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Fluoride movement through Douglas-fir and hem-fir lumber following dipping in potassium/ammonium bifluoride
1995 - IRG/WP 95-40040
The ability of ammonium and potassium fluoride to diffuse through Douglas-fir and hem-fir lumber was evaluated over a 90 day period. Boards were dipped in a solution containing 10% (by weight) of ammonium and potassium bifluoride, then stored under cover for 90 days. Samples removed 30, 60 and 90 days after treatment indicated that the fluoride was unable to completely penetrate the wood. Penetrat...
J J Morrell, C S Love


Fungicidal effectiveness of amended alkylammonium compound
1987 - IRG/WP 3421
Amendment of didecyldimethylammonium chloride was attempted to improve its fungicidal effectiveness and properties of treating solutions. Addition of copper definitely increased effectiveness in controlling wood decay fungi, although metal corrosiveness and stability of treating solutions was unsatisfactory. Further amendment with stabilizer(s), anticorrosive agent(s) and sequestering agent(s) res...
K Tsunoda, K Nishimoto


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


Fungitoxic effect of the quaternary ammonium compounds wood preservatives against the Ascomycetes and Deuteromycetes
1997 - IRG/WP 97-30138
Results of investigation on fungitoxic value of the three formulations of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethylbenzylammonium bromide, alkylbenzyldimethylammonium chloride) in relation to the surface wood colouring (moulds) and soft-rot fungi have been presented. The agar-plate (screening) and agar-wood plate for mouldi...
J Wazny, P Rudniewski


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Performance of proprietary formulations of anti-sapstain preservatives on Hevea brasiliensis timbers in laboratory tests
1989 - IRG/WP 3532
A total of 10 proprietary and two experimental formulations were assessed for their effectiveness against sap-stain caused by Botryodiplodia theobromae on Rubberwood (Hevea brasiliensis). Sterilized wood samples 5x20x40 mm³ were dipped in the test chemicals for 60 seconds and then inoculated with 0.5 ml of culture filtrate of Botryodiplodia theobromae for incubation in sterile, damp petri dishes....
L T Hong


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


Preliminary evaluation of new quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate for preventing fungal decay and termite attack
2005 - IRG/WP 05-30375
This study evaluates the decay and termite resistance of wood treated with didecyl dimethyl ammonium tetrafluoroborate (DBF), a recently developed quaternary ammonia compound containing boron. DBF contains boric tetrafluoride as a counter ion in its chemical structure. Laboratory decay resistance tests were performed using brown-rot fungus, Fomitopsis palustris and white-rot fungus, Trametes versi...
S N Kartal, W J Hwang, Y Imamura


The influence of timber species and preservative treatment on spore germination of some wood-destroying Basidiomycetes
1988 - IRG/WP 2300
Basidiospores from six wood decay fungi exhibited varying germination rates on untreated softwood and hardwood blocks. Germination inhibition of all test fungi was recorded on pine sapwood. No preference for a certain timber species by a particular fungus was evident. Whereas almost complete inhibition of germination occurred on wood treated with a quarternary-ammonium based wood preservative, mos...
B M Hegarty, G Buchwald


The biocidal efficacy of sulphates against basidiomycetes
1999 - IRG/WP 99-30192
Copper sulphate is used for the preservation of wood since decades. However, if copper sulphate is not combined with a compound it can be leached up to 50% and more from the treated wood. Previous results for leached wood indicated that the loss of biological efficacy against soft rot corresponds to leaching of copper. For basidiomycetes, however, the effectiveness decreases much more rapidly. The...
H Leithoff, E Melcher


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


Measurement of electrokinetic potential to evaluate adsorption of quaternary ammonium salt
1991 - IRG/WP 3672
Measurement of z-potential in the wood treated with preservatives is suggested as a method for determination of the adsorption of preservative to wood. It has been found that measurement of z-potential of wood treated with quaternary ammonium salt type preservatives can be a useful method to determine the adsorptives phenomena of preservatives and by which there is a remarkable differences in the ...
Yeong Suk Kim


A study of methanogenesis and sulphate-reduction: A possible source of explosive gas mixtures in a gold mine
1989 - IRG/WP 1399
Previous work isolated anaerobic bacteria from timbers and drainage water in a gold mine. The present work identifies the predominant methanogen in the mine ecosystem as Methanobacterium bryantii and sulphate-reducing isolates as Desulphovibrio desulphuricans and Desulphotomaculum antarcticum. Laboratory studies using model systems evaluate the activity of methanogenic and sulphate-reducing bacter...
L D Abraham, J F Putterill, A A W Baecker


Influence of fungal exposure on the redistribution of copper in treated spruce wood
2002 - IRG/WP 02-10450
The redistribution of copper in treated wood after exposure to basidiomycete decay fungi is described. The micro-distribution of copper in copper(II) sulphate or copper(II) octanoate/ethanolamine treated Norway spruce wood before and after exposure to 3 different wood decay fungi was studied using transmission electron microscopy with X-ray microanalysis. The copper content of the mycelium and the...
M Humar, F Pohleven, R J Murphy, D J Dickinson, I Moris, M Zupancic, P Kalan, M Petric


The effect of stack height on the performance of preservatives used for the prevention of sapstain on seasoning wood
1997 - IRG/WP 97-10192
The performance of three anti-sapstain preservatives was investigated under field conditions in south east England. The preservatives under test were: copper-8-quinolinolate (Mitrol PQ8) trimethylalkylammoniumchloride and sodium hexanoate (Sinesto B) and chlorothalonil (Tuff Brite). The preservatives were tested on Corsican Pine grown in south east England. The field trial was set up to investigat...
J R Williams, D J Dickinson, J F Webber


A novel technique for comparative toxicity studies of potential insecticidal wood preservatives
1983 - IRG/WP 2198
For some years now a device has been under development at the New Zealand Forest Research Institute, the purpose of which is to study the effects of sub-lethal amounts of stomach poisons (but also of fumigants and contact active materials) on the co-ordinative abilities of a cerambycid larva. This insect is Prionoplus reticularis - indigenous to New Zealand its larvae feed in decaying logs and are...
D J Cross


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Alkyl dimethyl benzyl ammonium chloride: toxicity to Coniophora puteana when formulated in water and organic solvent
1986 - IRG/WP 2250
Results from agar block tests using Coniophora puteana demonstrate that the biological activity of alkyl dimethyl benzyl ammonium chloride is affected by the nature of the carrier solvent in which it is applied. In contrast to some earlier work, an alkyl ammonium compound in organic solvent formulation was identified that had significantly greater activity than its aqueous equivalent. A simple sol...
D P Blow


Biological resistance of didecyl dimethyl ammonium tetrafluoroborate (DBF)-treated wood in soil-bed and Basidiomycetes tests
2006 - IRG/WP 06-30393
This study evaluated the decay resistance of treated wood with a new quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) in laboratory soil bed and Basidiomycetes tests. Treated sugi sapwood specimens with DBF at various concentration levels were first subjected to soil bed tests using two types of soil. The specimens subjected to soil bed tests were then used for Basidi...
S N Kartal, C Brischke, A O Rapp, Y Imamura


Some textile auxiliaries as wood protective agents
2007 - IRG/WP 07-30417
This study evaluated some textile auxiliaries applicable for wood protection. Commercial alkoxysilane quarternary ammonium formulation and fluorocarbon based water-oil repellent were tested for their ability to provide hydrophobicity and antifungal effect to solid wood samples. Scots pine (Pinus sylvestris L.) sapwood samples were impregnated with 25, 50 and 100 % concentrations of the above menti...
E Dizman, A Temiz, N Terziev, Ü C Yildiz


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