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Wood surface pretreatments with metal tannates
1989 - IRG/WP 3552
The sequential application of aqueous solutions of tannins derived from radiata pine bark and water-soluble metal salts was examined as a means of improving the water repellency of wood surfaces. Nine metal salts were screened in combination with tannin solutions and, based on water repellency of pretreated filter paper, four were selected for further study. The two-step application of tannin solu...
D V Plackett, D R Cronshaw


Status of wood preservation industry in India
2005 - IRG/WP 05-30388
The paper traces the history of wood preservation industry in India, listing various mile stones for creation of treating capacity. The preservation industry developed with the development of rail road system on the line of most other developed countries. The most popular wood preservatives are CCA, CCB, ACC, Creosote and recently LOSP have also appeared in the market. The major users of CCA is th...
S Kumar


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


Leachabilty and efficacy of fatty acid derived boron esters as wood preservatives - leachability and efficacy of fatty acid derived boron esters as wood preservatives
2004 - IRG/WP 04-30351
Borates have many advantages as wood preservatives. However, boron is susceptible to depletion under humid conditions and this restricts its outdoor use. In order to reduce boron leachability in treated wood, one of the anticipative approaches is to use organic fixed boron-based preservatives. This study investigated the leachability of six boron ester compounds as potential preservatives. Scots p...
A Mohareb, J Van Acker, M Stevens


Relationship between degradation of wood, cellulose or lignin-related compounds and production of hydroxyl radical or accumulation of oxalic acid in cultures of brown-rot fungi
1994 - IRG/WP 94-10062
The degradation activities of brown rot fungi against wood, cellulose, and lignin-related compounds were measured in cultures containing glucose or wood as a carbon source. Also the activities of one-electron oxidation and hydroxyl radical production and the amount of oxalic acid present in the cultures were measured. The degradation activities of the fungi against wood, crystalline cellulose and ...
S Itakura, T Hirano, H Tanaka, A Enoki


Influence of acidification on decay processes of CCB treated wood
2004 - IRG/WP 04-10514
The phenomenon of copper tolerance by brown rot fungal strains has been known for a long period but the complete mechanism of copper tolerance by these fungi is not understood yet. Copper tolerance has previously been linked to oxalic acid excreted by copper tolerant brown rot fungal strains. This acid reacts with copper in the wood to form an insoluble and therefore less toxic copper oxalate. The...
M Humar, S A Amartey, M Šentjurc, F Pohleven


Soil treatment tests with the three products of boric acid for the prevention of the hyphal growth of Serpula lacrymans
1992 - IRG/WP 92-3693
Laboratory soil treatment tests were conducted for the evaluation of fungicidal or fungistatic effect of boric acid products against Serpula lacrymans. Boric acid products tested were the following three: a thickened boric acid solution in triethanolamine, boric acid-silica gel complex granules, and a nonwoven fabric laminated with a polypropylene film and coated with boric acid granules on one si...
S Doi, A Yamada, Y Mineki, M Mori


Old and new facts on the dry rot fungus Serpula lacrymans
1991 - IRG/WP 1470
The article collates some of the recent literature on the biology of the dry rot fungus Serpula lacrymans. The fungus can grow at 28°C, and maximum wood moisture is above 55%. Serpula Iacrymans degrades crystalline cellulose. The intensive production of extracellular oxalic acid is neutralized by calcium and iron. There is considerable variation among the strains with regard to factors such as gr...
O Schmidt, U Moreth-Kebernik


Reduction of preservatives leaching from wood by the application of animal proteins
2005 - IRG/WP 05-30387
The investigations consisted in the estimation of the effectiveness of protein borates and protein propionates in wood preservation against Coniophora puteana. The estimation was made on the basis of mass losses caused by the test fungus action against treated wood which was subjected to leaching with water. The investigations were performed for Scots pine wood (Pinus sylvestris L.) treated with p...
B Mazela, I Ratajczak, M Bartkowiak


Properties of cellulose degraded by the brown rot fungus, Postia placenta
1988 - IRG/WP 1350
To gain further understanding of the nature of the cellulose depolymerizing agent or agents of brown-rot fungi, brown-rotted cellulose was chemically and physically characterized. Various culture conditions, such as low nitrogen and elevated oxygen levels, did not induce degradation of cellulose by Postia placenta in liquid cultures. Therefore, brown-rotted cellulose for analysis was prepared by a...
T L Highley, R E Ibach, T K Kirk


Remedial treatment of creosoted railway sleepers of redwood by selective application of boric acid
1980 - IRG/WP 3134
An ideal preservative for remedial treatment must primarily be characterized by two requirements. First, it must have an ability to diffuse and distribut evenly into the wood and secondly, it must be fixed properly so that it does not leach out too fast. However, these two characteristics conflict with each other, and the choice of preservative must of necessity be a compromise. Wood preservatives...
C Bechgaard, L Borup, B Henningsson, J Jermer


Preservative treatment of rubber wood (Hevea brasiliensis) to increase its service life
2005 - IRG/WP 05-40320
Rubber wood (Hevea brasiliensis) possess excellent properties for interior designing, wood working and furniture making. But it is very much susceptible to sap stain and mould fungi which decreases the service life. For profitable uses , it is necessary to increase the service life of rubber wood. To protect the rubber wood from wood degrading agents, the sawn timber were treated with Borax – b...
K Akhter


Influence of surface coating on the leachability of boric acid and bifluorides from spruce wood
1995 - IRG/WP 95-50050
In the Netherlands, window joinery made from non-durable timber species (spruce) are widely protected with preservative rods. These rods contain non-fixing wood preservatives (e.g. bifluorides or boric acid). This reseach was performed to show the possible influence of a coating system to hinder the leaching of the active ingredients. The results of the leaching tests show, that bifluorides and ev...
W J Homan, H Militz


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


Effect of thickened boron in preventing conidial germination of sapwood-inhabiting fungi
1994 - IRG/WP 94-30059
We evaluated the efficacy of thickened boron preservative "Diffusolä" in preventing conidia germination of sapwood-inhabiting fungi using plate bioassay, Southern Yellow Pine and sweetgum block tests, and green pine log sections. The test fungi were sapstain fungi Ceratocystis coerulescens, Ceratocystis minor, and Aureobasidum pullulans and mold fungi, Aspergillus niger, Penicillium spp, and Tric...
S C Croan


Practical experiments with Boracol 10 Rh used as a fungicide in the repair process after attack by the dry rot fungus (Serpula lacrymans)
1987 - IRG/WP 3458
The test is carried out in an old house in Nyhavn, Copenhagen. The roof and the walls close to were heavily attacked by dry rot fungus (Serpula lacrymans) because damage to the zinc covering the frontspice were letting in water to the wood and wall construction. An attack by the dry rot fungus is more complicated to repair compared with other wood destroying fungi because beside the damage on wood...
J Bech-Andersen


The effect of of sorbitol on the decay of boric acid treated Scots pine
1991 - IRG/WP 1509
The tetra-hydroxy borate ion is known to undergo complexation with polyols of biological importance and probably protects treated timber by this action. The inhibitory effect of boric acid upon fungal growth and dehydrogenases has been shown to be prevented by the addition of certain polyols. This work was extended, with a study of the effects of a polyol on the performance of boric acid in treate...
J D Lloyd, D J Dickinson, R J Murphy


A possible role of unique TCA cycles in wood-rotting basidiomycetes
2003 - IRG/WP 03-10461
The copper tolerant brown-rot fungus, Fomitopsis palustris, acquires metabolic energy by use of the constitutively-occurring Kornberg’s glyoxylate cycle coordinating with oxalate biosynthesis and glucose oxidation (Erman Munir et al. Proc. Natl. Acad. Sci. USA, (2001) 98, 11126-11130). Furthermore, this fungus does not have the normal TCA cycle, lacking 2-oxoglutarate dehydrogenase which is a ke...
E Munir, T Hattori, M Shimada


Biological resistance of steam-compressed wood pretreated with boric compounds
1999 - IRG/WP 99-30190
Wood compression under heating is aimed to enhance dimensional stability and surface hardness. Preservative treatment with an appropriate chemical is additionally required for the protection of wood against biological agents under hazardous service conditions. Boron pretreatment of compressed wood was targeted to a mutual benefit of increasing biological resistance of compressed wood as boron was ...
M K Yalinkilic, W Dwianto, Y Imamura, K Tsunoda, M Takahashi


The lasting dehydration of wood treated by bifluorides worked up in Diffusec noticed by a continual drying of the wood
1999 - IRG/WP 99-30196
After an immersion of sound wood in a solution of Diffusec, in which a combination of acid potassium and ammonium bifluorides = FHF- in dissociated form is present, their potassium and ammonium fluoride ions together with the bifluoride ion = (FHF-) diffuse into the wood. They make use of the woodmoisture available as O-H-O bonds directly attached to the cellulose in the wood fibres to attract the...
H F M Nijman


Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Production, function and neutralization of oxalic acid produced by the dry rot fungus and other brown rot fungi
1987 - IRG/WP 1330
The formation of oxalic acid by the wood-destroying fungi causing brown rot, is found to be the key which by hydrolysing the hemicellulose brings the cellulose in the tracheid wall in contact with the cellulase enzymes and yeld watersoluble sugars leaving only a lignin skeleton. To control the pH in the substrate the excess oxalic acid is precipitated to water insoluble calcium oxalate by the dry ...
J Bech-Andersen


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