Your search resulted in 253 documents. Displaying 25 entries per page.
The compatability of tributyltin fungicides and synthetic pyrethroid insecticides as wood preservatives
1987 - IRG/WP 3414
The stability of three synthetic pyrethroids, cypermethrin, deltamethrin and permethrin, to selected tributyltin compounds, Bu3SnX {where X = OSnBu3, Cl, 02CC6H5, O2C (Naphthenyl), OSO2Et}, (Bu3SnO)3PO and {NBu4} {Bu3SnCl2}, in toluene solution was investigated by infra-red spectroscopy over a six month period. It was found that only (Bu3Sn)2O reacted with the pyrethroids and that their order of r...
S J Blunden, R Hill
The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara
Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers
1991 - IRG/WP 2381
Standardized heartwood blocks of kempas (Koompassia malaccensis), keruing (Dipterocarpus sp.) and tualang (Koompassia excelsa) were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicola grisea, Petriella setifera and Trichurus spiralis in a containerized vermiculite-burial decay system according to draft CEN/TC 38 WG 4....
A H H Wong, R-D Peek
The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick
The implementation of restrictions on the use of arsenic and chromium based wood preservatives in Sweden
1995 - IRG/WP 95-50062
In 1992 the Swedish National Chemicals Inspectorate introduced restrictions on the use of wood treated with arsenic and/or chromium based wood preservatives. Such wood is now in principle only allowed for use in ground contact or in water. These restrictions have had considerable influence on the use of wood preservatives for sawn timber for the Swedish domestic market. Thus only 35% of the preser...
J Jermer, M-L Edlund, K Nilsson
Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm
An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper/chrome/arsenic preservative
1981 - IRG/WP 3180
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. The growth characteristics of spruces (Picea spp) make them attractive candidates for forestry schemes. In 1975 the UK Forestry Commission had about 400 000 hectares, about 20% of total UK forest area, planted with Sitka spruce (Picea sitchensis)...
C R Coggins
Field testing of alkylammonium wood preservatives
1983 - IRG/WP 3248
The field test performance of five alkylammonium wood preservatives is described. The relative effectiveness of three unmodified formulations was determined by calculation of a Performance Index. Of the three, didecyldimethylammonium chloride was found to be superior to octyldecyldimethylammonium chloride, and both were more effective than alkyltrimethylammonium chloride. However, none were consid...
J N R Ruddick
Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden
Leaching characteristics, decay and termite resistance of treated wood with boron compounds, N'-N-(1,8-Naphthalyl) hydroxylamine (NHA-Na), and hydroxynaphthalimide (NHA-H)
2003 - IRG/WP 03-30307
Despite many advantages of boron wood preservatives, boron itself does not adequately protect wood in ground contact and exterior applications because its natural diffusibility and susceptibility to leaching. As a result of previous studies to limit or decrease boron leaching, several fixation systems have been developed. In this study, we evaluated the effects of N'-N-(1, 8-Naphthalyl) h...
S N Kartal, Y Imamura
Fungal remediation of CCA-treated wood
2004 - IRG/WP 04-50210
This study evaluates oxalic acid accumulation and bioremediation chromated copper arsenate (CCA) treated wood by three brown-rot fungi, Fomitopsis palustris, Coniophora puteana, and Laetiporus sulphureus and ten mold and staining fungi, Aspergillus niger, Aureobasidium pullulans, Gliocladium virens, Penicillium funiculosum, Rhizopus javanicus, Ceratocystis pilifera, C. peceae, Alternaria alternata...
S N Kartal, Y Imamura
The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren
Volatile organic compounds (VOC) measured during drying of impregnated timber
2004 - IRG/WP 04-50216
Discussion about drying of impregnated timber has taken place in the Nordic countries under eighties and nineties and goes on nowadays. The drying increase the value of production and the customer gets fewer problems when handles the timber. This introduces a positive attitude to the impregnation as a process and its products. Beside the important information about the advantages of impregnated ti...
N Terziev, V Djokic
Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe
Effect of boron compounds-furfuryl alcohol treatment of wood on dimensional stability, termite resistance and boron leachability
2001 - IRG/WP 01-40195
Sapwood blocks of Japanese cedar (Cryptomeria japonica) and Caribbean pitch pine (Pinus caribaea) measuring 20 (tangential) x 20 (radial) x 10 (longitudinal) mm were impregnated with furfuryl alcohol (FFA) by a vacuum-diffusion process followed by curing under heating. Boron compounds (boric acid, ammonium borate and ammonium biborate) were mixed in the impregnation solution of FFA. Anti- swelling...
S K Ozaki, M K Yalinkilic, Y Imamura, M F Souza
Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz
Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski
Extracellular hydrogen peroxide producing and hydrogen peroxide reducing compounds of wood decay fungi
1991 - IRG/WP 1516
Extracellular H2O2-producing and H2O2-reducing compounds were isolated from wood-containing cultures of all the white-rot and brown-rot fungi and Ascomycetes which well degraded wood, but were not detected in the culture of the fungi which degraded little wood. The compounds are glycopeptides with a low molecular weight, require H2O2 for one-electron oxidation, catalyze the redox reaction between ...
A Enoki, G Fuse, H Tanaka
Giftwirkung einiger organischer Zinn-Verbindungen auf Eilarven von Hylotrupes bajulus (L.). [Toxic efficacy of some organic tin compounds against egg larvae of Hylotrupes bajulus (L.)]
1978 - IRG/WP 2120
The toxic values of 12 organic tin compounds towards newly hatched larvae of Hylotrupes bajulus were determined after 4- and 12-week test periods in comparison with bis-tri-n-butyltin oxide (TBTO). Tri-n-butyltin benzoate as well as the 2-, 3- and 4-methyl benzoate of tributyltin oxide were equally effective as TBTO and the latter two were somewhat more effective after a 12-week test period. Almos...
G Becker
Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis
Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski
Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura
Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick
Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman
Assessment of the Inhibition of wood decay fungi by volatile organic compounds identified from Trichoderma spp.
1999 - IRG/WP 99-10302
Previous research identified five volatile organic compounds produced by Trichoderma spp. that may be inhibitory to wood decay fungi. The effects of four of these volatile organic compounds, 2-propanone, 2-methyl-1-butanol, heptanal and octanal were tested over a range of concentrations against four selected wood decay fungi. The fungi were incubated in malt extract broth under appropriate conditi...
S N Humphris, R E Wheatley, A Bruce, C Payne