IRG Documents Database and Compendium


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Towards a colour assay of wood degradation
1982 - IRG/WP 2180
A colour assay for the enzyme catalase is described. Since the activity of this enzyme has previously been shown to be correlated with degree of wood degradation as determined by other methods, this assay may provide a rapid quantitative indicator of superficial and internal wood decay....
M A Line


Aspergillus fumigatus Fresenius resistance to chemical preservatives in piles of pine and birch wood chips
1981 - IRG/WP 1146
Investigation has been carried out on the communities of fungi developing in birch and Scots Pine chip piles in the Ostroleka Pulp and Paper Mill in the North-East of Poland The species composition or fungal communities and their development in a dozen of chip piles during storage was investigated. Untreated and chemically treated birch and pine wood chips were investigated. In all samples the gre...
M H Zielinski


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Fluoride woodpill
1987 - IRG/WP 3431
Decay problems of spruce joinery in the Netherlands in the 1960's and 1970's led to the introduction of preservative treatment. Because of the known penetration difficulties with Spruce, the results of the treatments were not always successful. The fact that the decay was found only in the joints led to development of the philosophy of "local preservation" of the joints in remedi...
J W P T Van der Drift, K J M Bonsen


Chemical Analysis of Southern Pine Pole Stubs Thirty-Nine Months Following Treatment with Three Methylisothiocyanate-Based Fumigants
2004 - IRG/WP 04-30349
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC-based fumigants, liquid metham sodi...
R J Ziobro, J Fomenko, D J Herdman, J Guzzetta, T Pope


Determination of total fluoride in preservative-treated wood by ion selective electrode, without steam distillation
1996 - IRG/WP 96-20086
An analytical method was developed to determine total fluoride in wood treated with aqueous fluoride or borate-fluoride formulations. Ground wood was mixed with 60% sodium hydroxide solution and oven-dried overnight before furnacing at 600°C. The cool fused product was dissolved in warm water before adding a powerful complexant/buffer solution containing sulphosalicylic acid and EDTA. Fluoride wa...
M J Kennedy


Long-term protection of stored lumber against mould, stain, and specifically decay: A comparative field test of fungicidal formulations
1984 - IRG/WP 3281
The problem of decay in packaged, unseasoned lumber stored for many months has become of major importance in recent years. Large financial claims have resulted from decay in Canadian lumber stored at length in seaports and storage yards of distributors. For decades acceptable protection from moulds and sapstain was readily achieved with chlorinated phenols applied at appropriate treating levels. H...
A J Cserjesi, A Byrne, E L Johnson


The use of a physical field model to study the effects of remedially treated timber on the growth of perennial ryegrass (Lolium perenne) and rye (Secale cereale), and the accumulation of toxic preservative constituents in Lolium perenne
1995 - IRG/WP 95-50040-02
Low cost laboratory model systems can be used to give relatively rapid indications of the environmental effects of preservative treated timber in soil contact. This paper details the effects of remedially treated timber on the growth of crops of Lolium perenne and Secale cereale seeded on soilbeds of different texture in close proximity to remedially treated creosoted pole sections. Lolium perenne...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines


The influence of wood moisture content on the fungitoxicity of methylisothiocyanate in Douglas fir heartwood
1987 - IRG/WP 3430
The fumigant methylisothiocyanate (MIT) effectively controls decay fungi in large wood structures, but the influence of environmental factors on its performance are not well understood. Experiments found wood moisture content to greatly influence the fungitoxicity and sorption of MIT in Douglas fir heartwood. At constant, low MIT vapor concentrations (less than 1 µg/cc air), wood at 10% MC bound ...
A R Zahora, J J Morrell


Initial results and observations of a model system to assess the efficacy and environmetal impact of preservative treated wood
1993 - IRG/WP 93-50001-02
The development of a closed model system for the laboratory assessment of the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles has been described (IRG/WP/2395-92). The model consists of a precipitation apparatus above a treated pole section positioned in a soil profile from which leachate was collected via a series of simulated field dra...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Laboratory evaluation of borate formulations as wood preservatves to control the subterranean termite coptotermes acinaciformis (isoptera: Rhinotermitidae) in Australia
2001 - IRG/WP 01-30266
The termiticidal efficacy of Borocol (sodium octaborate tetrahydrate), boric acid, bore-ester-7 and tri- methyl borate was evaluated in laboratory bioassays against Coptotermes acinaciformis (Froggatt). Seasoned sapwood blocks of Pinus radiata D. Don, and Eucalyptus regnans (F. Muell) were impregnated with the various borate compounds. There were marked differences in mass loss and mortality rate ...
B M Ahmed, J R J French, P Vinden


A laboratory evaluation of the fumigant, sulfuryl fluoride (VikaneR), against the Formosan termite Coptotermes formosanus Shiraki
1982 - IRG/WP 1164
A series of laboratory experiments showed that the fumigant sulfuryl fluoride (VikaneR) was effective against small groups of Coptotermes formosanus Shiraki exposed to the gas directly at temperatures from 20-40°C. At 10°C fumigations failed regardless of initial gas concentration. Very high or total mortality was observed at concentrations of 0.79 cc/L or higher. A second series of experiments ...
J P La Fage, M Jones, T Lawrence


Performance of boron and fluoride based rods as remedial treatments in Douglas-fir poles
1995 - IRG/WP 95-30070
Boron and fluoride are widely used for remedial internal treatments, but their use in North America has been limited. Recently, however, interest in these chemicals has increased as the result of concerns about the risks of fumigant usage. The performance of boron or a boron/fluoride combination was assessed in Douglas-fir poles over 1 to 3 year periods. Both chemical formulations diffused well th...
J J Morrell, P F Schneider


The effect of different concentrations of polesaver rods on the survival of selected decay fungi in liquid culture
1998 - IRG/WP 98-30166
An in-vitro method was developed to determine the effect of solutions of Polesaver Rods on the survival of selected decay fungi. Polesaver Rods are a diffusing preservative treatment containing fluorine and boron designed for the internal remedial treatment of power poles. Two white-rot fungi, Perenniporia tephropora and Trametes versicolor, and two brown-rot fungi, Polyporus verecundus and Gloeo...
M A Powell, T Deldot, C McEvoy


Determination of total fluoride and boron in preservative-treated wood fluoride by ion selective electrode without steam distillation, and boron colorimetrically using azornethine-h
1998 - IRG/WP 98-20135
An analytical method was developed to determine total fluoride and boron in wood treated with aqueous or solid diffusing fluoride or borate-fluoride formulations. Ground wood was mixed with 30% sodium hydroxide solution and oven-dried for 2 hours before furnacing at 600° C for 1 hour. The cool fused product was dissolved in hot water, transferred to a plastic beaker and neutralised. Fluoride was ...
P A Collins, M J Kennedy


Effect of wood species on decomposition efficiency of metham sodium
1992 - IRG/WP 92-3699
The effect of wood species and temperature on efficiency of metham sodium (32.1% sodium N-methyldithiocarbamate) decomposition to methylisothiocyanate (MITC) was investigated on 10 hardwoods and 9 conifers over a 144 hour period. Gas chromatographic analyses of headspace samples and ethyl acetate extracts of the wood revealed that decomposition never approached the theoretical decomposition effici...
J J Morrell


Risk of pulmonary damage as a result of an evaporation of ca. 50 ppb = 42 mg HF, evaporated from wood treated by difluorides
1987 - IRG/WP 3401
In this review of the literature the effects of fluorides and fluorine on man are described, especially the low level effects of inhaled HF on human beings. The term "fluoride" is used as a general term everywhere, where exact differentiation between ionic and moluecular forms or between gaseous and particulate forms is uncertain or unnecessary. The term covers all combined forms of the element, r...
H F M Nijman


Effects of alkali treatment on some mechanical and chemical properties of creosote treated oaks
1991 - IRG/WP 2366
To date, there is a lack of information on the effects of chemical treatment on the performance of creosote preservative treated oak sleepers. This factorial experiment was designed to analyze three main effects: species (Quercus alba and Quercus rubra) creosote treatment (treated and untreated), and alkali (NaOH) soaking (0, 1, and 10 percent). The modulus of elasticity (MOE) and fiber stress at ...
P Chow, A J Reinschmidt, E J Barenberg, L C Chang


Gas chromatographic determination of 1,8-naphthalimide, N-Hydroxy-1,8-naphthalimide (N,N-naphthaloylhydroxylamine) and the sodium salt of N-Hydroxy-1,8-naphthalimide
2003 - IRG/WP 03-20259
A number of naphthalimide (NI) derivatives are used as efficient laser dyes, in medicine or in scanning electron microscopy. Only N,N-naphthaloylhydroxylamine (NHA) has been shown to be an effective wood preservative against wood decay fungi and termite damage. However, limited information is available concerning the analytical detection of NI-derivatives in treated timber. There is a clear need ...
E Melcher, F Green III


Emissions from the combusting of boron and fluoride containing wood
1995 - IRG/WP 95-50040-18
The combustion properties of waste wood and wood residues containing wood preservatives were investigated in several test series after having been blended with untreated wood at a ratio of 1:4. The results for CFB, SF and boric salt show that, provided an optimized combustion, the concentrations of the stack pollutants correspond approximately with those found for untreated wood. Only during the c...
T Salthammer, H Klipp, R-D Peek


Development of a model system to assess the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles
1992 - IRG/WP 92-2395
A closed model system was designed to facilitate a controlled study of the leachability and environmental fate of a remedial preservative under laboratory conditions. The elements of the model include a precipitation apparatus above a treated pole section which is positioned in a representative soil profile supporting a sward of perennial ryegrass. The model will allow detailed examination of the ...
D C R Sinclair, G M Smith, A Bruce, B King


Diffusion of chromium and fluoride in Rentex treated creosoted pole sections
1991 - IRG/WP 3659
A chromated fluoride preservative was applied by injection to the groundline regions of creosoted distribution pole sections and these were erected at a filed site in Scotland. Wood samples were recovered for chemical analysis at one week, two, five and twelve months after treatment. Small sample mass and destructive nature of the analysis necessitated modification of an alkali fusion technique to...
D C R Sinclair, G M Smith, A Bruce, B King, H J Staines


Determination methods of phytotoxic effect of wood preservatives
1990 - IRG/WP 2349
The phytotoxic effect of wood preservatives so widely used plays a considerable role in the protection of natural environment. A review was made of the existing methods with which to assess the phytotoxicity of the above chemicals and some suggestions were given concerning the methods most appropriate for their unification. Two areas of research are proposed: 1) estimating the direct effect on ind...
A Kundzewicz, J Wazny


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