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Synergistic effects between 2-HPNO, Irganox 1076 and EDTA on the inhibition of wood degradation by Coriolus versicolor
2004 - IRG/WP 04-30331
The efficiency of 2-hydroxypyridine-N-oxide (2-HPNO) as wood preservative has been investigated. As shown using classical experiments as well as using response surface methodology, the efficiency of 2-HPNO as wood preservative is strongly improved in presence a chelator like EDTA and/or of Irganox 1076 an industrial antioxidant. In these conditions, wood preservative efficiency of the mixture the ...
A Mabicka, S Dumarçay, N Rouhier, M Linder, J P Jacquot, P Gérardin, E Gelhaye


Susceptibility of angiosperm sapwood to white-rot fungal colonization and subsequent degradation: a hypothesis
1997 - IRG/WP 97-10211
It has long been recognized that angiosperm sapwood in nature is relatively easily and preferentially degraded by white-rot fungi. This susceptibility to white-rot fungi is generally believed to be mainly caused by the structure and concentration of angiosperm lignin. However, an explicit explanation as to why lignin structure makes a particular wood vulnerable to white-rot colonisation and subseq...
T Schultz, D D Nicholas


Synergistic combination of an antioxidant and wood preservative: a preliminary study
1998 - IRG/WP 98-30172
We previously proposed that extractives in highly durable angiosperm heartwood may protect wood against white-rot fungal colonization and subsequent degradation by a dual mechanism: extractives have some fungicidal activity and are also free radical scavengers (antioxidants) and thus interfere with the fungal free radical degradative mechanisms. We tested this hypothesis using the commercial bioci...
T Schultz, D D Nicholas, J Minn, K D McMurtrey, T H Fisher


Targeted inhibition of wood decay fungi: degradation of cotton cellulose
1999 - IRG/WP 99-10321
Brown-rot decay is responsible for 80% of the damage and replacement of wood in service. For nearly thirty years, researchers have postulated a one-electron oxidase system combining Fe+2 oxalic acid, and H2O2 in the production of hydroxy radicals which ultimately oxidize cellulose in situ. Recently, researchers have been investigating antioxicants, in combination with biocides (Schultz, et al.,199...
F Green III, T A Kuster


Environmentally benign wood preservatives based on organic biocide antioxidant combinations: A brief review of laboratory and field exposure results and discussion of a proposed mechanism
2004 - IRG/WP 04-30335
The combination of various organic biocides with commercial antioxidants generally increased the biocides’ efficacy 2-3 fold against wood-destroying fungi in short-term laboratory decay tests, and some positive results have been obtained after 2-4 years of outdoor exposure. The two antioxidants principally examined, propyl gallate and butylated hydroxytoluene, are low cost and, since both are f...
T Schultz, D D Nicholas, W Henry, C Pittman, D Wipf, B Goodell


Prevention of non-microbial sapwood discolorations in hardwood lumber: chemical and mechanical treatments
1997 - IRG/WP 97-30137
Sapwood discolorations in hardwood lumber that are non-microbial in origin result from the formation of pigmented starch-like granules in ray parenchyma cells. These discolorations can be prevented by treating unseasoned lumber with an antioxidant (sodium bisulfite). Exposing unseasoned lumber to microwaves or treating logs with fumigants also will prevent these discolorations. Subjecting unseason...
T L Amburgey, S Kitchens


Investigation of new wood preservation formulations based on synergies between antioxidant, 2-HPNO and Propiconazole
2006 - IRG/WP 06-30401
Wood degradation by fungi is a complex phenomenon taking place in part through oxidative reactions involving many oxidizing agents like free radicals and hydroperoxide. In order to develop novel and more environmentally benign preservative systems, mixtures of Propiconazole and antioxidants with different stabilization mechanisms were investigated to detect possible synergies allowing to reduce th...
B Bakhsous, S Dumarçay, E Gelhaye, P Gérardin


A hypothesis on a second non-biocidal property of wood extractives, in addition to toxicity, that affects termite behavior and mortality
2008 - IRG/WP 08-10638
While it is has long been recognized that heartwood extractives affect termite behavior, the exact cause and relationship between total extractives, extractive types, and termite resistance remains unclear. Generally, researchers have proposed that the extractives are toxic and/or repel termites. We propose, based on the well known fact that many extractives have excellent antioxidant properties...
T P Schultz, K Ragon, D D Nicholas


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


Vacuum drying of European oakwood: Color, chemistry and anti-oxidant potency of wood. Improving appearance in forest value added products
2008 - IRG/WP 08-40432
In hardwoods used for decorative and appearance purposes, wood colour is one of the most important factors of wood quality; in addition colour is related with durability and biological decay of wood. Wood discolouration during drying is mainly affected by heat, light, physiological reactions, combinations of reactions, biochemical and chemical reactions, and micro-organisms attack. In freshly fell...
S Sandoval, W Jomaa, F Marc, J-R Puiggali


Impact of an Antioxidant on the Efficacy of Quaternary Ammonium Compounds (Quats) and Triazoles – Seven Year Above-Ground Study
2009 - IRG/WP 09-30504
It has been reported that antioxidants have great potential for use with organic biocides in the area of wood protection. This paper demonstrates the impact of a low level of the antioxidant butylated hydroxytoluene (BHT) on the efficacy of quat-based and triazole-based formulations. A seven year lap joint test revealed a positive effect of BHT on the efficacy of quat-based formulations, especiall...
Xiao Jiang, D Biro, W Holcombe


Effect of extractives on durability of Prosopis juliflora heartwood
2009 - IRG/WP 09-30518
The heartwood of Prosopis juliflora is resistant to fungal attack caused by different brown and white rot fungi. This durability due to the presence of high amounts of extractives decreases after extraction of these latter ones with different solvents. Heartwood extractives were effective in inhibiting the growth of the fungi. Depending on the concentration used, development of the fungal mycelium...
P Sirmah, K Iaych, B Poaty, S Dumarçay, P Gérardin


Direct estimation of the durability of high-pressure steam modified wood by ESR-spectroscopy
2010 - IRG/WP 10-40508
Heat generated persistent free radicals have been detected by electron spin resonance measurement of thermally modified wood, prepared by high pressure superheated steam treatment. The specific density of these radicals have been correlated with the durability against basidiomycetes, as measured by the European standard EN113 test. In the lower range of specific radical densities, the found correl...
W Willems, A Tausch, H Militz


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Investigations on the durability of several Congo basin wood species
2015 - IRG/WP 15-10840
The sawdust of ten wood species was studied to assess their natural resistance to decay. The extractives and lignin contents were primarily determined (between 2.7-16.0% and 26.8-35.9% respectively) to give an overview of the chemical distribution. Then, a phytochemical screening (colorimetric methods) characterized the different chemical functional groups in all extracts studied. Antioxidant act...
S Mounguengui, J-B Tchinda Saha, M Kor Ndikontar, S Dumarçay, C Attéké, D Perrin, E Gelhaye,


Chemical composition of extractives of different wood compartments of Pinus merkusii and their potential implication in wood durability
2015 - IRG/WP 15-10841
Amounts and nature of extractives differ strongly according to the compartment of wood and to the nature of the wood species. Previous studies reported that knotwood of several European Pinus sp. contains extractives contents much higher than stemwood consisting mainly of lignans which may find valuable applications in cosmetic, nutraceutic or pharmaceutic sectors. Different explanations have been...
A Wijayanto, S Dumarçay, R Kartika Sari, W Syafii, P Gérardin, C Gérardin-Charbonnier


Wood Natural durability study source of biomolecules: case of Dicorynia guianensis Amsh. heartwood
2016 - IRG/WP 16-10871
The chemical investigations of Dicorynia Guianensis heartwood led to the isolation of four new indole alkaloids for the first time in this plant Compound (1) identified as spiroindolone 2’,3’,4’,9’ -tetrahydrospiro [indoline-3,1’pyrido[ 3,4-b]-indol ]- 2- one, and compound (3) described as nitrone 1-methyl-4,9 -dihydro-3H-pyrido [3, 4-b] indole 2 – oxide and were isolated for the first...
J-B Say Anouhe, A A Adima, F B Niamké, D Stien, B Kassi Amian, D Virieux, J-L Pirate,S Kati-Coulibaly, N Amusant


Characterization of waste from Pinus radiata generated during industrial thermal-treatment
2016 - IRG/WP 16-20586
The thermal-treatment is an established chemical-free process to modify wood, improving the durability and physical properties of wood through its service life. During the hydro-thermolysis several reactions from wood components occur, releasing volatile and non-volatile compounds from wood to the chamber. Once the process is accomplished, solid residues agglomerate below the wood load and gaseous...
R Herrera, D Thomas da Silva, R Llano-Ponte, J Labidi


Biocomposites based on PVA, cellulose nanofibrils and tannic acid
2022 - IRG/WP 22-40957
Biocomposite films based on a polyvinyl alcohol (PVA) with the addition of cellulose nanofibrils (CNF) as a reinforcing component and with the addition of the biologically active tannic acid (TA) were prepared. The influence of different additions of CNF and TA in the polymer matrix PVA on the mechanical properties, improvement of hydrophobicity of the prepared films was studied. In all cases, the...
U Osolnik, V Vek, I Poljanšek, Poven