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Health aspects concerning the use of bifluorides in wood
1981 - IRG/WP 3173
An attempt has been made to find a correlation between the quantities F¯ and HF present among other ions in an 'Improsol' solution consisting of NH4F.HF and KF.HF, the quantity absorbed by the wood from this after immersion and the toxicological effects of this treated wood when it is used in rooms destined for the residence of people or animals or for the storage of foodstuffs....
H F M Nijman


The use of bifluorides-diffusion in remedial treatments
1983 - IRG/WP 3256
A description is given about the experience to date of a 14 years' development to bring bifluorides-diffusion from laboratory evaluation to commercial service application. The described treatment is an adjunct to good design and not a replacement for it. The process is also used with an injection method for the remedial treatment of premature decayed external joinery....
H F M Nijman


Diffusion of bifluorides and borates from preservative rods in laminated beams
1991 - IRG/WP 3644
Laminated beams from spruce, pine and larch were treated with two preservative rods, based on bifluorides and octaborate respectively. After 3 and 6 months placed in different climates (65% r.h., 100% r.h., water) the diffusion of the active ingredient was measured. After the 6 months period, the diffusion of the bifluorides was, in all species, ca. 5 times larger than the diffusion from octaborat...
H Militz


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Risk of pulmonary damage as a result of an evaporation of ca. 50 ppb = 42 mg HF, evaporated from wood treated by difluorides
1987 - IRG/WP 3401
In this review of the literature the effects of fluorides and fluorine on man are described, especially the low level effects of inhaled HF on human beings. The term "fluoride" is used as a general term everywhere, where exact differentiation between ionic and moluecular forms or between gaseous and particulate forms is uncertain or unnecessary. The term covers all combined forms of the element, r...
H F M Nijman


Emissions from the combusting of boron and fluoride containing wood
1995 - IRG/WP 95-50040-18
The combustion properties of waste wood and wood residues containing wood preservatives were investigated in several test series after having been blended with untreated wood at a ratio of 1:4. The results for CFB, SF and boric salt show that, provided an optimized combustion, the concentrations of the stack pollutants correspond approximately with those found for untreated wood. Only during the c...
T Salthammer, H Klipp, R-D Peek


Formation of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) during the combustion of impregnated wood
1995 - IRG/WP 95-50040-19
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) a...
T Salthammer, H Klipp, R-D Peek


Insect resistance of preservative treated tropical plywood against Lyctus
1990 - IRG/WP 1453
Seven plywood types composed of tropical wood species, vulnerable to Lyctus, were treated with various commercial water-borne and oil-borne preservatives. A wide range of preservative retentions was obtained by treating boards with dip treatment, steeping, double-vacuum and vacuum-pressure impregnations. Selected samples were subsequently tested for their insect resistance against Lyctus africanus...
J Van Acker, M Stevens, M Pallaske


The influence of crystalline and amorphous cellulose on extracellular hydrogen peroxide production by brown-rot fungi
1991 - IRG/WP 1482
The production of hydrogen peroxide (H2O2) has been suggested to play a key role in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by a quantitative method which detects the oxidation of the 2,2-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horseradish peroxidase (HRP) in liquid culture medium. The carbon sources u...
A-C Ritschkoff, L Viikari


Cytochemical localization of hydrogen peroxide in brown rot fungus Tyromyces palustris by cerium chloride technique
1999 - IRG/WP 99-10299
Cerium chloride (CeCl3) was used to localize H2O2 cytochemically for studying relationship between ultrastructural and functional characteristics of cellulose degradation by brown rot fungi. This technique proved very useful in localizing discrete electron-densereactionproducts at high resolution with minimal nonspecific deposition. The cytochemical localization of extracellular H2O2 by CeCl3 usin...
Yoon Soo Kim, Seung-Gon Wi


Preliminary results of investigations on screening test of chemical compounds suitable for the preservation of lignocellulosic materials against biodeterioration
1976 - IRG/WP 262
This paper investigates the possibilities of reducing the time needed for the determination of the effectiveness of chemical compounds from the point of view of their eventual application to lignocellulosic materials for preservation against decay and soft-rot....
K Lutomski, S S Neyman


Studies on the infestation behaviour of the powder-post beetle Lyctus brunneus (Steph.) and its physical control in the wood yards of the Caspian forests of Iran
1985 - IRG/WP 1271
Lyctus brunneus (Steph.) is a pest which has not been previously thoroughly studied in Iran. It severely attacks Iranian hardwoods, especially those used in wooden houses and that have not been treated. Research work was necessary to determine the natural resistance of the most important timber species in Iran against this insect....
P Niloufari


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


The 1999-2000 annual report for the IRG - Wood Preservation in Egypt
2000 - IRG/WP 00-40188
The wood destroying insects in Egypt are belonging to several families of Coleoptera, Lepidoptera and Isoptera. Imported woods are treated by The Agricultural Quarantine or the authorized companies. The materials used for protection as pre-treatment are the same of the treatment. They are Bromide methyl, copper or fluoride salts, organo-phosphorus compounds, pyrethroides, creosote or creosodial. A...
S I M Moein


Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell


Involvement of hydrogen peroxide in wood decay by brown-rot and white-rot fungi
1985 - IRG/WP 1256
To gain further understanding of the role of H2O2 in wood degradation by brown- and white-rot fungi, we studied the following: (a) extracellular H2O2 production, (b) effect of various hydroxyl radical (·OH) and singlet O2 (1O2) quenching agents on wood and cellulose degradation, (c) intracellular H2O2 production and catalase activity, and (d) cytochemical localization of H2O2 with diaminobenzidin...
T L Highley, L L Murmanis


Performance if internal remedial treatments to arrest fungal attack in poles and large timbers
2018 - IRG/WP 18-40834
Internal remedial treatments have been used to arrest internal fungal attack in utility poles and other large timbers. Water diffusible systems and volatile fumigants have both been used for this purpose. While both work, it is important to understand the performance attributes of each system. This paper reviews the literature on both systems and makes recommendations for future research....
J J Morrell


Iron in stone wool - one reason for the increased growth and decay capacity of Serpula lacrymans
1992 - IRG/WP 92-1537
The chemical compositions of stone wool and glass wool were analysed. There was more iron in the stone wool than in the glass wool. It was found that iron present in stone wool was easily dissolved by oxalic acid that Serpula lacrymans is able to produce. The stone wool promoted the decay of pine wood by Serpula lacrymans. The glass wool had no effect on the decay capacity of Serpula Iacrymans. Th...
L Paajanen, A-C Ritschkoff


Fluoride woodpill
1987 - IRG/WP 3431
Decay problems of spruce joinery in the Netherlands in the 1960's and 1970's led to the introduction of preservative treatment. Because of the known penetration difficulties with Spruce, the results of the treatments were not always successful. The fact that the decay was found only in the joints led to development of the philosophy of "local preservation" of the joints in remedi...
J W P T Van der Drift, K J M Bonsen


Determination of total fluoride in preservative-treated wood by ion selective electrode, without steam distillation
1996 - IRG/WP 96-20086
An analytical method was developed to determine total fluoride in wood treated with aqueous fluoride or borate-fluoride formulations. Ground wood was mixed with 60% sodium hydroxide solution and oven-dried overnight before furnacing at 600°C. The cool fused product was dissolved in warm water before adding a powerful complexant/buffer solution containing sulphosalicylic acid and EDTA. Fluoride wa...
M J Kennedy


The use of a physical field model to study the effects of remedially treated timber on the growth of perennial ryegrass (Lolium perenne) and rye (Secale cereale), and the accumulation of toxic preservative constituents in Lolium perenne
1995 - IRG/WP 95-50040-02
Low cost laboratory model systems can be used to give relatively rapid indications of the environmental effects of preservative treated timber in soil contact. This paper details the effects of remedially treated timber on the growth of crops of Lolium perenne and Secale cereale seeded on soilbeds of different texture in close proximity to remedially treated creosoted pole sections. Lolium perenne...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Screening of lignin peroxidase from white-rot fungi
1998 - IRG/WP 98-10274
Since lignin peroxidase was first found in the ligninolytic culture of Phanerochaete chrysosporium, it has been regarded as an enzyme responsible for the lignin biodegradation and studied comprehensively. As the results of these studies its unique characteristics have been revealed. On the other hand, the features of lignin peroxidase produced by other white-rot fungi have not been studied so much...
I Momohara


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines


Initial results and observations of a model system to assess the efficacy and environmetal impact of preservative treated wood
1993 - IRG/WP 93-50001-02
The development of a closed model system for the laboratory assessment of the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles has been described (IRG/WP/2395-92). The model consists of a precipitation apparatus above a treated pole section positioned in a soil profile from which leachate was collected via a series of simulated field dra...
D C R Sinclair, G M Smith, A Bruce, H J Staines


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