Your search resulted in 110 documents. Displaying 25 entries per page.
Natural weathering of wood in a sunny climate effects on surface chemistry and paint adhesion
1997 - IRG/WP 97-20109
Radiata pine veneers and blocks were exposed to natural weathering under Australian summer conditions over a period of 30 days. Infrared spectroscopy revealed that there was perceptible surface delignification after 4 hours exposure, substantial surface delignification after 3 days exposure and almost complete surface delignification after 6 days. Viscometry determinations on holocellulose samples...
P D Evans, P D Thay, K J Schmalzl
Reaction of osmium tetroxide with a diphenolic compound as a model substance for demethylated lignin
1986 - IRG/WP 1303
By using caffeic acid as a model substance for diphenolic moieties of demethylated lignin it was found that electron dense particles called by the authors "osmiophilic particles" in former papers are reaction products of OsO4 with the model substance. By these products it is possible to indicate the enzymatic demethylation of lignin taking place during wood decay. The appearance of the electron de...
K Messner, E Srebotnik
Formation of soft rot cavities in relation to concentric layers in wood fibre walls
1983 - IRG/WP 1185
A large number of timber species attacked by soft rot have been examined using light microscopy. The S2 layers in a large number of the timbers exhibited special structural features in the form of thin concentric layers. Several observations indicate that these layers may be characterised as "weak" zones by being more easily degradable than the surrounding wall layers. The chemical structure of th...
T Nilsson, G F Daniel
Microbial breakdown mechanisms. Mini-Symposium at the 18th IRG meeting, Honey Harbour, Ontario, Canada
1987 - IRG/WP 1327
An understanding of how micro-organisms cause chemical alternation to wood is essential for effective wood preservation. Investigation of the Microbial Breakdown of wood is a very dynamic research field and is increasing in importance as several biocides are being examined as alternativesw to classic wood preservatives. These biocides often do not possess broad spectrum activity. It is esential th...
L E Leightley
Correlation between changes in colour and chemical composition during photo-degradation of wood surfaces
2005 - IRG/WP 05-40301
Changes in colour of wood (yellowing) during photo degradation or weathering reflect chemical changes in wood. Therefore, the relationship between changes in chemical composition and CIELAB colour parameters is very important to characterize photodegradation of lignocellulosic surfaces. In this study, the changes in chemical composition and yellowing due to photo-degradation was studied by expos...
K K Pandey
Effect of angle of exposure on degradation of radiata pine during weathering trials
1988 - IRG/WP 2301
The importance of angle of exposure on the degree of weathering of materials has not been adequately resolved. In conventional tests, specimens are exposed at an angle of 45° facing the equator, but more recently experiments on polymeric materials have suggested that an angle of 0° may be preferable since this angle maximises levels of received ultra-violet radiation. In this paper the degradati...
P D Evans
Distinguishing isolates of Aureobasidium on the basis of their ability to utilise lignin breakdown products as a sole carbon source
1996 - IRG/WP 96-10151
Wild isolates of Aureobasidium were obtained by dilution plating from a ca 20 year old painted pine window frame. Four isolates were obtained from the paint/wood interface region and four isolated from regions deep in the wood. The isolates were then used to inoculate liquid cultures containing ferulic acid, a lignin breakdown product, present as the sole carbon source. Ability of the isolates to ...
M W Schoeman, D J Dickinson
Soft rot decay in acetylated wood. Chemical and anatomical changes in decayed wood
2002 - IRG/WP 02-40231
Acetylated Beech (Fagus sylvatica) and Scots Pine (Pinus sylvestris) wood were studied in soil beds under laboratory conditions for longer periods. High mass losses and dynamic MOE losses were measured in non-acetylated wood and at lower weight percent gains (WPG). Rapid losses of lignin, holocellulose and ?-cellulose occurred in non-acetylated beech wood and no losses were detected at the highest...
B Mohebby, H Militz
Evidence for the participation of the osmiophilic particles in the enzymatic demethylation of lignin
1984 - IRG/WP 1239
Transmission electron microscopic observations of the white-rot fungi Trametes hirsuta and Phanerochaete chrysosporium grown on a series of wood pulp with a graded lignin content and mycelium from the clarified centre of an agar-medium containing lignin (E1-effluent from the bleaching process) showed that osmiophilic particles are only induced by native lignin. Taking into account that the osmioph...
K Messner, H Stachelberger
Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe
Quantification of wood decay effects by HPLC analysis
1992 - IRG/WP 92-1576
The present work quantified the effects of the white rot basidiomycetes Coriolus versicolor and Phanaerochaete chrysosporium, and also those of the brown rot fungi Coniophora puteana and Lentinus lepideus, on Pinus patula and Eucalyptus grandis. Wood colonisation was quantified by Kjeldahl nitrogen determinations converted to biomass assays, and degradation was quantified by weight losses produced...
V Singh, M Tarin, G D Shelver, A A W Baecker
The rôle of lignin in the nutrition of several Australian termites
1983 - IRG/WP 1191
The ability of Nasutitermes exitiosus (Hill), Coptotermes acinaciformis (Frogatt), Coptotermes lacteus (Froggatt) and Mastotermes darwiniensis (Froggatt) to degrade 14C-lignin preparations was examined. The lower termites were unable to degrade lignin. Nasutitermes exitiosus was able to cause a 5-8% degradation of hardwood lignins and a synthetic lignin. It failed to degrade the lignin of Pinus ra...
L J Cookson
A technique for the rapid assessment of wood surface degradation during weathering
1987 - IRG/WP 2281
Radiate pine (Pinus radiata D. Don) sapwood samples taken from four trees were converted into thin strips 100 x 10 x 0.085 (85 µm) mm³, (longitudinal x radial x tangential) in size and exposed in preweighed hatches to the weather inclined at 45° facing equatorially for 10, 20, 40, 60, 80 and 100 days. Significant (P < 0.001) weight losses occurred with time over the exposure period. Differen...
P D Evans, D Abbott, S Thein
Pyrolysis GC-MS as a tool for lignin analysis
1987 - IRG/WP 2201
Pyrolysis-GC-MS is a rapid process for analysis of rather complex organic compounds. The method has great application to petroleum shale oil and wood lignin. Small powdered samples (several mg) are placed in silica capillary tubes and rapidly heated in an inert atmosphere such as He or N2. Breakdown products of the pyrolysis are then trapped and held for an allocated time in an injector attached t...
L Doimo
Lignin degradation by a non-enzymatic system supposed to be active in white rot fungi
2000 - IRG/WP 00-10340
Electron microscopic investigations have shown that ligninolytic enzymes of white-rot fungi are only able to penetrate the wood cell wall in late stages of degradation. Thus, the selective degradation of lignin of certain white-rot fungi can only be explained on the basis of a low molecular weight, highly diffusible system. A system, consisting of copper, a coordination compound and either H2O2 or...
P Lamaipis, W Gindl, T Watanabe, K Messner
Rapid loss of lignin at wood surfaces during natural weathering
1992 - IRG/WP 92-2390
Thin veneers of radiata pine (Pinus radiata D. Don) were exposed to natural weathering over a period of 30 days. Incident UV radiation was monitored at the test site. FTIR internal reflectance spectroscopy was used to study the chemical changes taking place at the veneer surface during weathering. Spectra obtained show that after only 3 days exposure there was substantial delignification at veneer...
P D Evans, K J Schmalzl, A J Michell
Über Hausbock Hylotrupes bajulus (L.), (Col., Cerambycidae), in Laubholz: Versuche mit Laubholzarten, Prüfung der Wirkung von Ligninstoffen und von Ginkgo biloba, Beobachtungen an Hesperophanes. [On House-longhorn Beetle Hylotrupes bajulus (L.), (Col., Cerambycidae) in hardwood: Investigations with several hardwood-species, tests on activity of lignin components and Ginkgo biloba, observations on Hesperophanes]
1982 - IRG/WP 1144
Hylotrupes bajulus-larvae feed and develop in softwoods, hardwood acts as a feeding poison. The reason for this is still little known. According to literature some observations contradict this established opinion and the question was raised, whether the colour-strain scutifer (= lividus) is able to live in hardwood. Testing ten European and tropical hardwood-species (following the DIN-EN test proc...
S Cymorek
Durability of heat-treated wood
1999 - IRG/WP 99-40145
Heat-treated wood from the French process were laboratory tested against decay using agar block test and a modified soil block test. Water absorption, bending strength, lignin content and acid number were also determined to evaluate the effect of heat treatment. Heat treated samples exhibit a higher lignin content and a lower acid number compared to untreated control indicating the degradation of ...
D P Kamdem, A Pizzi, R Guyonnet, A Jermannaud
Effects of cyproconazole and copper sulphate on the length of the hyphal growth unit (HGU) of the white-rot fungus Coriolus versicolor
2003 - IRG/WP 03-10473
Wood decay basidiomycetes have been shown to produce appreciable quantities of extracellular mucilaginous materials (ECMM). The relationship between ECMM and total biomass production has been investigated in the white-rot fungus Coriolus versicolor (CTB 863 A). Differences in the amount of ECMM produced by the fungus proportionally to the total biomass, were observed under a range of physiological...
D Vesentini, D J Dickinson, R J Murphy
Relationship between degradation of wood, cellulose or lignin-related compounds and production of hydroxyl radical or accumulation of oxalic acid in cultures of brown-rot fungi
1994 - IRG/WP 94-10062
The degradation activities of brown rot fungi against wood, cellulose, and lignin-related compounds were measured in cultures containing glucose or wood as a carbon source. Also the activities of one-electron oxidation and hydroxyl radical production and the amount of oxalic acid present in the cultures were measured. The degradation activities of the fungi against wood, crystalline cellulose and ...
S Itakura, T Hirano, H Tanaka, A Enoki
Attempts to isolate tunnelling bacteria through physical separation from other bacteria by the use of cellophane
1992 - IRG/WP 92-1535
During attempts to isolate tunnelling bacteria in pure culture, physical separation from other bacteria was successfully achieved by the use of cellophane. Cellophane was used in liquid cultures as a substrate for tunnelling bacteria that were present in a mixture with other bacteria. By tunnelling into cellophane, TB were physically removed from contaminating bacteria which could then be removed ...
T Nilsson, G F Daniel
Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden
Persistance of active ingredients in treated wood
1993 - IRG/WP 93-50001-20
Disposing of chemically protected waste wood implies the distinction between surface and pressure treatment. Considering that barked round-wood merely contains, after 7 months open storage, less than 30 g per ton of bark or 25 mg per ton of sapwood, depending on the type of insecticide, the bark or sapwood shavings may be incinerated normally, according to less severe legal prescriptions than for ...
E Graf, P Manser, S Rezzonico, B Zgraggen
Detection of methanogenic bacteria in mining timber
1988 - IRG/WP 1352
Methane explosions in gold mines have been attributed to spontaneous ignition of methane/air mixtures. Biogenesis of methane in the heartwood of diseased trees has been shown, but never in timber in service. Studies were therefore undertaken to establish whether methanogens were present in wooden pit props. Core samples were removed by Pressler increment borer from props in disused areas 2,600 m d...
L D Abraham, K Westlake, R I Mackie, J F Putterill, A A W Baecker.
Tunnelling bacteria
1983 - IRG/WP 1186
The micromorphology of decay in wood caused by a certain group of single-cell bacteria, called tunnelling bacteria (TB), is described. TB are characterised by their tunnelling ability within the secondary cell walls of wood fibres. Pure cultures of TB have not yet been obtained although the typical decay patterns can be reproduced using mixed bacterial cultures. Some indications of lignin degradin...
T Nilsson, G F Daniel