Your search resulted in 56 documents. Displaying 25 entries per page.
Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric
Fungicidal activity of some organic solvents, copper carboxylates and their complexes with 2-aminoethanol
1997 - IRG/WP 97-30136
We evaluated the activity of eight organic solvents against wood - rotting fungus Trametes versicolor in order to choose the most appropriate one for rapid screening tests of some copper(II) carboxylates and their adducts with 2-aminoethanol. Their activity against the selected fungus was classified in the following order: chloroform > N,N-dimethylformamide > acetonitrile > methanol > ...
M Petric, F Pohleven
Field Testing of Copper Carboxylate Preservatives
2003 - IRG/WP 03-30322
This paper details our ongoing experience with field testing of copper naphthenate and other copper carboxylate preservative systems. Results from field stake tests at an AWPA Hazard Zone 4 test site are presented. In general, copper carboxylates made with ‘synthetics’ yielded results equivalent to or only slightly lower than systems with straight nap acids or nap acids amended with syntheti...
H M Barnes, M G Sanders, T L Amburgey
The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of t...
S J Blunden, R Hill
Non-enzymatic Gloeophyllum trabeum decay mechanisms: Further study
2001 - IRG/WP 01-10395
Information will be presented on the mechanisms involved in, and potential application of, non-enzymatic wood decay by brown rot decay fungi. Specifically, the hypothesized role of low molecular weight phenolate derivatives will be discussed in relation to non-enzymatic degradation of wood. The mechanism of binding of iron by cellulose, and binding and reduction of iron by fungal derivatives and m...
B Goodell, J Jellison
Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley
Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley
Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens
Removal of heavy metals from treated wood using biological methods
2005 - IRG/WP 05-50226
Heavy metals were removed from wood treated with copper based preservatives using brown-rot fungus Fomitopsis palustris. The amount of effective elements removed by treatment methods was examined. The relationship between oxalic acid concentration and the amount of heavy metals removed from each treated wood was also investigated. The relationship between fungus weight and removal rate was also in...
Dong-won Son, Dong-heub Lee
Bioassays for rapid assessment of heavy metal toxicity in seawater
1998 - IRG/WP 98-50112
In evaluating the effect of CCA leachate on the establishment of fouling communities on wood exposed in the sea, three organisms were assessed as biological indicators of heavy metal toxicity. These were two macroalgae, Fucus serratus and Undaria pinnatifida. and the motile protist thraustochytrid, Schizochytrium aggregatum. The choice of these organisms for the tests carried out was based on the ...
C J Brown, R L Fletcher, R A Eaton
Optimum growth conditions for the metal-tolerant wood decay fungus, Meruliporia incrassata TFFH 294
1999 - IRG/WP 99-50142
There is a worldwide need for alternative methods for the treatment and disposal of CCA-treated waste wood. Illman and Highley (IRG/WP 96-10163) reported the isolation of a unique strain of Meruliporia incrassata (TFFH 294) with tolerance to CCA. The strain is capable of degrading CCA treated waste wood, giving a 40% weight loss in the ASTM soil block test. The strain is an ideal candidate for deg...
V W Yang, B Illman
Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston
Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman
Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils.
A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens
Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele
The degradation of wood by metal fastenings and fittings
1972 - IRG/WP 302
As well as the hazards of biological decay, timber used in boat building is subject to the effects of chemical decay associated with the corrosion of metallic fastenings. The title has been deliberately chosen to emphasize that in wooden construction the troubles are not just those of corrosion of the fastenings, but also the destructive secondary effects on the wood caused by the products of the ...
L C Pinion
The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley
Wood surface pretreatments with metal tannates
1989 - IRG/WP 3552
The sequential application of aqueous solutions of tannins derived from radiata pine bark and water-soluble metal salts was examined as a means of improving the water repellency of wood surfaces. Nine metal salts were screened in combination with tannin solutions and, based on water repellency of pretreated filter paper, four were selected for further study. The two-step application of tannin solu...
D V Plackett, D R Cronshaw
Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis
Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions.
Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens
Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele
Detection of increased metal cations after wood decay using Chromeazurol-S
1997 - IRG/WP 97-20112
Chromeazurol-S (CAS) is a dye used for the spectrophotometric determination of metals, mainly aluminum (Al), berillium (Be) and copper (Cu). CAS has been widely used for determining the penetration of copper containing preservatives like CCA (AWPA A3-96). Additional uses include: i) detection of utility pole decay (Esyln, 1979), ii) a chemical spot test for aluminum in wood (Kukachka and Miller, 1...
F Green III, U Srinivasan, R B Miller
The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs
Metal plate fasteners in trussed rafters treated with preservatives or flame retardants - corrosion risks
1977 - IRG/WP 3104
In designing roof trusses employing metal plate fasteners it is generally assumed that the roof will remain dry in service. Whilst this is generally true, damp conditions do arise under some circumstances, although it is not possible to quantify the extent of the risk. It is only possible, therefore, to give general recommendations which must be interpreted in the light of local experience of serv...
R A Laidlaw, L C Pinion
Further steps in the development of above ground wood preservative systems
2002 - IRG/WP 02-30300
Metal and organo-metallic wood preservative systems have provided the consumer with cost effective wood preservative systems which satisfy the performance requirements in a wide range of end uses.
With increasing environmental and legislative control, metal-free formulations have emerged as the dominant preservative systems for the protection of timber in the lower hazard classes.
In higher ha...
P Warburton, A S Hughes