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Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


Acceleration of the fixation of chromated wood preservatives by UV-radiation
1989 - IRG/WP 3544
Preliminary laboratory tests demonstrated that the fixation of chromated water-borne wood preservatives may be accelerated by UV-radiation. The degree of fixation depends on the intensity of radiation and the prevailing temperature. Three hours radiation at 20°C in a device for artificial weathering diminished the leaching of chromium to 43% and of copper to 23% compared to not-radiated samples. ...
H M Illner, H Willeitner, K Brandt


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Leaching Characteristics of Copper in Copper Treated Wood
2003 - IRG/WP 03-30316
The leaching characteristics of copper in copper treated bamboo and other wood species such as slash pine and poplar has been conducted in this paper according to AWPA M11-87 standard, the result indicates that: --Copper fixation rate of salts from organic acids such as citrate and oxalate and malate is less than other non-organic acid formulations. --Copper fixation rate of oven-dried bamboo sa...
Mingliang Jiang, Junliang Liu, Daochun Qin, Yamei Wang, Zehui Jiang


Determination of fixation properties by bioassays - A proposal for the assessment of safety indexes in wood protection
1990 - IRG/WP 3566
In the determination of environmental effects of chemicals tests with fishes, daphnia and algae have proved to be practicable. With respect to wood protection such bioassays are suitable to control effects of treated timber against aquatic organisms. By using the fish-acute-toxicity-test the development of a laboratory test method is described for the checking of the fixation rate of a copper-chro...
H-W Wegen


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi


Environmental situation on wood preservation industries in Bangladesh
2000 - IRG/WP 00-50148
The hazard that wood preservative chemicals pose to people and the environment is serious. The lack of information, legislation and awareness create an unfavorable situation on wood preservation industries. In this regard, three wood preservation industries have been visited to collect the information about pollution. It was observed that different steps have been taken to minimize the contaminati...
K Akhter


Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz


Proposal for further work on fixation of CCA-preservatives in wood
1988 - IRG/WP 3493
Many studies on the fixation and fixation-mechanism of CCA-preservatives in lignocellulose materials have been published but few on the practical consequences of this knowledge. For the wood preserving industry and the user of treated wood it is important to know what is meant by the word fixation, when fixation is complete and how fixation can be recorded in an easy way according to a non-destruc...
M-L Edlund


CCA modifications and their effect on soft rot in hardwoods. Part 2
1983 - IRG/WP 3244
The work outlined in this document is a continuation of that presented in Document No: IRG/WP/3201. The findings described in the previous paper are summarised below: a double treatment of CCB followed by arsenic (CCB+A) is more effective than a double treatment of boron followed by CCA (B+CCA) or a single treatment of CCA, CCB or CCAB in controlling soft-rot due to Chaetomium globosum in birch. C...
S M Gray, D J Dickinson


Fixation and leaching of selected Malaysian tropical hardwood after treated with CCA
2001 - IRG/WP 01-40207
The objective of this study is to investigate the fixation and leaching properties of selected Malaysian tropical hardwood (sentang wood (sapwood and heartwood) and rubberwood) after being treated with copper chrome arsenate (CCA) type-C preservative. The samples were treated with retention level of 0.5%, 2.0% and 5.0%. The samples were leached and the leachate were analyzed by AAS and the amount ...
R Hashim, O Sulaiman, Tan Siew Ching, K Yamamoto


Effectiveness of CCA fixation to avoid hexavalent chromium leaching
2002 - IRG/WP 02-50187
It is generally assumed that hexavalent chromium in chromated copper arsenate wood preservative is substantially reduced to trivalent chromium during fixation and that the potential to leach the more toxic CrVI is minimal. However, there are occasional claims some hexavalent chromium remains in wood after fixation and that small amounts of CrVI are available for leaching. One problem is that ot...
P A Cooper, D Jeremic, Y T Ung


Microbial breakdown mechanisms. Mini-Symposium at the 18th IRG meeting, Honey Harbour, Ontario, Canada
1987 - IRG/WP 1327
An understanding of how micro-organisms cause chemical alternation to wood is essential for effective wood preservation. Investigation of the Microbial Breakdown of wood is a very dynamic research field and is increasing in importance as several biocides are being examined as alternativesw to classic wood preservatives. These biocides often do not possess broad spectrum activity. It is esential th...
L E Leightley


A suggestion for the improvement of the chemical protection of wooden poles
1987 - IRG/WP 3445
Insufficient drying of white poles in Sweden causes inadequate penetration of the impregnation compounds, CCA salts and creosote, in a varying proportion of the treated poles, and with pretreatment decay present, sooner or later, internal fungal attack in the ground-line zone of the standing poles is the result. The application of a diffusing fungicide in the ground-line zone in connection with th...
H Friis-Hansen


The multi-phase pressure (MPP) process. One stage CCA treatment and accelerated fixation process - Concepts proved by repetitive pilot plant treatments
1997 - IRG/WP 97-40079
Twenty-four charges of radiate pine roundwood or sawn timber were treated using the MPP Process and hot CCA solution. Treated timber met the CCA retention and penetration requirements of the NZ Timber Preservation Council for Hazard Classes H3 to H5. The objectives of the trials were: (1) To "stress" CCA solution by repetitive heating, treating and cooling to determine its stability in the process...
A J Pendlebury, J A Drysdale, K Nasheri, H Pearson, M E Hedley


Investigation of temperature effect on fixation of Celcure preservative (ACC) in beech (Fagus orientalis)
2001 - IRG/WP 01-40200
In this research, the fixation speed of Celcure 2% (ACC) preservative salt, under temperature of 17°C, 27°C and 50°C, on intact and stained wood specimens of beech was investigated. For this purpose, blocks of wood with 5x5x7 cm dimensions were prepared and saturated with 2% ACC concentration by full-cell process. The specimens were put in three incubators at the above-mentioned temperatures. F...
A Karimi, M Ghorbani


Délavabilité de bois ronds traités avec un sel CCA dans des conditions réelles de stockage. Incidence pratique de la fixation accélérée par étuvage. Impact effectif sur l'environnement
1993 - IRG/WP 93-50001-23
Un essai de terrain a été organisé pour mesurer concrètement, dans des conditions aussi proches que possibles des conditions réelles de terrain, les pertes effectives en produit de traitement lorsque le bois traité est soumis à des intempéries. L'essai a été conduit sur des bois ronds (poteaux), traités en autoclave par procédé Bethell avec un sel CCA de type C, avec comme fi...
M Rayzal, F Larroze


Preliminary studies of the decay mechanism of some brown-rot fungi
1989 - IRG/WP 1402
The importance of the enzymatic degradation of hemicellulose and cellulose by brown-rot fungi is still under discussion. Endo-ß-1,4-xylanase and endoglucanase activities of Coniophora puteana and Poria placenta cultures were measured by the increase in reducing groups. Enzymes were produced in liquid and solid sawdust based culture media. Enzyme activities were measured in two, four and eight wee...
A-C Ritschkoff, H Viitanen


Comparative study on leaching of CCA from treated timber: Modelling of emission data
1994 - IRG/WP 94-50027
Results of a comparative study on leaching of CCA from treated timber are reported. The study aims at investigating the applicability of prestandard leaching test methods for modelling purposes. Prestandards used are the European standard proposed by CEN/TC38/WG11 and NEN 7345 (Dutch prestandard for building materials). Parameters of study are type of fixation, wood species (pine - spruce), specim...
G M F Van Eetvelde, M Stevens, L Van der Mijnsbrugge


Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm


The environment and the timber preservation in the Benelux countries
1990 - IRG/WP 3580
The environment has become a major issue in all industries. To focus on the timber preservation industry an analysis is made of the production chain. Suggestions are made for diminishing or excluding emissions of agents of pollution. After a review of the legislation in Holland, some important statements are made on the production process, the products involved and the waste materials. Finally raw...
C De Mey, R Leegwater


Creosote for wood preservation
1971 - IRG/WP 36
By creosote one usually means coal tar creosote, although there are creosotes of other origin. For example, wood tar creosote is a product of wood distillation. It is, in fact, in this connection that the word 'creosote' was first used. Early in the nineteenth century the oily product obtained by distilling wood was said to have an odour which resembled 'smoked meat&...
Anonymous


Biochemical aspects of white-rot and brown-rot decay
1987 - IRG/WP 1319
This paper presents an overview of the decomposition of wood by white- and brown-rot fungi - the most important and potent of known wood-decay fungi. These organisms are unique among cellulose destroyers because of their strong capability to enzymatically degrade lignified material. Special emphasis is given to the following aspects of wood decomposition by white- and brown-rot fungi: (1) effects...
T L Highley


Effects of fixation conditions and seawater on leaching of wood treated with marine retention CCA
1997 - IRG/WP 97-50088
The effect of post-treatment conditioning temperature and humidity on leaching of chromated copper arsenate (CCA) was compared in seawater and deionized water. Southern pine cubes treated to 40 kg/m3 CCA were stored at 2° C and 82% relative humidity (RH), 24° C and 65% RH, or 32° C and 30% RH for 3, 10, or 17 days. Cubes were then leached in deionized water or artificial seawater. The rate of l...
S T Lebow


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