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Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Borate-treated food affects survival, vitamin B12 content, and digestive processes of subterranean termites
1990 - IRG/WP 1448
Toxicity of boron compounds was studied by analyzing survival rates and vitamin B12 contents in Formosan subterranean termites, Coptotermes formosanus Shiraki, that were exposed to dietary treatments for 10 days. The dietary treatments applied in moistened cellulose were (a) 0.05% boric acid equivalent (BAE) of disodium octaborate tetrahydrate, (b) 0.05% BAE of anmonium pentaborate plus sodium sul...
L H Williams, S I Sallay, J A Breznak


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Comparative response of Reticulitermes flavipes and Coptotermes formosanus to borate soil treatments
1991 - IRG/WP 1486
Eastern (Reticulitermes flavipes [Kollarl]) and Formosan (Coptotermes formosanus Shiraki) subterranean termite workers (Isoptera: Rhinotermitidae) were exposed to borate-treated sand in an indirect exposure tunneling assay in the laboratory. In the ten day assay period, both termite species readily penetrated sand containing 5000, 10000, or 15000 ppm (wt. of compound / wt. of sand) disodium octabo...
J K Grace


Borate thermal treatments
1992 - IRG/WP 92-3715
Green, partially seasoned (air-dried, steam conditioned), or kiln-dried southern pine timbers were treated thermally using 15% disodiumoctaborate tetrahydrate solution. After treatment, sections were stored under non-drying conditions to allow for diffusion. Results showed that effective treatment meeting the AWPA minimum retention (0.17 B203 pcf [2.72 kg/m³] in the outer inch) and penetration (2...
H M Barnes, R W Landers, L H Williams


Effect of protective additives on leachability and efficacy of borate treated wood
2002 - IRG/WP 02-30290
Borate preservatives have been used extensively in many countries as an effective means for protecting wood against fungal and insect attack especially in interior environments. Under exterior conditions, borate compounds have a main disadvantage as they can be leached from treated wood as a result of their water solubility. In this study, we compared the potential of different additives for re...
A Mohareb, J Van Acker, M Stevens


Field Testing of Copper Carboxylate Preservatives
2003 - IRG/WP 03-30322
This paper details our ongoing experience with field testing of copper naphthenate and other copper carboxylate preservative systems. Results from field stake tests at an AWPA Hazard Zone 4 test site are presented. In general, copper carboxylates made with ‘synthetics’ yielded results equivalent to or only slightly lower than systems with straight nap acids or nap acids amended with syntheti...
H M Barnes, M G Sanders, T L Amburgey


The effect of temperature on the rate of fixation of an alkyl ammonium compound (AAC) wood preservative
1984 - IRG/WP 3293
The rate of fixation of an alkyl ammonium compound wood preservative was measured by soaking samples of wood wool in various preparations of the preservative for arbitrary times followed by immediate leaching in water. The wood wool was then analysed for residual preservative. The results indicated that fixation was very rapid and increased at higher temperatures....
P Vinden


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi
1989 - IRG/WP 1394
Field tests using freshly felled pine sapwood were set up to determine the effectiveness of a range of antisapstain compounds and to study the problems of colonization by mould and sapstain fungi. Differences were recorded both in the overall performance of the compounds and also their selectivity in controlling specific fungal types. These results were found to be useful in gaining a better under...
G R Williams, D A Lewis


Options for accelerated boron treatment: A practical review of alternatives
1985 - IRG/WP 3329
Boron wood preservatives are almost exclusively applied by momentary immersion and block diffusion storage. Alternative techniques are described which can be used to accelerate boron treatment. Diffusion coefficients have been derived to define the acceleration of diffusion with increasing temperature. Schedules are described for pressure impregnation of green timber, involving steam conditioning,...
P Vinden, T Fenton, K Nasheri


Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent wa...
T L Highley, L Ferge


Sequential exposure of borate treated Douglas-fir to multiple Formosan subterranean termite colonies in a 40-week field test
1993 - IRG/WP 93-10006
Douglas-fir boards (ca. 74.5 g) pressure-treated with disodium octaborate tetrahydrate (DOT) retentions of 0 (controls), 0.88, 1.23, 1.60, or 2.10% (weight/weight) DOT were sequentially exposed to four active field colonies of Formosan subterranean termites, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae), in an above-ground field test. Samples were placed in contact with each colony fo...
J K Grace, R T Yamamoto


Evaluation of an alkyl ammonium compound as a fungicide to control sapstain and mould during diffusion storage
1984 - IRG/WP 3282
An alkyl ammonium compound ('Akzo' ES 255) was evaluated for its effectiveness against mould and sapstain during diffusion storage of boron-treated rubber wood. Though ES 255 at 1.0% concentration was effective against mould (71%) and sapstain (89%) it is less satisfactory compared to 0.5% sodium pentachlorophenoxide against mould (92%) and sapstain (98%)....
R Gnanaharan


Protection of OSB against termites by incorporation of different actives via glue line treatment
2008 - IRG/WP 08-30453
Different organic actives and zinc borate were incorporated into OSB during the manufacturing process to enhance the resistance against termites. Tests according to EN 117 revealed excellent performance of thiacloprid. Other organic actives such as permethrin might be effective when used in higher amounts. Zinc borate failed the test by far....
S Donath, P Spetmann, T Jaetsch, T Zahlmann


Tests on the effectiveness of concentrated borate wood preservative
2009 - IRG/WP 09-30500
Tests were carried out to examine the toxicity of concentrated borate wood preservative to termites, fungi and mammals. The results showed that the preservative treated timber had high resistance to termite or decay and its acute oral toxicity belonged to low grade. The research shows that concentrated borate solution is an environmentally sound preservative and can be used in non-pressure treatin...
Su Haitao, Zhang Yanjun, Xie Guijun, Chen Lifang, He Xuexiang


Diffusion of fused borate rods in top ends of poles
1989 - IRG/WP 3518
Diffusion tests of fused borate rods were carried out on extremities of sapwood poles in service. Rods were set in drills under the cone with or without addition of liquid Boracol 40. After one year of weathering, a good diffusion in the slice under the cone and even below the slice and in the cone itself was observed in Scots pine and spruce poles. The rods were still intacts and constitute, in f...
D Dirol, J P Guder


The influence of previous anti-blue-stain preservative treatments on the fixation of CC in spruce
1997 - IRG/WP 97-30134
Freshly cut and kiln dried spruce boards were treated with 4 different anti-blue stain preservatives (ABP). After a period of 10 days allowing the samples to dry and fixate, the samples were treated with CC (chromium, copper formulation) using a vacuum pressure cycle. After impregnation the wood was steam fixed. A submersion leaching test showed differences in the leachable quantity of copper and ...
M Van der Zee, W J Homan


Kinetic modelling of adsorption of quaternary ammonium compounds by Scots pine wood sawdust (Pinus sylvestris L.)
2005 - IRG/WP 05-30369
The adsorption of new quaternary ammonium compounds from aqueous solutions onto Scots pine wood (Pinus sylvestris L.) sawdust was studied. The pseudo first- and second- order kinetic models were used for the mathematical description of the sorption dynamic process of QACs onto wood. The highest correlation coefficients were obtained for the pseudo-second order kinetic model, those suggest that che...
J Zabielska-Matejuk


Conditions for basidiospore production in the brown rot fungus Gloeophyllum separium in axenic culture
1984 - IRG/WP 1232
Attempts to control and optimize the production of hymenial structures and basidiospore production in Gloeophyllum sepiarium in axenic culture resulted in the proposal of the following conditions as being suitable. The dikaryotic mycelia originally isolated from basidiocarps could consistently be induced to produce hymenial structures and pure basidiospore collects if illuminated by near ultraviol...
J Bjurman


The performance of wood preservatives in soil-bed soft rot tests
1993 - IRG/WP 93-20007
Testing the efficacy of wood preservatives in soil is recognised as a fundamental part of the assessment of long-term wood protection in ground contact. Laboratory based tests can provide a hazardous environment in which a preservative can be challenged by a range of micro-organisms. This paper presents the results of tests carried out to investigate the performance of wood preservatives in a wet ...
G R Williams, S Caswell


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