Your search resulted in 41 documents. Displaying 25 entries per page.
Non-enzymatic Gloeophyllum trabeum decay mechanisms: Further study
2001 - IRG/WP 01-10395
Information will be presented on the mechanisms involved in, and potential application of, non-enzymatic wood decay by brown rot decay fungi. Specifically, the hypothesized role of low molecular weight phenolate derivatives will be discussed in relation to non-enzymatic degradation of wood. The mechanism of binding of iron by cellulose, and binding and reduction of iron by fungal derivatives and m...
B Goodell, J Jellison
Regulation of hyphal sheath formation iron-chelator production by the brown rot fungi Gloeophyllum trabeum and Postia placenta
1994 - IRG/WP 94-10074
Hyphal sheath formation and iron-chelator production by liquid cultures of the brown rot fungi Gloeophyllum trabeum and Postia placenta were monitored over time. The effects of incubation at various temperatures, pH's and concentrations of iron, manganese and nitrogen were determined. Hyphal sheath production was observed microscopically and quantified with JAVA video analysis. The hyphal...
Y Chen, J Jellison
Chelator-Mediated Fenton Chemistry in Wood Degraded by Fungi
2007 - IRG/WP 07-10618
Wood specimens were colonized by individual isolates of brown rot, white rot, soft rot and blue (sap) stain fungi. Ethyl acetate extracts of the ground wood were analyzed for their iron-reducing capabilities using a ferrozine-based assay. Extracts from wood colonized by brown rot fungi showed a significantly greater iron-reducing capability than extracts from wood colonized by white rot fungi or n...
B Goodell, G Daniel, J Jellison, Yuhui Qian
The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison
The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida
Iron promotes decay capacity of Serpula lacrymans
1993 - IRG/WP 93-10008
The influence of iron and iron compounds on the decay capacity of Serpula lacrymans was studied. Mass losses of pine wood caused by dry rot fungus were increased when FeSO4 was added into the culture medium or when there were iron nails or stone wool on the culture medium. This supports the hypothesis that iron in stone-based building materials is one reason for the increased decay capacity of Ser...
L Paajanen
Synergistic effects between 2-HPNO, Irganox 1076 and EDTA on the inhibition of wood degradation by Coriolus versicolor
2004 - IRG/WP 04-30331
The efficiency of 2-hydroxypyridine-N-oxide (2-HPNO) as wood preservative has been investigated. As shown using classical experiments as well as using response surface methodology, the efficiency of 2-HPNO as wood preservative is strongly improved in presence a chelator like EDTA and/or of Irganox 1076 an industrial antioxidant. In these conditions, wood preservative efficiency of the mixture the ...
A Mabicka, S Dumarçay, N Rouhier, M Linder, J P Jacquot, P Gérardin, E Gelhaye
Prevention of brown-rot decay by chelators
1992 - IRG/WP 92-1540
In this work the brown-rot decay was shown to be prevented by chelating the endogenous metals existing in wood by using organic or inorganic chelators or iron-binding siderophores. The fungal growth and decaying ability were significantly decreased by the chelating treatments of the solid wood-based culture medium and pine wood pieces, respectively. The transition metals existing in native wood ar...
L Viikari, A-C Ritschkoff
Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric
Elimination of alternative explanations for the effect of iron on treated wood
1993 - IRG/WP 93-30006
Amounts of iron which had previously been found in stakes removed from ground contact reduced decay of untreated wood by four brown-rot fungi. This suggested that the effect of iron may be on the preservative. Analysis of the leachates from CCA- and ACA-treated wood blocks first exposed to rusting iron, then to a brown-rot fungus, showed that the increased decay found in the laboratory for wood ex...
P I Morris, J K Ingram, D L Gent
Available iron promotes brown rot of treated wood
1992 - IRG/WP 92-1526
Exposure of treated wood blocks to rusting iron increased the toxic threshold of chromated copper arsenate and ammoniacal copper arsenate to a brown-rot fungus Leucogyrophana sp. This supports the hypothesis that the movement of iron ions into wood contributes to the unexpectedly high decay rate of treated wood at the stake test site at Westham Island BC. To what extent this phenomenon may occur e...
P I Morris
The effect of low molecular weight chelators on iron chelation and free radical generation as studied by ESR measurement
2000 - IRG/WP 00-10367
The focus of this work was to improve our current knowledge of the non-enzymatic mechanisms involved in brown-rot decay. Electron Spin Resonance (ESR), also known as Electron Paramagnetic Resonance (EPR), is an attractive technique for the identification and study of chemical species containing unpaired electrons (such as radicals and certain transition metal species). ESR spin-trapping techniques...
Yuhui Qian, B Goodell
Wood degradation mechanisms by the brown rot fungus Gloeophyllum trabeum
1997 - IRG/WP 97-10229
A mechanism for the degradation of wood by the brown rot fungus Gloeophyllum trabeum is outlined. The mechanism includes the function of redox-cycling, low molecular weight phenolic derivatives which sequester and reduce iron in acidic environments. The role of oxalate for the sequestration of iron (hydr)oxides and the pH dependent transfer of iron to the G. trabeum phenolic chelators, as well as ...
B Goodell, J Jellison
Iron in stone wool - one reason for the increased growth and decay capacity of Serpula lacrymans
1992 - IRG/WP 92-1537
The chemical compositions of stone wool and glass wool were analysed. There was more iron in the stone wool than in the glass wool. It was found that iron present in stone wool was easily dissolved by oxalic acid that Serpula lacrymans is able to produce. The stone wool promoted the decay of pine wood by Serpula lacrymans. The glass wool had no effect on the decay capacity of Serpula Iacrymans. Th...
L Paajanen, A-C Ritschkoff
Leaching of Arsenic from Mulch Made from Recycled Construction and Demolition Wood
2005 - IRG/WP 05-50232
Mulch made from recycled construction and demolition (C&D) wood has been reported to contain chromated copper arsenate (CCA)-treated wood and potentially release arsenic in the leachate by rainfall. Such recycled wood mulch is commonly masked with iron-oxide colorant, which is known to combine with arsenic. The objective of this study was to evaluate the levels of arsenic leaching from C&...
T Shibata, H M Solo-Gabriele, T G Townsend, B Dubey
Oxalic acid quantification, oxaloacetase assay and ESI localization of P, C, and Fe from the brown rot fungus Postia placenta
1994 - IRG/WP 94-10063
The mechanism by which brown-rot fungi initiate depolymerization of holocellulose in wood remains unknown. Recently, oxalic acid (OA) has received considerable attention in cellulose breakdown by brown-rot fungi. The OA could serve as a proton donor for hydrolytic or an electron donor for oxidative (Fenton's reaction-H2O2/Fe2+) cleavages of cellulose. The acid may originate via oxaloaceta...
C R Jordan, W V Dashek, T L Highley
Construction of dhows in Kuwait
1981 - IRG/WP 465
To most people Kuwait means oil and the opulence associated with it, but to the seafarer, Kuwait means Dhows. There are as early references to the Kuwaiti Dhows as the 17th century. The Danish explorer Nebuhr in 1756 described Kuwait as having a work power of 10,000 people and 800 wooden boats involved in fishing, pearl diving, and trade. Dhows might well have been the original carriers of "The Pe...
A S Zainal, M A Ghannoum
Chelator production and cellobiose dehydrogenase activity of wood inhabiting fungi
2000 - IRG/WP 00-10363
Multiple components have been postulated to be involved in the Fenton-based biological degradation of wood by brown rot fungi. Chelators have been implicated in essential iron reduction steps. Cellobiose dehydrogenase activity and quinone reducing activity have also been implicated in brown rot biodegradation. When biochelator production by three white rot fungi, three brown rot fungi and three wo...
Weihong Qi, J Jellison
Siderophore production by Trichoderma spp. and its importance in the biological control of wood decay fungi
1994 - IRG/WP 94-10070
Competition for iron as well as other micro-nutrients is an essential component of the microbial ecology of many ecosystems. A wide range of micro-organisms including fungi and bacteria have been shown to increase their ability to efficiently capture iron through the production of specialised iron chelating compounds called siderophores. Since iron is in low supply in wood and has been implicated ...
U Srinivasan, A Bruce, T L Highley
Preliminary studies of the performance of iron chelators as inhibitors of brown rot (Coniophora puteana) attack
1996 - IRG/WP 96-10185
This paper describes experiments to examine the proposal that the presence of iron is essential for brown rot fungi to utilize hydroxyl radicals remote from the hyphae as a means of converting the wood into a food source. reliminary test results are presented from trials using three different iron chelators impregnated into Scots pine (Pinus sylvestris) sapwood blocks. Their relative effects on th...
E D Suttie, R J Orsler, P M Wood
Deterioration of wood viewed from iron nail
1991 - IRG/WP 2368
Deterioration of nail was graded by a five - rank numerical - rating. The rating of nail moisture content and decay of wood were inspected in a mortal-wall of 34-year-old house. The wood was mostly in decay, when the rating of the nail was above about 4, and the moisture content was above about 20%. Nailed wood specimens kept in several humidity room of 20°C for 4 years showed that the rating of ...
H Imamura
The effect of a chelator mediated fenton system on activation of TMP fibres and decolorization of synthesized dyes
2004 - IRG/WP 04-50223
The purpose of this work is to improve our current knowledge of the non-enzymatic mechanisms involved in the brown rot degradation of wood, but also to study the potential applications of a chelator-mediated Fenton system in activation of wood fibers and decolorization of synthesized dyes. In this work, Electron Spin Resonance (ESR) spin-trapping techniques were used to study the generation of hyd...
Yuhui Qian, B Goodell, J Jellison
Electrochemical deterioration of wood in sea-water
1981 - IRG/WP 464
In the specialistic literature only few items can be found dealing with the specific kind of wood deterioration called electrochemical corrosion of wood. This deterioration occurs predominantly on marine vessels, yachts, and other marine craft where wood is jointed by means of various metal connectors. Up to date information demonstrates that in wood surrounding copper connectors, when in proximit...
J Raczkowski
A quantitative weathering study of wood surfaces modified by chromium VI and iron III compounds
1989 - IRG/WP 2330
Thin veneers of Pinus radiata were treated with dilute aqueous solutions of chromium VI and iron III compounds and exposed to natural weathering for 35 days. Zero-span tensile strength and weight losses of treated veneers were compared with losses observed in untreated specimens In a study designed to demonstrate the applicability of strength and weight loss measurements to the rapid quantitative ...
P D Evans, K J Schmalzl
The movement of iron into field test stakes
1987 - IRG/WP 2284
Failed and sacrificial stakes recovered from the Westham Island field test site were examined for their iron content. Varying amounts were recorded, which were greatest in the failed stakes. The possible role of the iron taken up by the below ground portion of the stakes, in accelerating the decay process and/or the preservative leaching is under investigation. The reaction of the iron with the ch...
J N R Ruddick, P I Morris