IRG Documents Database and Compendium


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Removal of heavy metals from treated wood using biological methods
2005 - IRG/WP 05-50226
Heavy metals were removed from wood treated with copper based preservatives using brown-rot fungus Fomitopsis palustris. The amount of effective elements removed by treatment methods was examined. The relationship between oxalic acid concentration and the amount of heavy metals removed from each treated wood was also investigated. The relationship between fungus weight and removal rate was also in...
Dong-won Son, Dong-heub Lee


Fungal biodegradation of CCA-treated wood wastes
2011 - IRG/WP 10-50276
Fungal biodegradation could be employed as a pretreatment method to alleviate problems caused by landfill disposal of CCA-treated wood wastes (e.g. a shortage of landfill space and a release of leacheate). It could be used to decrease the volume of waste and to remove metals from waste simultaneously. We have screened hundreds of decay fungi, including fungi isolated from CCA-treated wood in servi...
Gyu-Hyeok Kim, Yong-Seok Choi, Jae-Jin Kim


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell


Non-enzymatic Gloeophyllum trabeum decay mechanisms: Further study
2001 - IRG/WP 01-10395
Information will be presented on the mechanisms involved in, and potential application of, non-enzymatic wood decay by brown rot decay fungi. Specifically, the hypothesized role of low molecular weight phenolate derivatives will be discussed in relation to non-enzymatic degradation of wood. The mechanism of binding of iron by cellulose, and binding and reduction of iron by fungal derivatives and m...
B Goodell, J Jellison


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Effect of EDTA on removal of CCA from treated wood
2002 - IRG/WP 02-50182
Since substantial amounts of chromated copper arsenate (CCA) remain in the wood for many years, the disposal of CCA-treated wood causes escalating environmental concerns. Additionally, wood waste is generated when treated wood is put into service, for which environmentally benign disposal technologies need to be developed. Novel approaches to remove copper, chromium, and arsenic from CCA-treated w...
S N Kartal


Bioassays for rapid assessment of heavy metal toxicity in seawater
1998 - IRG/WP 98-50112
In evaluating the effect of CCA leachate on the establishment of fouling communities on wood exposed in the sea, three organisms were assessed as biological indicators of heavy metal toxicity. These were two macroalgae, Fucus serratus and Undaria pinnatifida. and the motile protist thraustochytrid, Schizochytrium aggregatum. The choice of these organisms for the tests carried out was based on the ...
C J Brown, R L Fletcher, R A Eaton


Estimation of the population of a sound colony of Coptotermes lacteus (Froggatt)
1988 - IRG/WP 1353
Selecting an area with a high termite hazard is deemed essential in locating field sites in order to screen potential termiticides and wood preservatives. Yet, quantifying termite populations in such sites remains imprecise. There are major problems associated with estimating populations of termites in mound colonies (either free-standing or in trees), and these are briefly discussed. In this pape...
D M Ewart, J R J French


Optimum growth conditions for the metal-tolerant wood decay fungus, Meruliporia incrassata TFFH 294
1999 - IRG/WP 99-50142
There is a worldwide need for alternative methods for the treatment and disposal of CCA-treated waste wood. Illman and Highley (IRG/WP 96-10163) reported the isolation of a unique strain of Meruliporia incrassata (TFFH 294) with tolerance to CCA. The strain is capable of degrading CCA treated waste wood, giving a 40% weight loss in the ASTM soil block test. The strain is an ideal candidate for deg...
V W Yang, B Illman


Removal of CCA from Spent CCA-Treated Wood
2002 - IRG/WP 02-50192
A novel method for the removal of CCA components from spent CCA-treated wood has been developed. The CCA-treated wood was first converted into liquid in the presence of polyethylene glycol and glycerin at mild temperatures (120 – 150 0C) by using sulfuric acid as catalyst. The resulting viscous liquefied wood was then resolved in acetone/water solvent. The hazardous components (i.e., Cr, As, and...
Lianzhen Lin, Chung-Yun Hse


Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele


The degradation of wood by metal fastenings and fittings
1972 - IRG/WP 302
As well as the hazards of biological decay, timber used in boat building is subject to the effects of chemical decay associated with the corrosion of metallic fastenings. The title has been deliberately chosen to emphasize that in wooden construction the troubles are not just those of corrosion of the fastenings, but also the destructive secondary effects on the wood caused by the products of the ...
L C Pinion


The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley


Wood surface pretreatments with metal tannates
1989 - IRG/WP 3552
The sequential application of aqueous solutions of tannins derived from radiata pine bark and water-soluble metal salts was examined as a means of improving the water repellency of wood surfaces. Nine metal salts were screened in combination with tannin solutions and, based on water repellency of pretreated filter paper, four were selected for further study. The two-step application of tannin solu...
D V Plackett, D R Cronshaw


Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process. In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Electrochemical removal of Cu, Cr and As from CCA-treated waste wood
2001 - IRG/WP 01-50166-18
CCA-treated waste wood poses a potential environmental problem due to the content of copper, chromium and arsenic. This paper presents the results obtained by electrodialytic remediation of CCA-treated waste wood. It is found that more than 90% Cu, and approximately 85% Cr and As was removed from the wood during the remediation. Thereby the concentration of copper in the wood is reduced from app. ...
I V Kristensen, L M Ottosen, A B Ribeiro, A Villumsen


Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis


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