Your search resulted in 32 documents. Displaying 25 entries per page.
Interactions between wood and propiconazole in supercritical carbon dioxide
2009 - IRG/WP 09-40461
Understanding the movement and deposition of biocides in wood is a fundamental aspect of the supercritical wood impregnation process and a key issue in developing the process e.g. to handle wood of larger dimensions. Previous research on supercritical wood impregnation frequently reports of a biocide concentration gradient in impregnated samples i.e. a lower concentration of biocides in the core o...
A W Kjellow, O Henriksen
Analysis of tebuconazole in wood treated with Tanalith™ E
1999 - IRG/WP 99-20158
A simple gas chromatographic method for determining tebuconazole in Tanalith™ E treated wood is described. A two step sequential extraction procedure with methanol was used. Sample extracts were analysed without cleanup or concentration using capillary column GC with thermionic specific detection. The performance of the method was assessed using radiata pine (Pinus radiata) sapwood, radiata pine...
D E Ferlazzo
An investigation into the stability of TBTO in LOSP-treated radiata pine
1987 - IRG/WP 3459
Nuclear magnetic resonance (NMR) spectroscopy and reverse phase paper chromatography were used to characterise the organotin compounds found in radiata pine treated with bis (tri-n-butyl) tin oxide (TBTO). Preliminary results indicate that the preservative is remarkably unstable in wood after light organic solvent preservative (LOSP) treatment. Significant decomposition of TBTO occurs in a matter ...
K J Archer, R Meder
Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell
Alternative technologies for wood wastes recycling - Part B: Biotreatment of PCP- and creosote-treated wood
1998 - IRG/WP 98-50101-18 b
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
S Legay, P Marchal, G Labat
Role of Global Cooperation in Wood Protection for Conserving Forest Resources
2007 - IRG/WP 07-50249
The current uses of treated wood are discussed along with the emerging concerns for continued use of these products. The issues of new chemicals, treatments for wood based composites, migration of chemicals from treated wood, and the disposal of these products at the end of their useful life are all outlined. The potential for the IRG to serve as the focus for research discussion as well as coll...
J J Morrell, G Deroubaix
Bending properties of TCMTB-treated Southern pine sapwood using supercritical carbon dioxide impregnation process
1997 - IRG/WP 97-40080
The effects of elevated pressure and treatment with thiocyanomethylthiobenzothiazole (TCMTB) on the bending properties of Southern pine sapwood were evaluated at pressures ranging from 1,800 to 3,600 psi. All bending properties were affected to some extent by supercritical fluid treatment. Modulus of elasticity and work to maximum load were not significantly affected by pressure levels. Modulus of...
Gyu-Hyeok Kim, S Kumar, E S Demessie, K L Levien, J J Morrell
An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner
Biocidal screening method of wood extractives by a direct use of cellulose TLC plate
2001 - IRG/WP 01-20226
Most of the methods to evaluate the biological durability of woods have focused on decay fungi and termite as deteriorating organisms and it is well known that one of the most important factors affecting the biological characteristics of wood is extractives. Bioassays for evaluating the biological activities of wood extractives have been mainly conducted with treated filter papers for termites or ...
R Yusiasih, T Yoshimura, T Umezawa, Y Imamura
Gas chromatographic determination of 1,8-naphthalimide, N-Hydroxy-1,8-naphthalimide (N,N-naphthaloylhydroxylamine) and the sodium salt of N-Hydroxy-1,8-naphthalimide
2003 - IRG/WP 03-20259
A number of naphthalimide (NI) derivatives are used as efficient laser dyes, in medicine or in scanning electron microscopy. Only N,N-naphthaloylhydroxylamine (NHA) has been shown to be an effective wood preservative against wood decay fungi and termite damage.
However, limited information is available concerning the analytical detection of NI-derivatives in treated timber. There is a clear need ...
E Melcher, F Green III
Termite Field Tests of Various Timber Species Treated with permethrin using supercritical carbon dioxide
2005 - IRG/WP 05-10560
Termite field tests were conducted on permethrin-treated Eucalyptus obliqua heartwood, Pinus radiata sapwood and P. radiata LVL. The permethrin was impregnated using either supercritical carbon dioxide (scCO2) or light organic solvent preservative (LOSP) systems. Comparative permethrin retentions were most accurately achieved in P. radiata sapwood, where no difference between impregnation systems ...
A Qader, L J Cookson, J W Creffield, D Scown
Volatile organic compounds (VOC) measured during drying of impregnated timber
2004 - IRG/WP 04-50216
Discussion about drying of impregnated timber has taken place in the Nordic countries under eighties and nineties and goes on nowadays. The drying increase the value of production and the customer gets fewer problems when handles the timber. This introduces a positive attitude to the impregnation as a process and its products. Beside the important information about the advantages of impregnated ti...
N Terziev, V Djokic
Cellular and fractural failure after supercritical fluid impregnation of four wood species
2004 - IRG/WP 04-10503
Supercritical fluids (SCFs) have been investigated for delivering biocides into sawn wood. Pressure differentials during treatment may exceed the compressive or tensile strength perpendicular to grain, creating a potential for transverse deformations that exceed elastic strain limits. Wood treated by SCF processing with CO2, a potential biocide carrier, was inspected macroscopically and microscopi...
M E Anderson, R J Leichti, J J Morrell
Supercritical fluid impregnation of Douglas-fir heartwood with cyproconazole using temperature induced deposition
2003 - IRG/WP 03-40259
A limited understanding of the fundamental aspects of supercritical fluid (SCF) impregnation in wood remains an obstacle to the development of this technology. Developing a better understanding of the effects of various process parameters on treatment results would facilitate more rational development of SCF impregnation. In this project, the effect of treating period and specimen length on su...
Sung-Mo Kang, J J Morrell
Supercritical fluid treatment: Effects on bending strength of white spruce heartwood
1993 - IRG/WP 93-20008
The effects of supercritical carbon dioxide on wood strength were evaluated using white spruce heartwood, a species known to be especially susceptible to collapse during exposure to higher pressures. The effects of pressures of 2000 or 3600 psig and temperatures of 40 or 80°C were evaluated using 30 or 60 minute exposure periods. No significant differences were noted in modulus of rupture or modu...
S M Smith, J J Morrell, E Sahle-Demessie, K L Levien
Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat
Applicability of supercritical carbon dioxide to the preservative treatment of wood-based composites
2001 - IRG/WP 01-40199
Treatability of five structural-use wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard and oriented strand board) was evaluated when supercritical (SC) carbon dioxide (CO2) was used as a carrier solvent. Treatments were conducted at three temperature 32 levels (25, 35 and 45°C) and two pressure levels [80 kgf/cm2 (7,845 kPa) and 120 kgf/cm2 (11,768...
M Muin, A Adachi, K Tsunoda
Potential for using dip/supercritical fluid treatments for wood impregnation
2004 - IRG/WP 04-40276
While supercritical fluid impregnation offers tremendous potential for impregnating wood species that resist conventional liquid preservative treatments, the resulting treatments are often not uniform among samples in a charge or between charges. One factor that influences treatment is the dynamic change in pressure that occurs during introduction of the biocide laden supercritical fluid into the ...
Sung-Mo Kang, J J Morrell
Preservative treatment of wood-based composites with a mixture formulation of IPBC-silafluofen using supercritical carbon dioxide as a carrier gas
2003 - IRG/WP 03-40251
Wood-based composites treated with a mixture formulation of a fungicide, 3-iodo-2-propynyl butylcarbamate (IPBC) and a termiticide, silafluofen using supercritical carbon dioxide (SC-CO2) as a carrier solvent were tested for their resistance to decay and termite attack in the laboratory. The treatment solution was prepared by mixing both biocides (IPBC 10 + silafluofen 1) with a co-solvent, ethano...
K Tsunoda, M Muin
Performance of Oriented Strandboard, Medium Density Fiberboard, Plywood, and Particleboard Treated with Tebuconazole in Supercritical Carbon Dioxide
2005 - IRG/WP 05-30364
The performance of oriented strandboard (OSB), medium density fiberboard (MDF), particleboard and plywood treated with tebuconazole using supercritical carbon dioxide was investigated over a 48 month exposure under harsh above ground conditions in Hilo, Hawaii. Samples treated to low retentions (<0.20 kg/m3) tended to experience decay at rates that were only slightly lower than those found wit...
J J Morrell, M N Acda, A R Zahora
The detection of organic solvent preservatives in wood by thin-layer chromatography
1975 - IRG/WP 357
A simple and rapid method for the detection of common organic solvent wood preservative materials is described. The method uses thin-layer chromatography after leaching of the preservative from sections of timber with chloroform. RF values and the sensitivity of the method are discussed and a routine procedure for identification of the organic and organometallic preservatives is proposed. Methods ...
B G Henshaw, J W W Morgan, N Williams
Internal pressure development within Oriented Strand Board during supercritical fluid impregnation
2000 - IRG/WP 00-40175
Supercritical fluids (SCF) offer an attractive alternative to conventional treatment processes for delivering material into wood, but there are many unanswered questions concerning the technology. One major concern is the potential for the development of excessive pressure gradients in the wood that might exceed the material properties and lead to crushing or other pressure-induced damage. Previou...
G Oberdorfer, P E Humphrey, R J Leichti, J J Morrell
Selecting fumigants for treatment of internal decay in wood
1986 - IRG/WP 3370
A number of potential fumigants were screened with respect to their toxicity to decay fungi, (Poria carbonica, and Lentinus lepideus) and their sorption characteristics on Douglas Fir (Pseudotsuga menziesii Mirb. Franco) wood. Wafers of infected wood were exposed to different fumigant concentrations for various times then cultured to determine viability. The lethal concentration X time (ct) factor...
P A Cooper
Stability of bifenthrin in a commercial phenol-formaldehyde plywood glue
2003 - IRG/WP 03-30311
Liquid phenol formaldehyde (PF) glue mixes used for plywood manufacture are strongly alkaline. At this pH insecticidal additives may not be stable for long periods. In order to establish practical working life of the synthetic pyrethroid insecticide, bifenthrin, in liquid PF glues the concentration of bifenthrin in the glue mix was measured under laboratory conditions over a 24 hour period. Glu...
M J Kennedy, P A Collins, R D Vella
Development of preservative treatment method using sub and super critical carbon dioxide
2007 - IRG/WP 07-40385
Significant efforts have been devoted for developing biocide impregnation method into wood materials using supercritical fluid. Developing better understandings of fluid phase and its effect on treatment results would facilitate a more rational development of supercritical fluid (SCF) impregnation. In this project, the preservative treatabilities under super- and sub-critical fluid conditions we...
Myeung-Won Cho, Sung-Mo Kang, Gyu-Hyeok Kim