Your search resulted in 66 documents. Displaying 25 entries per page.
Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions.
Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens
Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele
Detection of increased metal cations after wood decay using Chromeazurol-S
1997 - IRG/WP 97-20112
Chromeazurol-S (CAS) is a dye used for the spectrophotometric determination of metals, mainly aluminum (Al), berillium (Be) and copper (Cu). CAS has been widely used for determining the penetration of copper containing preservatives like CCA (AWPA A3-96). Additional uses include: i) detection of utility pole decay (Esyln, 1979), ii) a chemical spot test for aluminum in wood (Kukachka and Miller, 1...
F Green III, U Srinivasan, R B Miller
The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs
Metal plate fasteners in trussed rafters treated with preservatives or flame retardants - corrosion risks
1977 - IRG/WP 3104
In designing roof trusses employing metal plate fasteners it is generally assumed that the roof will remain dry in service. Whilst this is generally true, damp conditions do arise under some circumstances, although it is not possible to quantify the extent of the risk. It is only possible, therefore, to give general recommendations which must be interpreted in the light of local experience of serv...
R A Laidlaw, L C Pinion
Further steps in the development of above ground wood preservative systems
2002 - IRG/WP 02-30300
Metal and organo-metallic wood preservative systems have provided the consumer with cost effective wood preservative systems which satisfy the performance requirements in a wide range of end uses.
With increasing environmental and legislative control, metal-free formulations have emerged as the dominant preservative systems for the protection of timber in the lower hazard classes.
In higher ha...
P Warburton, A S Hughes
Enhanced removal of CCA from treated wood by Bacillus licheniformis in continuous culture
1997 - IRG/WP 97-50083
A gram positive, spore-forming bacterium, which was isolated from a 20-year-old Forest Service test plot of CCA-treated 2 x 4's in Madison, WI., demonstrated the ability to release copper, chromium, and arsenic from CCA-treated wood in liquid culture. CCA-treated sawdust was exposed to this organism, which has been presumptively identified as Bacillus licheniformis. Analysis of the sawdus...
C A Clausen
Evaluation of tropolone as a wood preservative : activity and mode of action
2002 - IRG/WP 02-30282
The fungicidal activity of 2-hydroxy cyclohepta-2,4,6-trienone (tropolone) analogue of b-thujaplicin a natural product responsible for the durability of heart wood of several
cupressaceous trees was investigated in vitro on growth of white and brown rot fungi. Results obtained show that tropolone, easily prepared from commercially available products,
possesses strong fungicidal activity similar ...
P Gérardin, M Baya, N Delbarre, P N Diouf, D Perrin, P Soulounganga, E Gelhaye,
J P Jacquot, C Rapin
Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic applications. Part 1: Laboratory scale investigation
1995 - IRG/WP 95-50046
In order to investigate the applicability of current prestandard leaching test methods, a series of experiments has been performed on CCA impregnated wood dealing with the influence of pH, temperature and agitation of the surrounding water. The leaching method used in this first part of the investigation is the European prestandard drafted by CEN/TC38/WG11, a short term dynamic leaching test under...
G M F Van Eetvelde, R J Orsler, G E Holland, M Stevens
CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith
Bethoguard; A new wood protecting fungicide for use in metal free ground contact wood preservatives
2002 - IRG/WP 02-30301
Research has identified the limitations in both the spectrum of activity and permanence of organic biocides placed in wood in high hazard environments, particularly in the absence of heavy metals such as copper. More specifically, the control of soft rot decay in wood in soil contact has proven to be most problematic.
The new organic biocide, Bethoguard; an oxathiazine, has demonstrated excellen...
S C Forster, G R Williams, M Van Der Flaas, M Bacon, J Gors
PXTS; A Metal Free Oligomer Wood Preserving System - A Summary of Data To Date
2004 - IRG/WP 04-30350
The world is continually looking for new wood preservative technology, especially to address environmental concerns. Recent changes in the USA have limited the use of arsenical containing formulations to industrial use through a negotiated voluntary cancellation of most residential label uses. PXTS (Polymeric Alkylphenol Polysulfide) offers a brand new technology that is an all organic system, lik...
M H Freeman, D D Nicholas, D Renz, R Buff
Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley
Corrosiveness of metal by copper-based preservatives
2006 - IRG/WP 06-40329
The corrosive rates of 4 types of metal as well as epoxy-coated metal by a variety of preservatives derived from different copper source and ingredients were conducted in this paper. The main results shown that: CCA is less corrosive to red brass and Q235A steel than other copper formulations; Copper-based preservatives such as ACQ and copper azole derived from basic cupric carbonate or cupric hyd...
Ying Zhang, Mingliang Jiang
Arsenic removal by plant pumping mechanism from arsenic solution using activated aluminum oxide as adsorbent – a preliminary study
2006 - IRG/WP 06-50239
This study evaluated the performance of plant pumping mechanism for removal of arsenic from arsenic solution using activated aluminum oxide as adsorbent. Generally, plants absorb water from soil mainly by osmosis process and toxic elements present in soil also move along with water. To remove toxic elements present in contaminated soils/water, different chemical substances are widely used as
...
B Tarakanadha, H Koyanaka, T Hata, Y Imamura
Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick
Laser stain removal of fungus-induced stains on paper-based cultural relics
2007 - IRG/WP 07-40389
Laser techniques has been developed and applied in commercial use for 40 years, but it has not been used successfully to remove stains from paper-based cultural relics . The purpose of this study was to investigate the paper cleaning by using a technique of Nd-YAG laser. Artificial stained papers were inoculated with fungi and then were treated at different laser cleaning parameters, in order to f...
Tsang-Chyi Shiah, Han Chien Lin
Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal
A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick
Optimization of oxalic acid production for bioleaching of metal components from CCA-treated wood by an unknown Polyporales sp. KUC8959
2010 - IRG/WP 10-50266
A brown-rot fungus, an unknown Polyporales sp. KUC8959, has recently been identified and proven as a prominent fungal species for bioremediation of CCA-treated wood wastes in our Lab. The fungus produced a larger amount of oxalic acid than other fungi tested, and removed 90 % or more of chromium, copper and arsenic from CCA-treated wood sawdust through bioleaching process. The bioleaching process ...
Yong-Seok Choi, Min-Ji Kim, Jae-Jin Kim, Gyu-Hyeok Kim
Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag
Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong
The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell
Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher
Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow