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Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


The impact of global warming on the UK distribution of house longhorn beetle Hylotrupes bajulus (L)
2001 - IRG/WP 01-10414
This paper reviews the effects of global warming on insect populations and distribution. The affects of global warming on the spread of Hylotrupes is predicted through a review of research related to the influence of temperature on its life-cycle and flight. Records of Hylotrupes distribution were obtained from published surveys, entomologists and museum collections and were plotted for the UK. Th...
P Oevering, A J Pitman


An example of media response to perceived environmental problems with CCA-treated wood
1990 - IRG/WP 3564
A recent study suggested that CCA-treated wood exposed to acidic precipitation could lose significant amounts of copper chromium and arsenic resulting in loss of efficacy and possible environmental contamination. The study received wide newspaper and radio coverage in Canada, thereby heightening public concern about CCA use. Subsequent studies in our laboratory confirmed that the high losses were ...
P A Cooper


Dimensional lumber model demonstrates the sensitivity of the particle capture immunoassay in early detection of brown-rot fungi
1995 - IRG/WP 95-20058
A dimensional lumber model was designed to test the sensitivity of the particle capture immunoassay (PCI) compared to traditional methods of culturing and microscopic examination for detection of brown-rot fungi. Southern yellow pine 2 x 4's (5.1x10.2 cm²), and 86.4 cm in length, were inoculated on one end with the brown-rot fungus, Postia placenta, and tested over the full length of the...
C A Clausen, L Ferge


Development of a model system to assess the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles
1992 - IRG/WP 92-2395
A closed model system was designed to facilitate a controlled study of the leachability and environmental fate of a remedial preservative under laboratory conditions. The elements of the model include a precipitation apparatus above a treated pole section which is positioned in a representative soil profile supporting a sward of perennial ryegrass. The model will allow detailed examination of the ...
D C R Sinclair, G M Smith, A Bruce, B King


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Dutch national environmental policy strategy (NMP): Implications throughout the life cycle of treated timber and for the Dutch preservation industry
1993 - IRG/WP 93-50001-31
All overview of relevant environmental legislation and instruments for control is given for each stage of the life cycle of treated timber. Recent policy in the Netherlands has been focused around the "National Environmental Policy Strategy", in which a general policy with regard to reduction of pollution to the air, soil and water is described. The principle is one of an "Integrated Chain of Cont...
P Esser, D A Lewis, A J Pendlebury


Characterization of Poria indoor brown-rot fungi
1995 - IRG/WP 95-10094
The heterogeneous group of "Poria" fungi causing brown rot in buildings and also of wood in ground contact comprises Antrodia vaillantii, Antrodia serialis, Antrodia sinuosa, Antrodia xantha and Tyromyces placenta. These fungi have similar morphological appearance and biology. Their nomenclature has a confusing history and is still not uniform. As a consequence, misinterpretations may occur. SDS p...
O Schmidt


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Chemostimulatory and chemotropic responses by fungi to preserved and unpreserved wood
1981 - IRG/WP 1134
During experiments to determine the presence of biotic connections between soil and wood at this laboratory, marked chemotropic responses to wood were demonstrated by some wood destroying micro-organism in agar culture. These were shown at some distance from bait, up to 35 mm away, and on some occasions were unaffected by the presence of toxic materials. This paper provides preliminary data on the...
G Mowe, B King


Feeding response of field populations of Coptotermes species to softwood blocks treated with non-toxic water-proofing and anti-microbial products.
2003 - IRG/WP 03-10487
The feeding response of field populations of the subterranean termite, Coptotermes lacteus, to Pinus radiata wood blocks (50 x 40 x40 mm) treated with various combinations of non-toxic and odourless water-proofing materials based on natural high molecular weight esters (TimberTreatÒ) and a new water insoluble quaternary ammonium compound (‘anti-microbial’) is described. Treated wood blocks we...
J R J French, T Pynsent, M Susic


A model for attack at a distance from the hyphae based on studies with the brown rot Coniophora puteana
1995 - IRG/WP 95-10104
In timber infested by brown rot fungi, a rapid loss in strength is attributed to production of hydroxyl radicals (HO·) at a distance from the hyphae. The immediate precursor is Fenton's reagent (Fe(II)/H2O2), but the pathways leading to Fe(II) and H2O2 have remained unclear. Cellobiose dehydrogenase, purified from cultures of Coniophora puteana, will couple oxidation of cellodextrins to ...
S M Hyde, P M Wood


Moisture Adsorption Behaviour of Rubber Wood Decayed by Brown and White rot Fungi
2005 - IRG/WP 05-40306
Moisture adsorption behaviour of rubber wood blocks decayed by each brown rot and white rot fungi was studied. The adsorption isotherms of decayed wood were compared with the isotherm of undecayed wood. The wood decayed by brown rot adsorbed less moisture as compared to sound or undecayed wood at all humidity levels. No significant difference was observed in adsorption behaviour of white rot dec...
S S Chauhan, H C Nagaveni


Termite Response to Oil-Heat-Treated Norway spruce, Scots Pine and Eucalyptus Wood
2006 - IRG/WP 06-20325
The work here presented focused on the behaviour of subterranean termites (Reticulitermes grassei Clément) towards Oil-Heat-Treated (OHT) Norway spruce (Picea abies L.), Scots pine (Pinus sylvestris L.) and eucalyptus (Eucalyptus globulus Labill) wood, with a particular interest in the development of simple methods adequate to study the resistence of these materials to termite attack. Small test ...
L Nunes, T Nobre, C Welzbacher, A O Rapp


The response of the Formosan subterranean termite (Coptotermes formosanus Shiraki) to different boron compounds
2007 - IRG/WP 07-10609
Although boric acid and other boron compounds have been used since the 1800s as insecticides, their mode of action is not well understood. Borate salts, in particular sodium and zinc formulations, are effective wood preservatives and are used extensively in Hawai’i to protect building materials from both drywood (Kalotermitidae) and subterranean (Rhinotermitidae) termites. The Formosan subterra...
M C Gentz, J K Grace


Foraging Behavior of the Formosan Subterranean Termite (Isoptera: Rhinotermitidae) in Response
2007 - IRG/WP 07-10605
Foragers of the Formosan subterranean termite, Coptotermes formosanus Shiraki, were allowed to tunnel in two dimensional, sand filled arenas containing Douglas-fir (Pseudotsuga menziesii [Mirb.] Franco) wafers pressure treated with disodium octaborate tetrahydrate (DOT) to an average retention of 1.77 % BAE on one side of each arena, and untreated wafers of Douglas-fir on the other side. Arenas w...
C E Campora, J K Grace


Seasonal response of feeding, differentiation, and growth in the eastern subterranean termite Reticulitermes flavipes (Kollar) in Wisconsin
2007 - IRG/WP 07-10604
In termites, differentiation plasticity in undifferentiated Reticulitermes progresses with growth stages from larvae to workers, which may then differentiate into soldiers, winged nymphs, or neotenics. Although studies have been done on seasonality of the termite life cycle, data appears to vary from location to location. Reticulitermes populations in Wisconsin appear to behave slightly differentl...
R A Arango, F Green III, G R Esenther


Determination of the lethal dose of fipronil for workers of Coptotermes formosanus (Isoptera: Rhinotermitidae
2007 - IRG/WP 07-10616
This document is a combination of two articles previously submitted to the journal, Sociobiology. Lethal dose of fipronil was determined in two experiments: topical application and contact with treated sandy loam. In the topical application the toxicity of fipronil was evaluated against workers of a laboratory colony of Coptotermes formosanus Shiraki. Fipronil was applied by the microsyringe to t...
K Tsunoda, R Yamaoka


Fire Safety of Wood Floor Assembly: Model and Full-scale Test
2007 - IRG/WP 07-20375
The present paper describes the model for the prediction of fire safety of wood floor assemblies. The model includes heat transfer model for the calculation of the flow of heat in floor assembly and structural model for the analysis of the mechanical performance of wood joists. The floor assemblies considered in this paper are constructed with nominal 2x10 (38x241mm) wood joists lined by Type X ...
H Takeda


Moisture adsorption isotherms of wood studies using a dynamic vapour sorption apparatus
2009 - IRG/WP 09-20398
Five types of wood including two Malaysian hardwoods acacia mangium (Acacia mangium) and sesenduk (Endospermum malaccense), two temperate softwoods, Sitka spruce (Picea sitchensis), radiata pine (Pinus radiata) and Accoya (commercially modified wood) were studied to determine their moisture sorption behaviour using a Dynamic Vapour Sorption (DVS) apparatus. The isotherm plot for each species teste...
J Zaihan, C A S Hill, S Curling


Differential response of wood to dry air thermal treatment (DATT) and soy oil thermal treatment (SOTT)
2009 - IRG/WP 09-40446
Thermal treatment is an alternative to chemical modification method which has been used to some extent in improving timber quality. In order to get the maximum benefits possible without compromising the various end-use quality requirements of timber, several possibilities have been and are still being investigated in relation to this technique. Clear wood samples (19 x 19 x 150mm) of kiln-dried re...
L Awoyemi


Estimating the age of subterranean termite attack and damage in buildings
2010 - IRG/WP 10-10727
This paper describes physical and experimental methods and a mathematical model (Rotramel 2003) to assist in estimating the age of subterranean termite attack and damage to building structures. Timber, building and termite management industries have to develop new strategies to assess and estimate termite attack and damage in the current climate of global warming. A case study will be used as an e...
J R J French, B M Ahmed Shiday, J Thorpe


Finite Element Modelling of the Checking of Wood Exposed to Accelerated Weathering
2010 - IRG/WP 10-20459
The surface checking that develops when wood is exposed to the weather reduces the visual appeal of treated wood products and can reduce the effectiveness of preservative treatments. There is strong interest in developing solutions to this problem and also a growing realization that such solutions may evolve from a deeper understanding of the mechanisms responsible for surface checking. In this pa...
S G Ribarits, P D Evans


Assessment of Boracol 200RH (FrameSaver) as a remedial treatment to control decay in pre-decayed model timber frame units
2010 - IRG/WP 10-30529
Model timber frame units constructed from untreated radiata pine were pre-wetted to approximately 40% moisture content and inoculated with Coniophora puteana and Oligoporus placenta. Units were transferred to a controlled environment room maintained at 25°C and 95% RH for 7 and 10 weeks to allow two levels of decay to become established in units. Following pre-decay, units were disassembled, clea...
Mick Hedley, Dave Page, Jackie van der Waals


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