effect of tobacco plant (Nicotiana tabacum L.), which is grown in many countries of the world, against brown rot fungi “Coniophora puteana”. The protective effect of this plant on Scotch pine (Pinus sylvestris L.) wood was considered by means of fungi decay test (EN 113). The wood samples have been treated by five different extracts; at 3%,...
Ü C Yıldız, S Yıldız, A Yılmaz, S Durmaz


Modifying wood with paraffin wax emulsion impregnation and thermal modification: hydrophobization effect and mechanism of the combined treatment
2016 - IRG/WP 16-40726
The aim of this study was to enhance the water repellency of wood by a combined treatment of paraffin wax emulsion (PWE) impregnation and thermal modification. Two different treating procedures were used to modify the southern pine (pinus spp.). One is first PWE impregnation and then thermal modification, another is first thermal modification and then PWE impregnation. The treated samples were imm...
Wang Wang, Jinzhen Cao, Cong Chen


Role of cell wall specific moisture content on the brown-rot fungal attack on wood
2016 - IRG/WP 16-40736
Wood is a hydroscopic resource because the cell wall polymers contain hydroxyl and other oxygen-containing groups that attract moisture through hydrogen bonding. Moisture content varies with changing moisture content in its environment. The moisture content in wood is responsible for many of the performance properties we observe. The strength properties of wood are dependent on the moisture con...
R M Rowell


Mechanism of nano metal fluorides against fungi
2018 - IRG/WP 18-30730
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredient in wood preservatives such as copper and boron. Wood specimens treated with fluoride sols of MgF2 and CaF2 have been tested against brown-rot fungi (Coniophora puteana and Rhodonia placenta) in accordance with EN 113 and against termites (...
S M Usmani, K Klutzny, I Stephan, T Hübert, E Kemnitz


Recent findings clarifying the mechanism of brown-rot decay protection in acetylated wood
2018 - IRG/WP 18-40827
This paper summarizes the findings obtained during my PhD research over the past three years. The results provide insights which help to understand the enhanced brown-rot decay resistance of acetylated wood with particular emphasis on the role of water. The protection acetylation provides is derived from moisture exclusion within the acetylated cell wall, but the exact mechanism by which water is ...
G Beck


Non-stochiometric oxidation and ROS generation promoted by guaiacol lignin structures and lignocelluose surfaces may be a component of brown rot fungal degradation mechanisms
2019 - IRG/WP 19-10937
Model guaiacol compounds representing lignin monomers, as well as DHP-lignin and wood flour of controlled particle size were used to assess iron reduction at the pH of the natural wood cell wall. All compounds functioned as electron donors for ferric iron, with the lignin monomers demonstrating capacity for non-stochiometric reduction of iron with multiple moles of ferric ion reduced per mole of l...
Y Tamarua, M Yoshidaa, L D Eltisb, B Goodell


The anti-weathering mechanism of extractives in thermally modified Scots pine
2019 - IRG/WP 19-40880
Results from the electron spin-resonance spectroscopy (ESR) analysis indicated that thermally modification of wood can inhibit the generation of phenoxyl radicals during UV irradiation and consequently lead to the increase of the color stability of wood. In order to clarify the evolution and role of extractives in thermally modified wood during the process of weathering, the compositions of aceton...
H Shen, J Cao


A new approach to wood protection: Potential of biologically synthesised CuO and ZnO nanoparticle formulation as a wood preservative
2022 - IRG/WP 22-30758
Even though metal nanoparticles are effective in protecting wood, they are less preferred, as they are synthesised using methods which are expensive and are not environmentally friendly. Biological synthesis of nanoparticles using plants, fungi, yeast, bacteria and viruses, has been accepted as an alternative approach and is referred to as green synthesis. Utilization of biologically synthesised n...
Shiny K S, R Sundararaj, N Mamatha


The cellulose binding mechanism of a novel cellulose binding domain from the brown-rot fungus Gloeophyllum trabeum
2023 - IRG/WP 23-11021
In nature, wood decay is caused by various wood-rotting basidiomycetes. Wood-rotting basidiomycete are mainly divided into white-rot fungi and brown-rot fungi. Their main carbon source is cellulose of the wood cell wall during wood decay, and they produce a variety of enzymes to decompose cellulose. The cellulolytic enzymes often possess a cellulose binding domain (CBD) as an additional domain con...
M Aoki, Y Kojima, M Wada, M Yoshida


Efficacy of a wide-spectrum plant bio-based anti-termite product - Laboratory trials
2023 - IRG/WP 23-11024
Compared to the number of timbers available, the list of wood species resistant to termites is rather limited and largely composed of tropical timbers. In addition, due to climate change and environmental degradation, together with global trade, a significant global expansion of termites is predicted along with the economic losses due to their activities. Therefore, there is a demand to find produ...
M-F Thévenon, F Chopinet, J Vuillemin, A Robert, S Lafay, D Messaoudi


How the biochemical activities of polyphenols may be effective for the protection of wood deterioration by termites?
2023 - IRG/WP 23-30789
In spite of the remarkable mechanical characteristics of wood for building construction and furniture industry, this material is prone to biodeterioration by xylophagous organisms. This compromises its durability and performances during storage and services, and results in considerable economical losses estimated by the billions. Protection against fungi, termites and other wood biodegrading organ...
J-P Joseleau, D Messaoudi, K Ruel


Potential of plant polyphenol extracts in pesticide formulations against Xylophagous insects
2023 - IRG/WP 23-30790
Termite castes (soldiers, nymphs, and reproductives) are unable to feed themselves and are fed via trophallaxis from the workers which degrade the cellulose from wood. It is of great economical importance to ascertain the efficacy of preservatives against wood decay organisms in order to extend wood products service life. Remedial chemical product applications are used primarily as wood treatments...
K Ruel, D Messaoudi, J-P Joseleau


Synthetic Oxalate/ß-glucan Fungal Extracellular Matrix Demonstrates Potential Inhibition of Extracellular Enzyme Diffusion into Wood Cell Walls, and Calls into Question the Role of Enzymes in Wood Decay
2025 - IRG/WP 25-11053
ß-glucan is the major component of the extracellular matrix (ECM) of many fungi, including wood degrading fungi. Many of these species also secrete oxalate into the ECM. Our research demonstrates that ß-glucan forms a novel, previously unreported, hydrogel at room temperature with oxalate. This finding better explains the gel-like nature of the fungal ECM. Oxalate, at relatively low levels, was ...
B Goodell, G A Tompsett, G Perez-Gonzalez, K Mastalerz, M Timko


Revealing the degradation process of Moso bamboo (Phyllostachys edulis) by different decay fungi
2025 - IRG/WP 25-11060
Moso Bamboo (Phyllostachys edulis) is the main bamboo species for engineering; however, it is highly susceptible to various fungi during use. In this study, four prevalent decay fungi, including two brown rot fungi and two white-rot fungi, were used as the test fungi to investigate the changes in structure and chemical composition of Moso bamboo samples at different incubation times in order to be...
J Xue, D Cui, M Zhou, J Cao


Enhanced Flame Retardancy in Wood via In Situ Polymerization of Phosphorus-Containing Ionic Liquids
2025 - IRG/WP 25-20736
Wood, a ubiquitous material in furniture and construction, is limited by its natural flammability. Existing wood flame retardant technologies are often ineffective and lack environmental sustainability. Ionic liquids (ILs), known for their non-flammability and non-volatility, offer a green solvent solution to these challenges. In this study, we synthesized a novel phosphorus-containing, polymerisa...
J Jiang, Y Wu, J Luo, W Qu


Carbon quantum dots as a fungicide and its applications in wood
2025 - IRG/WP 25-20754
In this work, we synthesised nitrogen-doped carbon quantum dots (CQDs) via a microwave assisted method. CQDs with proper structure showed excellent anti-fungal effects against both brown (Postia placenta, Pp) and white rot decay fungi (Trametes versicolor, Tv) on wood. The underlying anti-fungal mechanisms of CQDs on wood were further elucidated. We found that positively charged nano-sized CQDs pr...
X Zhao, Z Zhang, M Zhou, J Cao


Enhancing the Effectiveness of Penflufen by using a Plant Booster
2025 - IRG/WP 25-20759
Penflufen (Preventol® A 800) is a modern pyrazole fungicide which has been approved by the US EPA for the use in wood protection in 2018. Penflufen is an inhibitor of the succinate dehydrogenase (SDHI). It is highly efficient against wood decaying basidiomycetes fungi. In the European standard efficacy test EN 113/ EN 84, penflufen is controlling both brown rot and white rot fungi at the low rete...
D Messaoudi, A Robert, P Meckler, T Jaetsch


CIOL Wood – Industrialization of Sustainable Wood Products: Progress and Prospects
2025 - IRG/WP 25-30820
CIOL® is an innovative, low-cost, non-toxic wood modification system designed to replace traditional, non-sustainable treatments used for wood protection. Since our last contribution in 2023, significant progress has been made in the development of CIOL® towards industrial-scale production. This update presents new results on fire protection, mechanical properties, and the continued scaling of t...
J Biørnstad


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