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Long-term protection of stored lumber against mould, stain, and specifically decay: A comparative field test of fungicidal formulations
1984 - IRG/WP 3281
The problem of decay in packaged, unseasoned lumber stored for many months has become of major importance in recent years. Large financial claims have resulted from decay in Canadian lumber stored at length in seaports and storage yards of distributors. For decades acceptable protection from moulds and sapstain was readily achieved with chlorinated phenols applied at appropriate treating levels. H...
A J Cserjesi, A Byrne, E L Johnson


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


Laboratory evaluation of borate formulations as wood preservatves to control the subterranean termite coptotermes acinaciformis (isoptera: Rhinotermitidae) in Australia
2001 - IRG/WP 01-30266
The termiticidal efficacy of Borocol (sodium octaborate tetrahydrate), boric acid, bore-ester-7 and tri- methyl borate was evaluated in laboratory bioassays against Coptotermes acinaciformis (Froggatt). Seasoned sapwood blocks of Pinus radiata D. Don, and Eucalyptus regnans (F. Muell) were impregnated with the various borate compounds. There were marked differences in mass loss and mortality rate ...
B M Ahmed, J R J French, P Vinden


Low polymer levels containing bioactive monomer polymerized in situ provide resistance to Gloeophyllum trabeum
1995 - IRG/WP 95-30066
Wood preservation based on in situ polymerization of potentially bioactive monomers has been studied. Tributyltin oxide acrylate (TBTOA) and pentachlorophenol acrylate (PCPA) were synthesized. Wood samples were treated at 2, 5, 10, 15 and 20% by weight solutions with varying amounts of crosslinker (trimethylolpropane trimethacrylate, TMPTM) and polymerized in situ in wood samples (2.54 x 2.54 x 0....
R E Ibach, R M Rowell


Effect of wood species on decomposition efficiency of metham sodium
1992 - IRG/WP 92-3699
The effect of wood species and temperature on efficiency of metham sodium (32.1% sodium N-methyldithiocarbamate) decomposition to methylisothiocyanate (MITC) was investigated on 10 hardwoods and 9 conifers over a 144 hour period. Gas chromatographic analyses of headspace samples and ethyl acetate extracts of the wood revealed that decomposition never approached the theoretical decomposition effici...
J J Morrell


Effects of alkali treatment on some mechanical and chemical properties of creosote treated oaks
1991 - IRG/WP 2366
To date, there is a lack of information on the effects of chemical treatment on the performance of creosote preservative treated oak sleepers. This factorial experiment was designed to analyze three main effects: species (Quercus alba and Quercus rubra) creosote treatment (treated and untreated), and alkali (NaOH) soaking (0, 1, and 10 percent). The modulus of elasticity (MOE) and fiber stress at ...
P Chow, A J Reinschmidt, E J Barenberg, L C Chang


Gas chromatographic determination of 1,8-naphthalimide, N-Hydroxy-1,8-naphthalimide (N,N-naphthaloylhydroxylamine) and the sodium salt of N-Hydroxy-1,8-naphthalimide
2003 - IRG/WP 03-20259
A number of naphthalimide (NI) derivatives are used as efficient laser dyes, in medicine or in scanning electron microscopy. Only N,N-naphthaloylhydroxylamine (NHA) has been shown to be an effective wood preservative against wood decay fungi and termite damage. However, limited information is available concerning the analytical detection of NI-derivatives in treated timber. There is a clear need ...
E Melcher, F Green III


Mixtures of fungicides screened for the control of sapstain on Pinus radiata
1984 - IRG/WP 3307
Fourty nine mixtures of fungicides were evaluated in a rapid laboratory screen for the control of stain, mould and decay fungi on Pinus radiata (D.Don). The most effective mixture was thiophanate methyl plus chlorothalonil closely followed by the mixtures of thiophanate methyl plus benzisothiazolone and thiophanate methyl plus dithio-bis (benzmethylamide). Benzalkonium chloride, thiram and ziram, ...
P J Hayward, W Rae, J Duff


Trials of new treatments for prevention of kiln brownstain of white pine (Pinus strobus)
1995 - IRG/WP 95-30068
White pine (Pinus strobus) often develops a surface brown oxidative stain when kiln dried. Such stain downgrades high quality lumber and is most likely to occur when fresh, unseasoned lumber is stacked during warm weather prior to kiln drying. Use of reducing agents or pH alteration has been successful, but may have some practical limitations for general use. This study attempted to prevent browns...
E L Schmidt, E Christopherson, T L Highley, M H Freeman


Improvement of intrinsic properties of wood by chemical wood densification - Hydrophobic aspects and durability aspects
1999 - IRG/WP 99-40149
To improve the intrinsic properties of Scot pine wood ((1) hydrophobic surface and (2) durability), two ways of chemical modification have been tested. The first one is the chemical modification of hydroxyl groups by active substances like diisocyanate compounds with a copolymerization step. The second way is a densification by an impregnation of resins and a gamma polymerisation. This second way ...
G Labat, Q K Tran, I Le Bayon


Determination methods of phytotoxic effect of wood preservatives
1990 - IRG/WP 2349
The phytotoxic effect of wood preservatives so widely used plays a considerable role in the protection of natural environment. A review was made of the existing methods with which to assess the phytotoxicity of the above chemicals and some suggestions were given concerning the methods most appropriate for their unification. Two areas of research are proposed: 1) estimating the direct effect on ind...
A Kundzewicz, J Wazny


Movement of water through quaternary ammonium treated wood
1987 - IRG/WP 3440
Radiata pine sapwood stakes were treated with didodecyl methyl 1, 3 dichloropropenyl ammonium chloride and distearyl dimethyl ammonium chloride. Various ratios of these two chemicals were, tested to determine the extent of water movement through the treated wood. Measurements were taken of the amount of water moved through the wood, degree of wetting of various sectors of the stakes, and the distr...
P J Hayward, J Duff


Development of a disinfection treatment for oak logs to be imported from the USA
1984 - IRG/WP 3283
The European veneer industry depends greatly on oak supplies from the USA. To prevent the accidental introduction of the American Oak Wilt Disease (Ceratocystis fagacearum) into the member states of the EC, a disinfection treatment was developed for oak logs under consideration of the technical requirements of veneer production. Laboratory experiments and field trials in Germany and in the USA sho...
W Liese, M M Ruetze


Reduction of kiln brown stain in radiata pine lumber after log fumigation with methyl bromide
1997 - IRG/WP 97-30129
Methyl bromide fumigation of freshly felled radiata pine log sections effectively killed living cells in parenchyma to at least 75mm into sapwood. Lumber cut from logs (fumigated and control) stored 1 month outdoors (dry) showed slightly reduced brown stain when kiln dried at conventional temperatures. A more dramatic reduction and elimination of brown stain was noted in lumber cut from fumigated ...
E Schmidt, M E Hedley, D R Page, D Cross


Dimensional stability and decay resistance of wood upon modification with some new type chemical reactants
1994 - IRG/WP 94-40028
Solid wood of home grown species can be upgraded by chemical modification with environmentally acceptable chemicals. The best kwown example of modification reaction is acetylation with acetic anhydride. A continued search for reactive chemicals other than acetic anhydride is ongoing, aiming at the improvement of technical properties of wood. This contribution deals with the results of a screening ...
P Goethals, M Stevens


Log fumigation prevents enzyme-mediated sapwood discolorations in hardwoods
1993 - IRG/WP 93-10003
Non-microbial sapwood discolorations in hardwood lumber can cause economic loss by degrade of quality. Based on the hypothesis that the enzyme-mediated sapstain may develop in part from byproducts of parenchyma cells in wood, reshly felled logs of red oak (Quercus spp.) and sugar hackberry (Celtis laevigata) were fumigated under a plastic tarp with methyl bromide. Log sections were checked after f...
E L Schmidt, T L Amburgey


Chemical Analysis of Southern Pine Pole Stubs Thirteen Months Following Treatment with Three Methylisothiocyanate Based Commercial Fumigants
2002 - IRG/WP 02-30294
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC based fumigants, liquid metham sodi...
R J Ziobro, T C Anderson, D J Herdman, J Guzzetta, T Pope


Performance of groundline bandage remedial treatments in western US species transmission poles
1993 - IRG/WP 93-30019
Groundline bandages are an important element in remedial treatment strategies for utility poles in the United States. Several bandages containing new or reformulated components have recently been developed but have not been adequately tested. This paper reports on the degree of diffusion of copper naphthenate, boron, and sodium fluoride from groundline bandages into pressuretreated Douglas-fir, po...
P G Forsyth, J J Morrell


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Preservative treatment specifications in Fiji
1982 - IRG/WP 3190
The preservative treatment specification used in Fiji is outlined. Reference is made to a basic end use classification and to locally approved treatment processes, preservatives and retention levels. Amenability ratings are defined and penetration requirements for broad commodities indicated. Currently commercial operations rely entirely on pressure treatment with copper-chrome-arsenic multisalts ...
A S Alston


Effects of chemical pretreatment of Douglas-fir heartwood on efficacy of potential bioprotection agents
1990 - IRG/WP 1440
Biological protection against wood decay fungi represents an environmentally attractive alternative to the use of chemicals; however, the process of identifying suitable candidates and the conditions that ensure successful protection pose major challenges. One critical aspect of this problem is to identify organisms that can rapidly and uniformly colonize the wood. Wood contains low levels of nutr...
B Dawson-Andoh, J J Morrell


Ten year performance of l-joints made from borate diffusion treated wood
2000 - IRG/WP 00-30225
While there are decades of experience with borate-treated wood in coated, exterior applications in New Zealand and the UK, other countries have been more reluctant to use this process. As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up, in 1990, an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and ...
P I Morris


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Treatment of wood by diffusion of salts
1976 - IRG/WP 368
A brief survey is given on the treatment of wood by diffusion of salts. The compounds used for this process, mainly boron and fluorine compounds, are mentioned and the factors influencing diffusion described. The main pre-condition is a high moisture content of the wood of above 40%. Fields of application are fresh roundwood, remedial treatment of poles and sleepers, preservation of posts and espe...
G Becker


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


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