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Local preservation with difluoride pills: Life-time of preservative
1998 - IRG/WP 98-40127
A brief history of the situation in the Netherlands with respect to the preservation of joinery is given. Already in the eighties in the Netherlands many spruce window frames were treated with difluoride pills. One of the possible disadvantages of this kind of diffusing preservatives is the high leaching rate found in laboratory situations. The leaching rate in practice is influenced by many facto...
W J Homan, C Blom, B W Holleboom


Factors affecting leaching of preservatives in practice
1978 - IRG/WP 3113
At the 7th Meeting of the IRG in Poland in May 1975, the findings of collaborative laboratory leaching techniques were discussed, and the dangers inherent in using such results to predict the behaviour of preservative-treated components in service were emphasised. In order to improve our understanding of the factors governing leaching of preservatives in practice, and to identify areas where furth...
R Cockcroft, R A Laidlaw


Leaching of Active Components from Preservative Treated Timber. Stage 1: Semi-Field Testing
2004 - IRG/WP 04-20302
The project is aiming at finding realistic leaching rates from preservative-treated wood in use class 3 (above ground). The project focuses on developing a field trial method for investigating leaching. Panels are subjected to outdoor exposure under natural weather conditions at a test field at the Danish Technological Institute. The leachate is collected and monitored by chemical analysis of the...
N Morsing, B Lindegaard


Elimination of alternative explanations for the effect of iron on treated wood
1993 - IRG/WP 93-30006
Amounts of iron which had previously been found in stakes removed from ground contact reduced decay of untreated wood by four brown-rot fungi. This suggested that the effect of iron may be on the preservative. Analysis of the leachates from CCA- and ACA-treated wood blocks first exposed to rusting iron, then to a brown-rot fungus, showed that the increased decay found in the laboratory for wood ex...
P I Morris, J K Ingram, D L Gent


The influence of previous anti-blue-stain preservative treatments on the fixation of CC in spruce
1997 - IRG/WP 97-30134
Freshly cut and kiln dried spruce boards were treated with 4 different anti-blue stain preservatives (ABP). After a period of 10 days allowing the samples to dry and fixate, the samples were treated with CC (chromium, copper formulation) using a vacuum pressure cycle. After impregnation the wood was steam fixed. A submersion leaching test showed differences in the leachable quantity of copper and ...
M Van der Zee, W J Homan


Evaluation of the leach resistance and preservative efficacy of novel biocides as surface treatments applied by brush to spruce (Picea abies)
1998 - IRG/WP 98-30170
The comparative leach resistance and preservative efficacy of a number of alternative organic preservatives (available from Zeneca Specialties) and selected commercially available biocides as surface coatings to wood in Hazard Class 3 have been assessed. Two concentrations of test preservatives were applied by brush to Spruce (Picea abies), including formulation and untreated controls. A leaching ...
I M Tierney, A Bruce, D C R Sinclair, T Yeates


Germination of basidiospores on preservative treated wood after leaching or natural weathering
1981 - IRG/WP 2150
In tests of residual toxic efficacy after leaching or natural weathering, spore germination with Gloeophyllum trabeum has proved to be a less reliable criterion of attack than when used with unaged preservative treatments. Since spores sometimes prove more tolerant than their parent mycelium, their use should be continued....
J K Carey


Leaching of CCA preservative from treated timber in marine environment
2001 - IRG/WP 01-30254
Knowledge on the amount of preservatives leaching out of treated wood is essential to optimise the chemical loading in various species of timber required for different end uses. In order to gain more insight into this aspect, the residual CCA content in 40 treated timber panels belonging to 14 species removed on destruction by marine organisms from a series of durability tests conducted in Kochi w...
M V Rao, V Kuppusamy, K S Rao, L N Santhakumaran


The shower test method. A leaching test for assessing preservative losses from treated timber under simulated open storage conditions
1993 - IRG/WP 93-50001-04
In the late 1980's against the background of increasing environmental concern a laboratory based accelerated leaching test method for assessing preservative losses-from stored, treated timber was developed by the Dutch organisation for applied Scientific Research (TNO). This test method quantifies the amount of specific preservative components which leach from treated timber under simulat...
J B G A Havermans, W J Homan, M J Boonstra


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Effect of soil parameters on biocide depletion: laboratory and field studies of water- and emulsion-borne preservatives
2000 - IRG/WP 00-30234
Two field test sites with different soils were selected. Soil analysis showed that the soil at the two sites had considerable texture, base saturation, acidity, and cation exchange capacity differences. Five sets of field stakes were treated as follows: three with water-borne CCA to about 0.4 pcf (6.4 kgm-3) retention, one with 0.75% DDAC, and one with 0.75% DDAC:0.25% chlorothalonil. The last two...
T Schultz, D D Nicholas, D E Pettry, M G Kim


The new National Directive on wood preservation in the Netherlands
1998 - IRG/WP 98-50101-03
In the Netherlands the major part of treated timber is sold under the KOMO-certificate. The National Directive for vacuum pressure treated timber on which certification is based, is currently being revised. The new National Directive will contain a code of good practice including maximum leaching figures. It incorporates quality requirements for treated timber, existing legislative requirements an...
W J Homan, J K B Kwisthout, J Dubelaar


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


Chlorothalonil: A new ground contact wood preservative
1992 - IRG/WP 92-3712
Extensive investigations have been conducted in recent years on the performance of chlorothalonil (tetrachloroisophthalonitrile) as a ground contact wood preservative. Efficacy information is presented on a soil block test with 11 Basidiomycetes, a fungus cellar evaluation, above-ground field testing against termites in Australia and Hawaii, and ground-contact field stakes installed in Florida (9 ...
P E Laks, T L Woods


Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching. According to BPD hazard assessment has to be carried out f...
N Morsing


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 5: Effect of wood species and preservative composition on the leaching during storage
1975 - IRG/WP 354
Conversion reactions during storage of CCA treated wood take place even at and below the fiber saturation point as long as ion transport is possible. Increase in drying temperature increases the final pH of the treated wood and the leachability of Cu and decreases slightly the leachability of Cr, while the leachability of As is not affected. This temperature effect is considered to be of no techni...
S-E Dahlgren


Future Directions Regarding Research on the Environmental Impacts of Preservative-Treated Wood: Environmental Impacts of Preservative-Treated Wood. February 8-11, 2004, FL, USA Workshop – Research Needs
2004 - IRG/WP 04-50222
This paper presents a series of documents that focus on research needs for potential future work focusing on the environmental impacts of preservative-treated wood. These documents were developed through a conference sponsored by the Florida Center for Environmental Solutions (FCES), located in Gainesville, Florida. The conference was held in Orlando, Florida, February 8 – 11, 2004 and the tit...
H M Solo-Gabriele, J D Schert, T G Townsend


Aspects of leaching
1976 - IRG/WP 267
With respect to Document No: IRG/WP/246, and the recommendation that an economic leaching test can be based on a non-changing volume of water (500 ml/block), I would like to relate our experiences with this suggestion. Following 14 days of continuous immersion in de-ionized water it was found that blocks treated with moderate and above concentrations of a preservative gave no problems, but those b...
R S Smith


Waterborne preservative treatability of tamarack (Larix laricina (Du Roi) K.Koch)
1998 - IRG/WP 98-40112
Eastern larch or tamarack (Larix laricina (Du Roi) K.Koch) lumber from New Brunswick, Canada was evaluated for preservative treatability with chromated copper arsenate (CCA-C) and ammoniacal copper arsenate (ACA). The fixation and leaching characteristics of CCA-C treated tamarack sapwood and heartwood were also evaluated. CCA-C penetration into both sapwood and heartwood was poor. ACA fully penet...
A Taylor, Y T Ung, P A Cooper


Effect of climate, species, preservative concentration and water repellent on leaching from CCA-treated lumber exposed above ground
2001 - IRG/WP 01-50178
Few studies have examined leaching of chromated copper arsenate (CCA) from treated wood in above ground exposures due to the assumption that leaching is less severe compared to wood in continuous contact with soil or water. However, a significant portion of CCA treated wood is used for above ground applications, exposing considerable volumes of the preservative to precipitation and potential leach...
J L Taylor, P A Cooper


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Experiences with the OECD guideline proposals for the estimation of emissions from preservative-treated wood in the environment
2004 - IRG/WP 04-50209
The practicability of 2 CEN proposals for OECD guidelines on the estimation of emissions from preservative treated wood by laboratory methods for either wood held in storage after treatment and for wooden commodities that are not covered, and are not in contact with ground (guideline 1) or wooden commodities that are not covered and are in contact with ground, fresh water or seawater (guideline 2...
U Schoknecht, R Wegner, E Melcher


Interactions between water-borne preservatives and emulsion additives that influence the water repellency of wood
1991 - IRG/WP 2374
Incorporation of non-polar additives into water-borne treatments through of emulsion technology can greatly improve the physical characteristics of wood in service. Of specific interest with these emulsions is their effectiveness in reducing the rate of wood swelling. We have observed that the presence or absence of preservatives can often significantly influence the resultant effectiveness of the...
A R Zahora


Leaching of active components from preservative-treated timber. Stages 2 & 3: Laboratory testing and comparison with semi-field testing
2004 - IRG/WP 04-20303
This part of the project is focussed on leaching from preservative-treated wood obtained by the laboratory test method CEN/OECD draft guideline, February 2003 ”OECD guideline for the testing of chemicals proposal for new guideline XXX. Estimation of Emissions from Preservative-treated Wood to the Environment: Laboratory Method for wood held in the storage yard after treatment and for wooden comm...
N Morsing, B Lindegaard


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