Your search resulted in 43 documents. Displaying 25 entries per page.
A case study on quality control on telephone poles as a cost saving tool in Tanzania
1987 - IRG/WP 3418
A sample of 28 CCA treated Eucalyptus poles from a lot of 2,000 poles awaiting delivery to the field, was studied to reveal the quality of treatment. Results showed a product of very poor quality. Average figures for penetration and retention were 8.4 mm and 2.2 kg/m³; these results are 66% and 91% below the required standards, respectively. Consequences of such results are estimated to amount to losses of billion of shillings.
K K Murira
Wood extractive concentration and sem examination of pretreated southern yellow pine wood chips with blue-stain fungi for mushroom production
2001 - IRG/WP 01-10407
Mushroom-producing white-rotting basidiomycetes either do not colonize or else colonize very poorly on freshly prepared southern yellow pine wood chips. This study evaluates the resinous extractive content of southern yellow pine before and after treatment with colorless mutant blue-stain fungi. The blue-stain fungi penetrate into the sapwood of southern yellow pine and utilize nonstructural resinous extractives, simultaneously reducing the total resinous extractive content. Scanning electron microscopic examination showed that heavy mycelial growth with good sporulation occurred on the surface of wood chips within 2 days and in parenchyma cells within 6 days. Ophiostoma spp. removed 61.1% to 99.9% of the extractives from the southern yellow pine wood within a period of 4 to 5 days. We conclude that white-rot basidiomycetes can easily colonize and produce fruiting bodies on treated southern yellow pine wood wastes.
S C Croan, J Haight
Treating Eucalyptus tereticornis wood with boron: Optimizing treatment conditions
2005 - IRG/WP 05-40309
Even though Eucalyptus tereticornis wood is suitable for small timber purposes, being non-durable, it needs to be treated with preservative chemicals. As it is a heavy, hard and difficult to treat species, the possibility of using diffusible boron compounds was investigated. The present study explored the effect of impregnation conditions such as treatment schedule, concentration of treatment solution and the moisture content of wood on the achievement of desired dry salt retention (DSR) of the preservative in the treated wood by conducting a commercial scale trial. The study revealed that wood density and moisture content adversely affected the boron impregnation. It was clear that even E. tereticornis wood in green condition could be effectively boron impregnated using appropriate treatment schedule. Only long duration treatment schedules were found to yield the desired DSR levels. A solution concentration of 8% boric acid equivalent (BAE) was found to be required. Application of an initial vacuum of 760 mm Hg (- 85 kPa) for 15 minutes followed by a pressure of 1300 kPa for a minimum period of 60 minutes and a final vacuum of 760 mm Hg(- 85 kPa) for 5 minutes was found to be an appropriate treatment schedule.
T K Dhamodaran, R Gnanaharan
The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures.
CCA fixation experiments. Part 1
1989 - IRG/WP 3504
A method of squeezing solution from CCA treated wood that has not been dried at various times after treatment appears to be useful in following the fixation of CCA in wood. Experiments confirm that temperature governs the rate of fixation.
W S McNamara
Investigation of the fixation in wood of chromated zinc chloride and copperised chromated zinc chloride preservatives
1976 - IRG/WP 372
A biological method of evaluating the extent to which CZC and CCZC preparations are retained in wood in terms of the potential protection which they afford against destruction by Merulius lacrymans (dry rot) is given. CCZC is recommended for protection of wood under moderate leaching conditions, while the use of CZC under such conditions is not recommended.
V N Sozonova, D A Belenkov
Health hazards and environmental aspects when using Cu-HDO-containing wood preservatives in vacuum pressure plants
1993 - IRG/WP 93-50001-11
Apart from the biological efficacy of wood preservatives, the health and environmental aspects concerning the utilisation of wood preservatives, the use of treated timber and the disposal of impregnated wood are of high significance today. Therefore, information on a possible aerial concentration of wood preservatives, on the mobility of active substances in soil leached from treated timber in service and on the composition and toxicity of thermal decomposition gases releasing on combustion of impregnated wood, are of absolutely fundamental interest. Measuring procedures relevant for the practical application will be presented, and the results concerning the utilisation of Cu-HDO-containing wood preservatives will be described. With the proper use of Cu-HDO-containing wood preservatives, the aerial concentration at workplace falls distinctly below the maximum permissible limit. If vacuum pressure treated timber is used properly, no active substances will seep into the ground water as a result of the leaching process of impregnated wood in service. The composition measured and the acute toxicity of the thermal decomposition gases released on combustion of impregnated wood may axtually be compared to those of untreated timber.
W Hettler, S Breyne, M Maier
Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are reported. Temperature and concentration appear to have an equally important effect on the preservative chemicals retentions and distribution in timber. pH, has also an effect but somewhat less marked than temperature and concentration, with the exception of the formation of sludges. Multivariable regression equations describing the amounts of Cu, Cr and As fixed on lignin and holocellulose for both pine and eucalyptus are also presented. The timber species treated also appears to have an important influence on the amounts of chemicals fixed and their distribution. Eucalyptus appears to be much less tolerant than pine to extremes of treating conditions. The influence of treating time under the most common treating conditions is also briefly discussed.
A Pizzi, W E Conradie, A Jansen
The influence of gaseous oxygen concentration on fungal growth rates, biomass production and wood decay
1998 - IRG/WP 98-10283
The effects of air and several levels of oxygen balanced with nitrogen (% oxygen (v/v) nitrogen to 100%) on growth rates, biomass production and wood decay were investigated. The best technique for measuring daily growth rates in anaerobic jars was found to be by using 40 mm petri dishes which were attached to the walls of the jars. At the end of the test period the same petri dishes were also used for determining the dry weight of the fungal mycelia. The results showed that 5% oxygen concentration was very favourable for white rot and brown rot fungi (Basidiomycetes). When oxygen levels were reduced from 1% to 0.01%, the growth rates and dry weight of these fungi were steadily decreased. On the other hand, there was a large difference between very low oxygen levels (0.01 to 1%) and other levels (5 to 21% 02). In the case of other fungi there was not a big difference on their growth rates and biomass. Observational and numerical results on Fagus sylvatica (beech) and Pinus sylvestris (Scots pine) degradation by Coriolus versicolor, Coniophora puteana and Chaetomium globosum showed that there was a large difference in the degradation of the wood samples caused by C. puteana and C. versicolor when exposed to air and other levels of oxygen (0.25,1, 5 and 10% 02). Weight losses obtained by C. globosum as a soft rot on timber specimens in air and other oxygen levels were all in same range and below 5%. On the other hand there was a safety point at 5% 02 below which the fungus was unable to degrade beech. This point was 10% 02 for scots pine. At these points, weight losses were under 5%.
S M Kazemi, D J Dickinson, R J Murphy
Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial pH of the CCA solution and (iii) its concentration. Variation in the values of these three parameters cause drastic differences in the distribution between lignin and holocellulose of the preservative chemicals which will considerably affect the durability of CCA-treated timber. New, more economical and more effective application schedules and CCA formulations both in chemical composition and requiring lower retentions (softwoods) and imparting equal or superior durability to the treated timber can be devised from the results presented. From the results it appears that CCA formulations producing better soft-rot resistant hardwoods can be devised and the changes necessary to obtain this, are outlined.
Environmental risk assessment of treated timber in service: The Environment Focus Group approach
2000 - IRG/WP 00-50162
In the context of the Biocidal Products Directive (98/8/EC), and of the OECD work on wood preservatives, the Environment Focus Group (EFG), comprising 8 institutes and the European Wood Preservative Manufacturers Group, has been working on the environmental risk assessment of treated timber in service. A literature review of emissions from treated timber has revealed that very little existing data is usable for environmental risk assessment; the most relevant data are kinetic curves of emissions over time, which show clearly the non-linear emissions behaviour of treated wood over time. The EFG has suggested real exposure conditions for treated timber in the environment, and listed typical exposure scenarios. Five representative scenarios are characterised in detail, for use in the calculation of Predicted Environmental Concentrations (PECs). The existing methods to determine emissions from treated wood have been reviewed. Most existing experimental models cannot be used to predict environmental emissions. Monitoring of commodities in service has its specific constraints. Chemical analysis and ecotoxicity testing have also been reviewed and their relationship has been discussed. Principles for the design of experimental models, for the determination of emission fluxes from treated wood to the environment, have been established.
G Deroubaix, G Labat, I Le Bayon, S Legay, P Marchal, C Yrieix, E Melcher, R-D Peek, S De Geyter, J Van Acker, W J Homan, D J Dickinson, R J Murphy, E D Suttie, A J Nurmi, A-C Ritschkoff, D Rudolph, I Stephan, D Aston, E F Baines, J B Simonin
A comparison of inductively coupled plasma spectroscopy and neutron activity analysis for the determination of concentrations in wood
1993 - IRG/WP 93-10048
As wood decays the ionic composition changes, with increases often being seen in the concentrations of Ca, Mg, Fe, Mn and sometimes K. The concentration of eight cations in red spruce sapwood and heartwood samples was determined independently by inductively coupled plasma spectroscopy (ICP) and by neutron activation analysis (NAA) as part of an effort to standardize our analytical procedures and create a uniform wood standard for use by multiple researchers. Preliminary studies indicate a difference in the values of Ca and K as estimated by ICP and NAA, possibly due to a loss of these elements due to volatilization during ashing.
J Jellison, J Connolly, K C Smith, W T Shortle
Influence of concentration, catalyst, and temperature on dimensional stability of DMDHEU modified scots pine
1998 - IRG/WP 98-40119
Dimethyloldihydroxyethyleneurea (DMDHEU) is being used in textile industry to improve wrinkle recovery. Trials on solid wood have been performed to minimise swelling of the wood. This paper focuses on the effect of various types and concentrations of catalyst and reaction temperature on the dimensional stability of Scots pine. Three different catalysts, NKS (based on magnesium chloride), 3282 (based on aluminium chloride) and citric acid have been tried separately or in combination with tartaric acid. Reaction temperatures between 100° and 125°C have been investigated. The results showed that an anti shrink efficiency of up to 50% can be obtained.
M Van der Zee, E P J Beckers, H Militz
Occupant re-entry times following insecticidal remedial treatments of timber in dwellings
1995 - IRG/WP 95-50055
This work was carried out principally to obtain quantitative data on the aerial concentrations of permethrin and white spirit likely to arise following the remedial treatment of timber in buildings, using insecticidal formulations. Such data are needed to allow assessments to be made of the length of time buildings should remain unoccupied following such treatments prior to re-occupation, and the likely levels of exposure of the occupants to the treatment products concerned. Two large, free-standing, wood-lined chambers were treated (in separate experiments) with a dilute oil-in-water emulsion and a micro-emulsion, both containing 0.2% m/m permethrin. The atmospheres in the chambers were sampled at intervals and analysed for their permethrin content. In addition, the aerial concentrations of white spirit were determined following treatment with the dilute oil-in-water emulsion. Results indicated that the aerial concentrations of permethrin following treatment never exceeded 20 µg/m³. Comparison of the measured levels with the threshold limit value (TLV) for permethrin (modified to a TLV/40 to represent the value associated with 24 hours-a-day continuous occupancy) indicated that such levels of permethrin constituted no significant risk to occupants. Aerial concentrations of white spirit in the test chambers from the dilute oil-in-water emulsion product indicated by calculation that the TLV/40 of this solvent would be attained approximately 10 hours after treatment in a model domestic situation having the relatively low air exchange rates of the test chambers. This work has shown the importance of further studies needed to identify the rate determining step in the evaporation of deposited constituents from the surface of timber and to quantify the effect of different air exchange rates in treated premises on the aerial levels of formulation constituents.
R J Orsler, G E Holland, G M F Van Eetvelde
The suitability of high pressure sap-displacement for the retention of UK grown spruce and pine
1990 - IRG/WP 3595
The concentration and radial distribution of copper, chrome, arsenic (CCA), and the moisture content and depth of radial checking in UK grown, field exposed spruce and pine poles treated by high pressure sap-displacement are examined. The concentration of CCA elements in samples obtained from increment cores is similar in Norway spruce, Scots pine and Corsican pine but is significantly lower in Sitka spruce. The concentration of chromium in all species, arsenic in Sitka spruce, Norway spruce and Corsican pine and copper in Sitka spruce are at a maximum in the outer sapwood and decrease centripetally with increasing core depth. In contrast, arsenic in Scots pine and Norway spruce at groundline and copper in Norway spruce, Scots pine and Corsican pine are at a maximum in the inner sapwood. The slopes of metal concentration against radial core depth are similar in Norway spruce and Scots pine but are significantly larger (steeper) and smaller (less steep) respectively in Sitka spruce and Corsican pine. Checking is more severe in Sitka spruce than in the other species and appears to be associated with steep moisture gradients. In Sitka spruce, checks penetrate the preservative treated annulus thus greatly facilitating decay since micro-organisms have access to untreated non durable wood. The results suggest that high pressure sap-displacement is suitable for the treatment and long term protection of Norway spruce, Scots pine, and Corsican pine but is inadequate for the protection of Sitka spruce. Modifications to the high pressure sap-displacement process that could improve the treatment of Sitka spruce are discussed.
P D Evans, S D Hainey, A Bruce, G M Smith, B King
Effect of climate, species, preservative concentration and water repellent on leaching from CCA-treated lumber exposed above ground
2001 - IRG/WP 01-50178
Few studies have examined leaching of chromated copper arsenate (CCA) from treated wood in above ground exposures due to the assumption that leaching is less severe compared to wood in continuous contact with soil or water. However, a significant portion of CCA treated wood is used for above ground applications, exposing considerable volumes of the preservative to precipitation and potential leaching. This paper presents preliminary results of a one-year study that continuously monitors CCA leaching from above ground, naturally exposed 5.08 cm x 15.24 cm (2 x 6 inch) dimensional lumber. Three wood species, southern yellow pine (Pinus spp.), jack pine (Pinus banksiana Lamb.), and black spruce (Picea mariana (Mill.) B.S.P.), along with two preservative concentrations and one commercial water-repellent are evaluated for their effect on leaching rates. Preliminary leaching results indicate significant differences between wood species, treating solution concentrations, and the use of water repellent. In addition it appears that climatic variables affect elemental leaching of copper, chromium and arsenic differently. However, the exact effects of climatic variables are inconclusive at this time. Upon completion, this study will offer a substantial amount of leaching data to validate the findings of previous leaching tests, and provide insight into the leaching mechanism of CCA-treated lumber in above ground exposures.
J L Taylor, P A Cooper
The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform segments. Afterwards each segment was milled and mixed to guarantee a nearly homogenous sample. After further sample preparation like an acidic digestion the remaining concentration of the inorganic components copper, zinc, boron and fluoride were measured by means of AAS, ICP and an ion selective electrode. Concerning the remaining concentration the following ranking of the investigated active ingredients could be deduced: Cr (90%)> Zn (60%)> Cu (40-70%) >= F (40%) > B (concentration <10%). Furthermore the results show that the remaining content of copper differs depending on the wood preservative used. The lowest content was detected for the CCZnF-formulation, the highest for the copper-quat-preservative. Furthermore it is obvious that the rate of biological decay correspond well with the distribution of the wood preservative components in the segments.
E Melcher, H-W Wegen
Standardization of preservative treated timber species for conductor, insulator and transformer packing of REB
1996 - IRG/WP 96-40071
In order to resolve the post landing failure problem of wooden packing for conductor, insulator, transformer of REB, the names of the suitable timber species from different parts of the world, irrespective of countries of origin have been standardized along with their strength and treatability grades. The CCA treatability of some Pakistani timber species have been presented for example which was treated at high impregnation pressure with low moisture (12% MC) and low concentration (1.5% W/V) of CCA-C (chromated copper arsenate type-c, oxides) and was analyzed spectroscopically for finding out the dry oxide retentions (W/V & W/W%) of individual components of CCA-C as well as chemical balance.
A K Lahiry
Chitosan for wood protection - state of the art
2005 - IRG/WP 05-30378
The aim of this paper was to give a state of the art description of chitosan as a wood protecting agent. Chitosan is a metal free natural compound derived from crustacean shells and is under evaluation as an environmentally benign wood protecting agent. Information from journals states that chitosan may act both fungistatically and at higher concentrations, as fungitoxic, but the mode of action is not yet fully understood. The hypothesis with most support in the literature is that chitosan interacts with the cell membrane and causes alterations in permeability. It is not proven that chitosan is more effective against a particular class of fungi, but morphological changes and reduction in growth rate is reported from a range of fungi. Results from agar plate growth rate tests are not conclusive with respect to whether high or low molecular weights are most effective against micro-organisms. Other factors than the molecular weights may influence microbial activity of the species studied, i.e. FA, pH, and internal distribution of the monomers, concentration and additives. In results available in the literature it is obvious that there is a dose-response relationship between chitosan and antimicrobial activity. In agar plates a lethal/totally inhibiting concentration is usually between 0.1 and 1 %. Chitosans in solution are more effective against antimicrobial growth than chitosans in suspension (i.e. solid chitosan particles). This is further reflected in that higher concentrations of chitosan are needed in wood than in agar amended plates. If the treated wood is subjected to leaching, around 5 % (w/v) chitosan solutions seems to be needed for good efficacy against fungal decay. Some tests where chitosan fails in decay tests are probably because of the use of to low concentrations, or to low penetration of chitosan solution due to high molecular weight.
M Eikenes, G Alfredsen, E Larnøy, H Militz, B Kreber, C Chittenden
Site characteristics impacting historic waterlogged wood: A review
2000 - IRG/WP 00-10344
Survival of waterlogged wood from hundreds and in rare cases millions of years presents scientists with a unique opportunity to examine wood specimens which, due to select properties of the wood itself and/or the depostional environment, have not been completely degraded. Although degradation patterns of various types of microbial wood decay have been studied in detail, the site parameters of the zone from which the wood was removed has not been systematically characterized and correlated to the specific types and cause of degradation. Studies have been conducted attempting to relate factors such as hydrogen-ion concentration (pH), redox potential (Eh), oxygen (O2) concentration, and chemical end-member concentration to specific environments, but there has been no unification of testing methodology. This paper proposes to review the literature concerning site characteristics that impact the biodegradation of historic submerged wood, and discuss the implication of such research to future needs for further advancement of the science.
B A Jordan, E L Schmidt
Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previous research has suggested that the degree of copper fixation may be influenced by the amine-copper formulation (including the type of amine), the copper concentration and the ratio of the amine to copper in the treating solution. However, the relationship between amine and copper concentration and the fixation efficiency is not fully understood. The purpose of this study is to determine the influence of a) the type of amine, b) the concentration of copper, and c) the amine to copper mole ratio, on the fixation chemistry of amine-copper preservatives.
N Lucas, J N R Ruddick
Simulation test of subchronic inhalation toxicity of TBTO vapours in the air
1987 - IRG/WP 3454
The test was carried out in a wainscotted room of a normal size. Wooden panelling had been treated with one coat of basic preserving agent and, after the installation, with 2 coats of stain. Laboratory animals (rats) were kept in this room for 90 days. For the same period a control group of test animals was kept in a room of equal size where there was no panelling. During the test, concentration of tin (Sn) in the air (originating from TBTO) was measured and the weight of the animals was taken. When the test was completed, typical characteristics of animal tissue likely to be affected by TBTO, were determined. Throughout the test, the quantity of Sn in 1 m³ of air had been approx. 1 µg. No changes i.e. differences in typical parameters of both the test and control animals have been observed (histological tests have not been made yet).
V Skubic, S Kobal, J Stupar, R Ajlec, J Korošin, G R Pecenko
Mould growth at lumber surfaces of pine after kiln and air drying
1994 - IRG/WP 94-40033
Distribution of water soluble substances in green wood and later redistribution during drying is of importance for the colonisation of wood by microorganisms. According to literature the availability of nitrogenous materials is probably a major limiting factor to the microbial colonisation of wood. King et al. (1974) and Oxley et al. (1976) have shown correlation between surface nutrient concentration and the degree of invasion by soft rot fungi. Although the effects of some factors on the susceptibility of wood to mould have been studied (Land 1986, Hallenberg and Gilert 1987, Bjurman 1989a, b), the effect of the drying treatment was not considered. In the study by Theander et al. (1993) it has been indicated that the growth of the mould fungi Penicillium brevicompactum and Aspergillus versicolor is positively correlated with the content of nitrogen and low-molecular carbohydrates. Kiln and air drying cause redistribution of the soluble sugars and nitrogen in different ways and the effect of kiln drying varies depending on the drying schedule (Terziev et al. 1993, Terziev 1994). The major goal of the present study was to investigate whether different drying treatments of wood (causing different redistribution of low-molecular sugars and nitrogen) create different susceptibility for mould growth. The material for the moulding tests was from the above mentioned studies of Terziev et al. (1993) and Terziev (1994). Thus, drying history and contents of soluble sugars and nitrogen were known for the test material. No data were found in the literature about mould growth after different drying treatments. The present experiment is to be considered as a preliminary study.
N Terziev, J Bjurman, J B Boutelje
Moderate temperature fixation of CCA-C
1989 - IRG/WP 3522
Several Canadian treating plants are using moderate temperature (40-60C°) fixation chambers to reduce drippage and leaching from fresh CCA treated wood. In this study, chromium reduction and surface leaching properties of CCA-C treated red pine (Pinus resinosa) pole sections were monitored during exposure to temperatures of 50-60C° and 90-100% RH conditions. Chromium-VI concentration in the absorbed treating solution dropped significantly during the treating cycle to 50-60% of that in the free treating solution. The chromium-VI concentration also dropped with increasing depth in the pole. During the six to 24 hour fixation cycle the Cr-VI concentration dropped steadily especially in the outer layers of the pole, but even after 6 hours, a significant amount of Cr-VI was observed at all measured depths. After 12 hours, Cr-VI was only barely detectable at all depths. The leachate analyses were consistent with the Cr-VI results, indicating reduced but still significant surface losses while Cr-VI could still be detected.
P A Cooper, Y T Ung
Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a higher percentage of copper fixed with lower retention treatments. Increasing the temperature of the treated wood from 22°C to 50°C reduced the stabilization time by up to ten times depending on the ACQ retention and the wood species. There was little species effect for low extractive content red pine (Pinus resinosa), jack pine (Pinus banksiana), white spruce (Picea glauca), balsam fir (Abies balsamea) and trembling aspen (Populus tremuloides). Neither was there a significant difference in the stabilization rates of jack pine sapwood and heartwood. However, Douglas-fir (Pseudotsuga menziesii) stabilized at a greater rate and to a higher degree than the other species with heartwood reacting faster and more completely than sapwood. This is likely attributed to the high reactivity of copper at high pH with phenolic extractives in Douglas-fir.
Y T Ung, P A Cooper