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Formation of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) during the combustion of impregnated wood
1995 - IRG/WP 95-50040-19
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) a...
T Salthammer, H Klipp, R-D Peek


Dimensional stability and decay resistance of wood upon modification with some new type chemical reactants
1994 - IRG/WP 94-40028
Solid wood of home grown species can be upgraded by chemical modification with environmentally acceptable chemicals. The best kwown example of modification reaction is acetylation with acetic anhydride. A continued search for reactive chemicals other than acetic anhydride is ongoing, aiming at the improvement of technical properties of wood. This contribution deals with the results of a screening ...
P Goethals, M Stevens


Fluoride movement through Douglas-fir and hem-fir lumber following dipping in potassium/ammonium bifluoride
1995 - IRG/WP 95-40040
The ability of ammonium and potassium fluoride to diffuse through Douglas-fir and hem-fir lumber was evaluated over a 90 day period. Boards were dipped in a solution containing 10% (by weight) of ammonium and potassium bifluoride, then stored under cover for 90 days. Samples removed 30, 60 and 90 days after treatment indicated that the fluoride was unable to completely penetrate the wood. Penetrat...
J J Morrell, C S Love


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


Chemical Analysis of Southern Pine Pole Stubs Thirteen Months Following Treatment with Three Methylisothiocyanate Based Commercial Fumigants
2002 - IRG/WP 02-30294
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC based fumigants, liquid metham sodi...
R J Ziobro, T C Anderson, D J Herdman, J Guzzetta, T Pope


Assessment of the effects of rentex remedial treatment on some wood pole inhabitant micro-organisms
1994 - IRG/WP 94-30053
The effects of a remedial ground-line treatment using Rentex, a stabilised paste containing a mixture of fluoride and dichromate salts, on the micro-organisms inhabiting a sample of some 160 creosoted, on-line, electricity distribution poles, have been investigated as part of an appraisal of the efficacy of this remedial treatment. Half of the poles were treated and the other half used as controls...
D C R Sinclair, G M Smith, A Bruce, H J Staines


The influence of drilling patterns on the distribution of toxicants from Polesaver Rods in hardwood poles
1994 - IRG/WP 94-30051
Polesaver Rods are solid rods of wood preservative that are used as a groundline maintenance treatment to control biodeterioration in hardwood transmission poles in Australia. The rods are inserted in holes that are drilled in a prescribed manner to distribute the toxicants into the critical groundline region of the poles. To determine the influence of drilling patterns on the distribution of toxi...
W D Gardner, C N McEvoy


Preservative treatment specifications in Fiji
1982 - IRG/WP 3190
The preservative treatment specification used in Fiji is outlined. Reference is made to a basic end use classification and to locally approved treatment processes, preservatives and retention levels. Amenability ratings are defined and penetration requirements for broad commodities indicated. Currently commercial operations rely entirely on pressure treatment with copper-chrome-arsenic multisalts ...
A S Alston


Chemical treatment of chips for outdoor storage. Evaluation of sodium N-methyldithiocarbamate + sodium 2,4-dinitrophenol treatment
1980 - IRG/WP 2134
Fresh slash pine chips were treated by spraying them with a dilute aqueous solution of sodium N-methyldithiocarbamate and sodium 2,4-dinitrophenol. The were then formed into an experimental chip file 10 feet high, and the pile was maintained for seven months. The treatment effectively slowed heat release and retarded losses in wood substances, tall oil, pulp yield, and pulp strenght. Under certain...
E L Springer, M Benjamin, W C Feist, L L Zoch, G J Hajny


Ten year performance of l-joints made from borate diffusion treated wood
2000 - IRG/WP 00-30225
While there are decades of experience with borate-treated wood in coated, exterior applications in New Zealand and the UK, other countries have been more reluctant to use this process. As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up, in 1990, an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and ...
P I Morris


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


Fluoride and chromium concentrations in soil adjacent to remedially treated distribution poles
1996 - IRG/WP 96-50066
Soils adjacent to Rentex treated 'on-line' distribution poles were analysed for total fluoride and chromium content for comparison with background values of these elements. Soil samples 6 cm and 25 cm downslope of selected poles were recovered at 1 week, 1 month, 6 and 12 months after treatment. Background soil samples were taken 50 m from the poles at sampling times. Fourteen po...
D C R Sinclair, G M Smith, A Bruce, H J Staines, P Durrant


Quantification of creosote and fluoride in remedially-treated poles
1997 - IRG/WP 97-40097
Three creosoted transmission poles were put into service in 1961 and they were subsequently remedially-treated with a proprietary fluoride remedial paste formulation in 1981. The poles were removed from service in 1996 and their ground-contact regions were analysed for creosote and fluoride contents. It was found that the poles were undecayed. Creosote retentions decreased down the profiles of the...
B P Hill


The efficacy of boron preparations
1987 - IRG/WP 3400
The toxicity threshold of boric acid for egg larvae of Hylotrupes bajulus Linné is approx. 0.4 kg/m³ of wood (71 g B/m³) over a 12-week test period, and approx. 0.3 kg/m³ of wood (53 g B/m³) over a 6-month test period. The corresponding values for borax are 0.5-0.6 kg/m³ of wood (56-68 g B/m³) and 0.3-0.4 kg/m³ of wood (34-45 g B/m³). The values are somewhat lower in the case of the egg l...
J T De Jonge


A field evaluation of chromated fluoride as a remedial treatment for creosoted wooden distribution poles
1989 - IRG/WP 3556
A commercial chromated fluoride formulation was applied by injection process to previously inoculated creosoted wooden distribution pole sections at a field site in Scotland and appraisal of the efficacy of the formulation against Lentinus lepideus was undertaken at two month and fifteen month intervals. Preliminary results suggest a rapid elimination of organisms from colonised areas. The usage o...
B King, A Bruce


The influence of pentachlorophenol on mycelial growth of wood decay fungi Trametes versicolor, Grifola frondosa, Hypoxylon fragiforme, and Coniophora puteana
2007 - IRG/WP 07-30437
Polychlorinated phenols have been one of the most commonly used biocides. In recent time they have been increasingly eliminated from the marked. Because of their high stability, they are still present in numerous products, including impregnated wood. In our research we studied in vitro the influences of pentachlorophenol and/or sodium pentachlorophenolate on mycelial growth of four wood degrading ...
F Pohleven, B Boh


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


Performance of softwood preservative treated stakes after 4 years exposure in-ground to decay fungi and termites in tropical Australia
2008 - IRG/WP 08-10643
This field study was based on the 1993 IUFRO method and designed as a graveyard (in-ground) test in the tropical region of the Northern Territory to examine the efficacy of novel preservative formulations developed as alternative protection for softwood timber against decay fungi and termites for Hazard Class 3 and 4. This study was supported by the Forest and Wood Products Research and Develop...
B M Ahmed (Shiday), J R J French, S R Przewloka, P Vinden, J A Hann, P Blackwell


Soft Rot Determines Service Life of L-joints with Low Borate Loading
2008 - IRG/WP 08-30470
As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and amabilis fir) in 1990. The treated material had a low initial retention of only 0.2% boric acid equivalent and analysis after 5 years revealed no detectable borate close to the tenon. Nev...
P I Morris, J Wang, J K Ingram


Effects of bleaching process on the roughness values of wood surfaces of Lebanon cedar (Cedrus libani A. Rich.) and Black poplar (Populus nigra L.) using NaOH (sodium hydroxide), H2O2 (hydrogen peroxide) and Ca(OH)2 (calcium hydroxide)
2008 - IRG/WP 08-40403
Technical progress in the wood industry has been rapid in recent times. In this case, the quality assurance of the consumer products aligned with aesthetics value appears as one of the most important parameters. Because of the outer appearance of goods exert an effect on customers, interest in production of high quality surfaces of wooden commodities has increased essentially based on the surface ...
I Usta, E Aydinlar


Degradation of polychlorinated organic biocides by the wood decaying fungi
2008 - IRG/WP 08-50253
Organochlorine biocides such as lindane, pentachlorophenol sodium salt, and polychlorinated biphenyl 153 have been widely used as wood preservatives. Due to their low degradability by soil bacteria, treated waste wood products pose a serious threat to the environment. Consequently, there is an increased need for development of new strategies for their detoxification. In this work, the bioremediati...
I Vidic, L Zupancic-Kralj, K Sepcic, F Pohleven


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Screening method to test efficacy of fumigants against fungi and preliminary data on the efficacy of sulfuryl fluoride
2014 - IRG/WP 14-20551
Methyl bromide is being phased out and there is an urgent need to find a suitable replacement that is effective in reducing exotic pest establishments via trade in wood products. Efficacy data for established phytosanitary fumigants were mostly developed for arthropods and nematodes, and limited information exists for plant pathogens. Increased interest in developing a fast screening process for f...
A Uzunovic, A Mukherjee, R Mack, P Elder, S Myers


Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


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